Bldg. 14 1443
[Coordination Chemistry, Organometallic Chemistry]
Tuesday, March 20, AM
Cr, Mo, W
Chair: HATANAKA, Tsubasa
(09:00-10:00)
* 8:50-9:00: interval for laptop PC connection.(1A8-01, 1A8-02, 1A8-03, 1A8-04, 1A8-05)
1A8-01
Efficient catalytic asymmetric Henry reaction by self-assembly Cr(III)-salen complex (Grad. Sch. Chem. Sci. Technol., TUS) º KOGA, Toshihiko; IMAHORI, Tatsushi
1A8-02#
Synthesis and Structure of a Complex Having an Mo-Ge Triple Bond (Grad. Sch. Sci., Tohoku Univ.) º DHUNGANA, Tara Prasad; HASHIMOTO, Hisako; TOBITA, Hiromi
1A8-03
Substituent Effect on Catalytic Nitrogen Fixation via Cleavage of Triple Bond of Nitrogen Molecule (Grad. Sch. Eng., The Univ. of Tokyo) º ITABASHI, Takayuki; ARASHIBA, Kazuya; EIZAWA, Aya; NAKAJIMA, Kazunari; NISHIBAYASHI, Yoshiaki
1A8-04
Vinylidene Rearrangement and Sulfinate Elimination from Sulfonylalkynes in a Molybdenum Complex (Grad. Sch. Sci. Eng., Chuo Univ.) º SAKAJIRI, Kousuke; KUWABARA, Takuya; KODAMA, Shintaro; ISHII, Youichi
1A8-05*#
Reactions of a Tungsten Silylyne Complex with Alkynes: Formation of Silametallacyclobutadienes via [2+2] Cycloaddition (Grad. Sch. Sci., Tohoku Univ.) º YOSHIMOTO, Takashi; HASHIMOTO, Hisako; HAYAKAWA, Naoki; MATSUO, Tsukasa; TOBITA, Hiromi
W, Fe
Chair: MURAOKA, Takako
(10:10-11:00)
* 10:00-10:10: interval for laptop PC connection.(1A8-08, 1A8-09, 1A8-10, 1A8-11, 1A8-12)
1A8-08
Formation of Peculiar Cationic Germylenes from the Reactions of a Cationic Germylyne Complex with Terminal Alkynes (Grad. Sch. Sci., Tohoku Univ.) º MIYAZAKI, Yoshikazu; WATANABE, Takahito; TOBITA, Hiromi
1A8-09
Oxidation of water using ferrocenium cation under visible light irradiation (Grad. Sch. Eng., The Univ. of Tokyo) º TANABE, Yoshiaki; NAKAJIMA, Kazunari; NISHIBAYASHI, Yoshiaki
1A8-10
Synthesis and Reactions of Iron Complexes of 1,1’-bis(arylamide)vanadocenes (Grad. Sch. Sci., Osaka Univ.; Sch. Sci., Tokyo Tech.) º KUSUNOSE, Hinano; HATANAKA, Tsubasa; KAWAGUCHI, Hiroyuki; FUNAHASHI, Yasuhiro
1A8-11
Synthesis and Reactions of Fe and Co Complexes with Terphenyldiamide Ligands (Grad. Sch. Sci., Osaka Univ.) º YAMADA, Yuka; HATANAKA, Tsubasa; FUNAHASHI, Yasuhiro
1A8-12
Synthesis and Reactions of Fe complexes with P,N,O-tridentate Schiff bases (Grad. Sch. Sci., Osaka Univ.) º KONYA, Natsumi; HATANAKA, Tsubasa; FUNAHASHI, Yasuhiro
Fe, P
Chair: HASHIMOTO, Hisako
(11:10-12:00)
* 11:00-11:10: interval for laptop PC connection.(1A8-14, 1A8-15, 1A8-16, 1A8-17, 1A8-18)
1A8-14
Construction and reactivity of coordinatively unsaturated 3d metal complexes bearing Organosilyl ligands (Grad. Sch. Eng., The Univ. of Tokyo) º ARATA, Shogo; SUNADA, Yusuke
1A8-15
Reactions of Dichlorogallyliron Complexes with Dimethyl Disulfide (Sch. Sci. Tech., Gunma Univ.) º OHTANI, Aoi; MURAOKA, Takako; UENO, Keiji
1A8-16
ron complexes with PNNP ligand: Siloxane bond formation reaction by dehydrogenative coupling reaction (Div. of Chem., Fac. Pure Appl. Sci., Univ. of Tsukuba; IRC3, AIST) º TAKESHITA, Tomoihro; SATO, Kazuhiko; NAKAJIMA, Yumiko
1A8-17
Synthesis of tetraphosphine compounds by an iron complex catalyzing double hydrophosphination reaction and their reactivities (Grad. Sch. Sci., Osaka City Univ.) NOCHIDA, Tomoya; º ITAZAKI, Masumi; NAKAZAWA, Hiroshi
1A8-18
Convenient synthesis of phosphinecarboxamide (Fac. Sci., Osaka City Univ.) ITAZAKI, Masumi; º MATUTANI, Takanari; NOCHIDA, Tomoya; NAKAZAWA, Hiroshi
Tuesday, March 20, PM
Al
Chair: NAKATA, Norio
(13:10-14:00)
* 13:00-13:10: interval for laptop PC connection.(1A8-26, 1A8-27, 1A8-28, 1A8-29)
1A8-26
Synthesis of Group 13 Metal-Pheox Complexes for a Lewis Acid-Lewis Base Catalyst (Grad. Sch. Eng., Osaka Univ.) NISHIMOTO, Yoshihiro; º TAKAKURA, Taro; YASUDA, Makoto
1A8-27#
Synthesis and Characterization of Pheox- and Phebox-Al Complexes and Its Application to the Coupling Reaction of β-Alkoxyenones with Silyl Enolates (Grad. Sch. Eng., Osaka Univ.) º NAKAO, Shuichi; NISHIMOTO, Yoshihiro; YASUDA, Makoto
1A8-28#
Copolymerization of Cyclohexene Oxide and Carbon Dioxide Catalyzed by Bifunctional Aluminum Porphyrin Complexes (Fac. Eng., The Univ. of Tokyo) MAEDA, Chihiro; TOKUDA, Hideki; EMA, Tadashi; º DENG, Jingyuan; NOZAKI, Kyoko
1A8-29*
Asymmetric conjugate cyanation of α,β-unsaturated imides by a self-assembly Al-salen catalyst (Fac. Eng., TUS) º KITAHARA, Yusuke; SUGIYAMA, Hirotaka; IMAHORI, Tatsushi
Co, Rh
Chair: IWASAKI, Takanori
(14:10-15:10)
* 14:00-14:10: interval for laptop PC connection.(1A8-32, 1A8-33, 1A8-34, 1A8-35, 1A8-36)
1A8-32
Efficient asymmetric hydrolytic ring-opening reaction of meso-epoxide by self-assembly Co-salen catalyst (Grad. Sch. Chem. Sci. Technol., TUS) º KOYAMA, Kenta; IMAHORI, Tatsushi
1A8-33
Cobalt(II)-Catalyzed Intermolecular Coupling Reaction of Alkyne with Pinacolborane (Fac. Sci., Fukuoka Univ.) º OKI, Yukari; KOGA, Yuji; MATSUBARA, Kouki
1A8-34
Silyl-bridged dicobalt complexes formed by the reaction of a NHC-cobalt dialkyl complex with hydrosilanes (Interdisciplinary Research Center for Catalytic Chemistry) º ISHIZAKA, Yusuke; NAKAJIMA, Yumiko
1A8-35
Self-Assembly Salen Complexes utilizing Charge-Transfer Complexes (Grad. Sch. Eng., TUS) º TSUNOGAYA, Kosuke; IMAHORI, Tatsushi
1A8-36*#
Organometallic Approaches to Optimization of Rhodium Catalysts for Efficient Parahydrogen-Induced Polarization (Grad. Sch. Eng., The Univ. of Tokyo; IRC3, AIST) º NAGANAWA, Yuki; ITODA, Marino; NONAKA, Hiroshi; SANDO, Shinsuke
Rh, Ir
Chair: KAYAKI, Yoshihito
(15:20-16:20)
* 15:10-15:20: interval for laptop PC connection.(1A8-39, 1A8-40, 1A8-41, 1A8-42, 1A8-43, 1A8-44)
1A8-39#
Dehydrogenation of dimethylamine-borane catalyzed by half-sandwich Ir and Rh complexes: Mechanism and the role of Cp* non-innocence (Grad. Sch. Eng., The Univ. of Tokyo) PAL, Shrinwantu; º KUSUMOTO, Shuhei; NOZAKI, Kyoko
1A8-40
Synthesis and structures of anionic diaryliridium complexes (Grad. Sch. Eng., Osaka Univ.) º AKAIWA, Toshikazu; IWASAKI, Takanori; KAMBE, Nobuaki
1A8-41
Photocatalytic CO2 reduction using an iridium complex with PNNP-type tetradentate ligand (Grad. Sch. Sci., Nagoya Univ.; Toyota Central R&D Labs., Inc.) º KAMADA, Kenji; MURAKI, Manami; JUNG, Jieun; SEKIZAWA, Keita; SATO, Shunsuke; MORIKAWA, Takeshi; FUKUZUMI, Shunichi; NOYORI, Ryoji; SAUTO, Susumu
1A8-42
Synthesis of Iridium Hydride Complex Supported by an Electro-rich Metallodiphosphine Ligand and Its Use in Catalytic E-Selective Semi-Hydrogenation of Alkynes (Grad. Sch. Sci., Osaka Pref. Univ.) º KITAMURA, Manami; TAKEMOTO, Shin; MATSUZAKA, Hiroyuki
1A8-43
Synthesis and reactivity of light-sensitizing trinuclear iridium polyhydride complexes ligated by diphosphines having fluorene moiety (Grad. Sch. Sci. Eng., TMU) º SHITAYA, Shoji; NOMURA, Kotohiro; INAGAKI, Akiko
1A8-44
Reaction of a Side-on-type Silanethione-coordinated Iridium Complex with Elemental Sulfur: Characterization of the Sulfur Insertion Products (Grad. Sch. Sci. Tech., Hirosaki Univ.) º OHTANI, Ryusuke; OHTA, Shun; OKAZAKI, Masaaki
Ir, Ni
Chair: OOHASHI, Masato
(16:30-17:30)
* 16:20-16:30: interval for laptop PC connection.(1A8-46, 1A8-47, 1A8-48, 1A8-49, 1A8-50, 1A8-51)
1A8-46
Synthesis and Reactivity of Iridium Complexes Having Silyl(2,2'-Bipyridine) Pincer Ligands (Grad. Sch. Sci., Tohoku Univ.) º MOCHIZUKI, Daiki; KOMURO, Takashi; TOBITA, Hiromi
1A8-47#
Studies on Catalysis of Dinuclear Iridium Complexes with Bridging 1,4-Butadienyl Ligand (Grad. Sch. Eng., Kyoto Univ.) º SASAKURA, Kohei; OKAMOTO, Kazuhiro; OHE, Kouichi
1A8-48
Straightforward Synthesis of Tethered N-sulfonyldiamine-Ir Complexes via Condensation of a Cp Ligand Having a Hydroxyl Alkyl Chain (Sch. Mater. & Chem. Tech., Tokyo Tech.) º NAKAMURA, Hitomi; MATSUNAMI, Asuka; KUWATA, Shigeki; KAYAKI, Yoshihito
1A8-49
Ni/Co-Catalyzed C(sp3)-C(sp3) Cross-Coupling Using Alkyl Tosylates as Radical Sources (Grad. Sch. Eng., Hiroshima Univ.) º MICHIYUKI, Takuya; OSAKA, Itaru; KOMEYAMA, Kimihiro
1A8-50
Nickel/Cobalt-Catalyzed Methylation of Organo Halides (Grad. Sch. Eng., Hiroshima Univ.) º YAMAHATA, Yuta; OSAKA, Itaru; KOMEYAMA, Kimihiro
1A8-51
Synthesis and Reactivity of Nickel-Aryne Complexes Bearing 2,3-Thiophyne Fragment (Grad. Sch. Eng., Osaka Univ.) º TERADA, Misaki; NISHII, Yuji; MIURA, Masahiro
Ni
Chair: OKAMOTO, Kazuhiro
(17:40-18:30)
* 17:30-17:40: interval for laptop PC connection.(1A8-53, 1A8-55, 1A8-56, 1A8-57)
1A8-53*#
Ni(0)-catalyzed multi-component coupling reactions of tetrafluoroethylene with unsaturated compounds (Grad. Sch. Eng., Osaka Univ.) º KAWASHIMA, Takuya; OHASHI, Masato; OGOSHI, Sensuke
1A8-55
Catalytic Si−F σ-Bond Activation by Nickel Complex (Grad. Sch. Sci., Osaka Pref. Univ.) º ISASA, Tomohito; KAMEO, Hajime; MATSUZAKA, Hiroyuki
1A8-56
Ni/Cu-catalyzed selective monoalkylation of chlorosilanes (IRC3, AIST) º BEPPU, Teruo; MATSUMOTO, Kazuhiro; SATO, Kazuhiko; NAKAJIMA, Yumiko
1A8-57
Nickel-Catalyzed Transformation of Propargylic Alcohol Derivatives into 2-Aryloxy-1,3-dienes (Grad. Sch. Eng., Kyoto Univ.) º HORI, Yusaku; OKUMURA, Shintaro; ISHIDA, Naoki; MURAKAMI, Masahiro
Wednesday, March 21, AM
Ag, Au
Chair: NAGANAWA, Yuki
(09:00-09:40)
* 8:50-9:00: interval for laptop PC connection.(2A8-01, 2A8-02, 2A8-03, 2A8-04)
2A8-01
Silver-Catalyzed Synthesis of 3-Sulfonyl Coumarin Derivatives From N-Sulfonyl Amino Acids (Sch. Advanced Sci. Eng., Waseda Univ.) º HAMADA, Daisuke; MAKINO, Sohei; KANYIVA, Kyalo Stephen; SHIBATA, Takanori
2A8-02
Facile Synthesis of Pyrroloindoline Derivatives Using Silver-Catalyzed α-Aminoalkylation as Key Step (Sch. Advanced Sci. Eng., Waseda Univ.) º KANYIVA, Kyalo Stephen; MAKINO, Sohei; SHIBATA, Takanori
2A8-03
[2+2] cycloaddition reaction of metallacyclic vinyl-gold complex (Fac. Sci., Shizuoka Univ.) º TANAKA, Yosuke; NISHINA, Naoko
2A8-04
Gold-Catalyzed Cyclization at the C5-Position of Isoxazoles (Lab. Chem. Life Sci., Tokyo Tech.) º FUKUHARA, Shintaro; MORITA, Taiki; FUSE, Shinichiro; NAKAMURA, Hiroyuki
Wednesday, March 21, PM
B, Si
Chair: KAWACHI, Atsushi
(12:30-13:20)
* 12:20-12:30: interval for laptop PC connection.(2A8-22, 2A8-23, 2A8-24, 2A8-25)
2A8-22
Synthesis, structure and reactivity of bromo(borapyramidane) (IRC3, AIST) º SEO, Yuto; LEE, Vladidimir Ya.; FUKAYA, Norihisa; CHOI, Junchul
2A8-23
Valence Isomerization of a Tetrasila-1,3-diene (Grad. Sch. Sci., Tohoku Univ.) º FUJIEDA, Kentaro; AKASAKA, Naohiko; IWAMOTO, Takeaki
2A8-24
Synthesis and Functionalization of a Novel Cyclic Disilene (Grad. Sch. Sci., Tohoku Univ.) º TANAKA, Kaho; AKASAKA, Naohiko; ISHIDA, Shintarou; IWAMOTO, Takeaki
2A8-25*#
Synthesis, Structure, and Reactivity of a Series of Disilenes Bearing Amino and Boryl Groups (Grad. Sch. Sci., Tohoku Univ.) º KOSAI, Tomoyuki; IWAMOTO, Takeaki
Si
Chair: IWAMOTO, Takeaki
(13:30-14:30)
* 13:20-13:30: interval for laptop PC connection.(2A8-28, 2A8-29, 2A8-30, 2A8-31, 2A8-32, 2A8-33)
2A8-28
Synthesis of o-(Silyl)(boryl)benzenes with Less Sterically Hindered Aryl Groups (Grad. Sch. Sci., Eng., Hosei. Univ.) º SHIMIZU, Tomomi; KAWACHI, Atsushi
2A8-29
Synthesis of Huge Silicon Clusters by the Reduction of Tetrachlorocyclooligosilane (Grad. Sch. Sci. Tech., Gunma Univ.; Grad. Sch. Sci., Osaka Pref. Univ.) º MORIKAWA, Yusuke; TSURUSAKI, Akihiro; KYUSHIN, Soichiro
2A8-30
Synthesis of Polyhydrooligosilanes by the Reduction of 1,2-Dichloro-1,2-dihydrodisilanes (Grad. Sch. Sci. Tech., Gunma Univ.) º TSUDA, Shunsuke; KYUSHIN, Soichiro
2A8-31
Synthesis and Liquid Crystalline Properties of Oligosilanes Bearing Polar End Groups (Grad. Sch. Sci. Tech., Gunma Univ.; Takasaki Advanced Radiation Research Institute) º SEKIZAWA, Takuya; KYUSHIN, Soichiro; YOSHIMURA, Kimio; MAEKAWA, Yasunari
2A8-32
Formation of Dianions of Ladder Oligosilanes (Grad. Sch. Sci. Tech., Gunma Univ.; Sagami Chemical Research Institute) º NOMURA, Ryunosuke; UETA, Yoshinori; TANAKA, Ryoji; KYUSHIN, Soichiro; MATSUMOTO, Hideyuki
2A8-33
Synthesis and Characterization of NHC-Coordinated Hydrosilylenes Bearing a Bulky Eind Group (Grad. Sch. Sci. Eng., Kindai Univ.) º SADAMORI, Kazuya; HAYAKAWA, Naoki; MATSUO, Tsukasa
Chair: KANNO, Ken-ichiro
(14:40-15:40)
* 14:30-14:40: interval for laptop PC connection.(2A8-35, 2A8-36, 2A8-37, 2A8-38, 2A8-39, 2A8-40)
2A8-35
Synthetic Study of Silanes with Bulky Aryl Substituents (Grad. Sch. Sci., Tohoku Univ.) º HONDA, Shunya; SASAKI, Shigeru; IWAMOTO, Takeaki
2A8-36
Synthesis and redox properties of a disilene bearing triarylamine moieties (Grad. Sch. Sci., Tohoku Univ.) º KARAKIDA, Takuro; SASAKI, Shigeru; IWAMOTO, Takeaki
2A8-37
Synthesis of Properties of a Highly-Distorted Disilene (Grad. Sch. Sci., Tohoku Univ.) º NUKAZAWA, Takumi; ISHIDA, Shintaro; IWAMOTO, Takeaki
2A8-38
Synthesis of Hexasilacyclohexane Derivatives Convertible Their Substituents (ICR, Kyoto Univ.) º YAMATO, Omatsu; YOSHIYUKI, Mizuhata; TOKITOH, Norihiro
2A8-39
Synthetic Studies of Novel Silabenzene with tert-Butyl Group at the 2-Position (ICR, Kyoto Univ.) º TSUJI, Shingo; MIZUHATA, Yoshiyuki; TOKITOH, Norihiro
2A8-40
Synthetic studies of 1-Silaazulene (ICR, Kyoto Univ.) º OSHIRO, Taku; MIZUHATA, Yoshiyuki; TOKITOH, Norihiro
Chair: MIZUHATA, Yoshiyuki
(15:50-16:40)
* 15:40-15:50: interval for laptop PC connection.(2A8-42, 2A8-43, 2A8-44, 2A8-45, 2A8-46)
2A8-42
Reactions of a Dialkyldisilyne with Dichlorophosphines (Grad. Sch. Sci., Tohoku Univ.) º SUGAWARA, Shohei; ISHIDA, Shintaro; IWAMOTO, Takeaki
2A8-43
Synthesis of Silyl- and Alkyl-substituted Disilene and its Reduction (Sch. Sci. Eng., Univ. of Tsukuba) º HIBI, Fuya; ICHINOHE, Masaaki
2A8-44
Generation of Silyl-substituted Silylene and Disilene by the Reation of Lithiosilacyclopropane Derivative with TipSiMeCl2 (Grad. Sch. Pure Appl. Sci., Univ. of Tsukuba) º KIKUCHI, Yui; SEKIGUCHI, Akira; ICHINOHE, Masaaki
2A8-45
Disproportionation Reactions of Various Dihydrodisilanes under Mild Conditions (Grad. Sch. Sci. Tech., Gunma Univ.) º SUZUKI, Yudai; KANNO, Ken-ichiro; KYUSHIN, Soichiro
2A8-46
Synthesis of 1,1,4,4-Tetrachlorotetrasilane as a Precursor of Silicon Clusters (Grad. Sch. Sci. Tech., Gunma Univ.) º OGURA, Hiromichi; KYUSHIN, Soichiro
Chair: ICHINOHE, Masaaki
(16:50-17:40)
* 16:40-16:50: interval for laptop PC connection.(2A8-48, 2A8-49, 2A8-50, 2A8-51, 2A8-52)
2A8-48
Synthesis and Structures of Various Bis(alkenyl)tetra- and hexasilanes via Ruthenium-Catalyzed Hydrosilylation (Grad. Sch. Sci. Tech., Gunma Univ.) º KAJIMA, Keisuke; KANNO, Ken-ichiro; KYUSHIN, Soichiro
2A8-49
Properties of Octahalocyclotetrasilanes (Grad. Sch. Sci. Tech., Gunma Univ.) º KOBAYASHI, Yukihisa; KYUSHIN, Soichiro
2A8-50
Ruthenium-Catalyzed Hydrosilylation of 1,3-Dienes (Grad. Sch. Sci. Tech., Gunma Univ.) º NOGUCHI, Seiya; KANNO, Ken-ichiro; KYUSHIN, Soichiro
2A8-51
Ruthenium-Catalyzed Hydrosilylations Using Hydrodisilane and Alkynes Having Electron-Withdrawing Groups (Grad. Sch. Sci. Tech., Gunma Univ.) º KANNO, Ken-ichiro; ONO, Yukie; NOGUCHI, Seiya; KYUSHIN, Soichiro
2A8-52
Novel approach to synthesizing hexahydrosilaphenalene via intramolecular triple metathesis of tri(1-cyclobutenyl)silane (Fac. Sci., Shizuoka Univ.) º LEE, Junghun; SUGINO, Takumi; SAKAMOTO, Kenkichi
Thursday, March 22, AM
Si
Chair: IMOTO, Hiroaki
(09:00-10:00)
* 8:50-9:00: interval for laptop PC connection.(3A8-01, 3A8-02, 3A8-03, 3A8-04, 3A8-05, 3A8-06)
3A8-01
Silyl-substituents effects on the photopysical properties of Thieno[3,2-b]thiophene (Grad. Sch. Urban Environmental Sci., TMU) º HAYASHI, Daiki; INAGAKI, Yusuke; SETAKA, Wataru
3A8-02
Synthesis of a Bipyridylene-bridged Molecular Gyrotop and Formation of its Palladium Complex (Grad. Sch. Urban Environmental Sci., TMU) º ITO, Masaya; INAGAKI, Yusuke; YAMAGUCHI, Kentaro; SETAKA, Wataru
3A8-03
Selective synthesis of alkoxysilyl-substituted siloxanes by Cu-catalyzed coupling reaction of alkoxyhydrosilanes with silanols (IRC3, AIST) º SATOH, Yasushi; YAMAMOTO, Mie; SATO, Kazuhiko; IGARASHI, Masayasu
3A8-04
Synthesis, Structure and Reactivity of Orthosilicic Acid and Its Origomers (IRC3, AIST) º IGARASHI, Masayasu; MATSUMOTO, Tomohiro; YAGIHASHI, Fujio; SATO, Kazuhiko; SHIMADA, Shigeru
3A8-05
Synthesis,Structure and Reactivity of Cubic Octamer of Orthosilicic acid. (IRC3, AIST) º NOZAWA, Takeshi; MATSUMOTO, Tomohiro; YAGIHASHI, Fujio; BEPPU, Teruo; SATO, Kazuhiko; IGARASHI, Masayasu
3A8-06
Hydride Reduction of Alkoxysilanes using NaBH4 (IRC3, AIST) º AOYAGI, Keiya; MATSUMOTO, Kazuhiro; SATO, Kazuhiko; NAKAJIMA, Yumiko
Ge
Chair: SAITO, Masaichi
(10:10-11:10)
* 10:00-10:10: interval for laptop PC connection.(3A8-08, 3A8-09, 3A8-10, 3A8-11, 3A8-12, 3A8-13)
3A8-08
Toward Polycyclic Aromatic Hydrocarbons of Heavier Group 14 Element Analogues of the Aryl Anion (ICR, Kyoto Univ.) º FUJIMORI, Shiori; MIZUHATA, Yoshiyuki; TOKITOH, Norihiro
3A8-09
Synthesis and Structure of Germanate Complex Having Phenanthrenedialkoxido Ligands (Fac. Eng., Tottori Univ.) º YONEDA, Tomoka; NANJO, Masato
3A8-10
Synthesis, Structure, and Properties of Chlorogermylenes Having an N-P and an N-O Bidentate Ligands (Fac. Sci., Gakushuin Univ.) º INOMATA, Koya; YABUKI, Shunsaku; MOCHIDA, Kunio
3A8-11
Synthesis and Characterization of Unsaturated Bond Species of Heavier Group 14 Elements with Bulky MPind Groups (Fac. Sci. Eng., Kindai Univ.) º OHNO, Ryoma; MAGAMI, Kosuke; KONAKA, Shigeaki; NUMATA, Yasuyuki; HAYAKAWA, Naoki; MATSUO, Tsukasa
3A8-12
Synthesis and Properties of π-Conjugated Digermene Compounds Bearing the Bulky Rind Groups (Fac. Sci. Eng., Kindai Univ.) º HAYAKAWA, Naoki; NUMATA, Yasuyuki; KAWAAI, Hotaka; YAMATANI, Kenta; HASHIZUME, Daisuke; MATSUO, Tsukasa
3A8-13
Synthesis and Structures of Divalent Species of Heavier Group 14 Elements with Bulky Carboxylate Ligands (Grad. Sch. Sci. Eng., Kindai Univ.) º YAMASHITA, Ryota; MIYAMOTO, Yu; NISHITANI, Nobuhisa; HAYAKAWA, Naoki; MATSUO, Tsukasa
Ge, Sn, Pb
Chair: NANJO, Masato
(11:20-12:10)
* 11:10-11:20: interval for laptop PC connection.(3A8-15, 3A8-16, 3A8-17, 3A8-18, 3A8-19)
3A8-15
Synthesis and Reactivity of Tetragermacyclobutadiene (Grad. Sch. Sci. Eng., Kindai Univ.) º NUMATA, Yasuyuki; HAYAKAWA, Naoki; MATSUO, Tsukasa
3A8-16
Investigation on Reactivity of a Zero-Valent Tin Complex Stabilized by a Butadiene Ligand (Grad. Sch. Sci., Eng., Saitama Univ.) º KOBAYASHI, Shinya; FURUKAWA, Shunsuke; SAITO, Masaichi
3A8-17
Reactivity of chlorostannylene stabilized by iminophosphonamide ligand (Fac. Sci., Saitama Univ.) º NAKAYA, Kazuki; TAKAHASHI, Shintaro; NAKATA, Norio; ISHII, Akihiko
3A8-18
Synthesis of tin-linked molecular bevel gears and observation of gear slippage (Grad. Sch. Urban Environmental Sci., TMU) º HOSONO, Satoshi; INAGAKI, Yusuke; YAMAGUCHI, Kentaro; SETAKA, Wataru
3A8-19
Synthesis and Reactivity of a Series of Diarylplumbylenes Bearing the Bulky Rind groups (Fac. Sci. Eng., Kindai Univ.) º KONAKA, Shigeaki; HAYAKAWA, Naoki; MATSUO, Tsukasa
Thursday, March 22, PM
Cu
Chair: SAKAMOTO, Ryu
(13:20-14:20)
* 13:10-13:20: interval for laptop PC connection.(3A8-27, 3A8-29, 3A8-30, 3A8-31, 3A8-32)
3A8-27*#
Copper(I)-Catalyzed Stereodivergent Hydrodefluorination of gem-Difluoroalkenes (Grad. Sch. Chem. Sci. and Eng., Hokkaido Univ.) º KOJIMA, Ryoto; KUBOTA, Koji; ITO, Hajime
3A8-29
Copper(I)-Catalyzed Stereoselective Defluoroborylation of Aliphatic gem-Difluoroalkenes (Grad. Sch. Chem. Sci. and Eng., Hokkaido Univ.) º SEO, Tamae; KOJIMA, Ryoto; ITO, Hajime
3A8-30
Copper(I)-Catalyzed Enantioselective Borylation of (E)-Allyltrifluorides via β-Fluoroelimination (Grad. Sch. Eng., Hokkaido Univ.) º AKIYAMA, Sota; KOJIMA, Ryoto; ITO, Hajime
3A8-31
Cu-catalyzed selective alkoxyalkylation of styrenes (Grad. Sch. Sci. Tech., Yamaguchi Univ.) º MURATA, Yumi; NISHIKATA, Takashi
3A8-32
Copper-catalyzed cyanation of tert-alkyl bromides (Grad. Sch. Sci. Tech., Yamaguchi Univ.) º ISHIDA, Syo; NISHIKATA, Takashi
Chair: NISHIKATA, Takashi
(14:30-15:20)
* 14:20-14:30: interval for laptop PC connection.(3A8-34, 3A8-35, 3A8-36, 3A8-37, 3A8-38)
3A8-34
Copper Catalyzed Asymmetric Borylation of Aliphatic Ketones and Ketimines (Grad. Sch. Chem. Sci. and Eng., Hokkaido Univ.) º OSAKI, Shun; KUBOTA, Koji; ITO, Hajime
3A8-35
Unusual Temperature Dependence of Enantioselectivity in the Asymmetric Ring Opening Reaction of Meso-epoxide Catalyzed by Homochiral MOF (Fac. Chem. Materials and Bioeng., Kansai Univ.) º NAKAJI, Kazusada; TANAKA, Kouichi
3A8-36
Development of Mono-N-alkylation of Primary Amides and Arylamines using Alkylsilyl Peroxides (Dep. Chem., Sch. Sci., Kyoto Univ.) º SAKURAI, Shunya; SAKAMOTO, Ryu; MARUOKA, Keiji
3A8-37
New Synthetic Method of Organoboron Compounds using Alkylsilyl Peroxides (Dep. Chem., Sch. Sci., Kyoto Univ.) º SEIHARA, Takumi; SAKAMOTO, Ryu; MARUOKA, Keiji
3A8-38
Development of Copper-catalyzed Alkylation of Terminal Alkynes using Alkylsilyl Peroxides via a Radical Mechanism (Dep. Chem., Sch. Sci., Kyoto Univ.) º KATO, Terumasa; SAKAMOTO, Ryu; MARUOKA, Keiji
Pd
Chair: WAKIOKA, Masayuki
(15:30-16:30)
* 15:20-15:30: interval for laptop PC connection.(3A8-40, 3A8-41, 3A8-42, 3A8-43, 3A8-44, 3A8-45)
3A8-40
Construction of group 10 transition metal clusters via insertion into Si-Si bonds (Grad. Sch. Eng., The Univ. of Tokyo; IIS, The Univ. of Tokyo) º SHIMAMOTO, Kento; SUNADA, Yusuke
3A8-41
Oxygenation of a Benzyl Ligand on Palladium Promoted by Secondary Phosphine Oxides (Fac. Sci., Nara Women's Univ.) º OKA, Sayaka; KATAOKA, Yasutaka; URA, Yasuyuki
3A8-42
Palladium-mediated stoichiometric anti-Markovnikov addition of an N-H bond of 2-pyridones to an alkenylphosphine (Fac. Sci., Nara Women's Univ.) º SATO, Ruriko; KATAOKA, Yasutaka; URA, Yasuyuki
3A8-43
Synthesis of 4-membered ring compounds using oxocyclobutenyl complex (Grad. Sch. Eng., Saitama Inst. of Tech.) º AZAMI, Hidekazu; IWASAKI, Masakazu
3A8-44
Cis/trans Isomerization Reaction of Methylpalladium Complexes Bearing a Partially Saturated IzQO Ligand (Grad. Sch. Eng., The Univ. of Tokyo) º AKITA, Shumpei; NAKANO, Ryo; ITO, Shingo; NOZAKI, Kyoko
3A8-45
Role of Ag salt in dehydrogenative cross coupling reaction (TREMS, Univ. of Tsukuba) º SHIMOYAMA, Yuto; KUWABARA, Junpei; KANBARA, Takaki
Chair: URA, Yasuyuki
(16:40-17:40)
* 16:30-16:40: interval for laptop PC connection.(3A8-47, 3A8-49, 3A8-51, 3A8-52)
3A8-47*
Diastereoselective Michael reaction catalyzed by pyridinebisamide-palladium (Sch. Mater. & Chem. Tech., Tokyo Tech.) º NAMBU, Yoko; TAKATA, Toshikazu
3A8-49*#
Syntheses of Substituted 1,4-Disila-2,5-cyclohexadienes from Cyclic Hexasilane Si6Me12 and Alkynes via Successive Si-Si Bond Activa-tion by Pd / Isocyanide Systems. (IMCE, Kyushu Univ.) º TAHARA, Atsushi; NAGINO, Shunsuke; SUNADA, Yusuke; HAIGE, Ryohei; NAGSHIMA, Hideo
3A8-51#
Synthesis of Poly(3-hexylthiophene) via Highly Selective Direct Arylation Polymerization: Control of Molecular Weight and End Groups (ICR, Kyoto Univ.) º XU, Kai; WAKIOKA, Masayuki; OZAWA, Fumiyuki
3A8-52
Stille Cross Coupling of α-(Trifluoromethyl) benzyl Chlorides with Allylstannanes (Fac. Eng. Nagoya Inst. of Tech.) PUNNA, Nagender; º HARADA, Kyosuke; TOKUNAGA, Etsuko; SHIBATA, Norio
Pd, Pt
Chair: KUWABARA, Junpei
(17:50-18:40)
* 17:40-17:50: interval for laptop PC connection.(3A8-54, 3A8-55, 3A8-56, 3A8-57, 3A8-58)
3A8-54
Mechanistic Insight into Dehydrogenative Arene Coupling of Dimethyl Phthalate: A Study of Palladium Complexes Catalyst by Liquid Phase XAFS (Grad. Sch. Fac. Eng., Tokyo Univ. of Agri. and Technol.; Grad. Sch. Eng. Sci., Osaka Univ.; ICR, Kyoto Univ.) º SANO, Kosuke; KOMINE, Nobuyuki; MITSUDOME, Takato; TAKAYA, Hikaru; HIRANO, Masafumi
3A8-55
Synthesis and Dynamic Behavior of Hydrido(dihydrosilyl)platinum(II) Complex Having Trimethyl Phosphine Ligands (Grad. Sch. Sci., Eng., Saitama Univ.) º AOYAMA, Motoo; KATO, Nanami; NAKATA, Norio; ISHII, Akihiko
3A8-56
Synthesis and Reactivity of Platinum Complexes Having a Group 14 Element-Containing Pincer Type Ligand (Sch. Sci., Tokyo Tech.) º NAKAYA, Ryota; TAKAYA, Jun; IWASAWA, Nobuharu
3A8-57
Macrocyclic Pt-complex having NCN pincer-type ligand: synthesis, structure and catalytic activity (Sch. Mater. & Chem. Tech., Tokyo Tech.) º HIGUCHI, Kazuki; YAMAMOTO, Koji; SOGAWA, Hiromitsu; TAKATA, Toshikazu
3A8-58
Oligomerization of Trimethylsilanol by Platinum Catalyst (Grad. Sch. Sci., Hiroshima Univ.) º TSUMURA, Daisuke; KUBO, Kazuyuki; KUME, Shouko; MIZUTA, Tsutomu
Friday, March 23, AM
Ce, Ti, Cr, Sm
Chair: ISHIDA, Yutaka
(09:00-10:00)
* 8:50-9:00: interval for laptop PC connection.(4A8-01, 4A8-02, 4A8-03, 4A8-04, 4A8-05, 4A8-06)
4A8-01
Mechanism for Alternative Copolymerization of Carbon Dioxide and Epoxide Catalyzed by Macrocycle Zn3Ln Cluster Complexes (Graduate School of Engineering Science, Osaka University) º AOKI, Ryota; NAGAE, Haruki; AKUTAGAWA, Shin-nosuke; SPANIOL, Thomas P.; OKUDA, Jun
4A8-02
Telomerization on Alternating Copolymerization of Cyclohexene Oxide with Carbon Dioxide Catalyzed by Macrocycle LnZn3 Cluster Complexes (Sch. Eng. Sci., Osaka Univ.) º AKUTAGAWA, Shin-nosuke; AOKI, Ryota; NAGAE, Haruki; SPANIOL, Thomas P.; TSURUGI, Hayato; OKUDA, Jun; MASHIMA, Kazushi
4A8-03
Synthesis of Titanium Pyrrolylaluminate Complexes and Their Catalytic Activity for α-Olefin Polymerization (Sch. Eng. Sci., Osaka Univ.) º HATO, Wataru; ANGA, Srinivas; TSURUGI, Hayato; MASHIMA, Kazushi
4A8-04#
C-N and C-C Bonds Cleavage of Substituted Pyridines by a Trinuclear Ti Hydride Complex (RIKEN CSRS) º HU, Shaowei; SHIMA, Takanori; HOU, Zhaomin
4A8-05
Dinitrogen Activation by a Dinuclear Chromium Hydride Complex (RIKEN CSRS) º SHIMA, Takanori; HOU, Zhaomin
4A8-06#
Cooperative Trimerization of Carbon Monoxide by Samarium and Lithium Boryls (Organometallic Chem. Lab. RIKEN) º WANG, Baoli; LUO, Gen; NISHIURA, Masayoshi; HOU, Zhaomin
Ce, Hf, Y, Ti
Chair: SHIMA, Takanori
(10:10-11:00)
* 10:00-10:10: interval for laptop PC connection.(4A8-08, 4A8-09, 4A8-10, 4A8-12)
4A8-08
Synthesis and reactivity of trivalent cerium complexes with N,N''-diaryldiethylenetriamine ligands (Grad. Sch. Eng. Sci., Osaka Univ.) º SHINOHARA, Koichi; TSURUGI, Hayato; MASHIMA, Kazushi
4A8-09
Preparation of Cationic Dinuclear Benzylhafnium Complexes with a Bidentate (2-Amido)ethoxide Ligand (Grad. Sch. Eng. Sci., Osaka Univ.) º INOUE, Mariko; TSURUGI, Hayato; MASHIMA, Kazushi
4A8-10*#
Direct Ortho-C-H Bond Aminoalkylation of Pyridine Derivatives Catalyzed by Amidoyttrium Complexes (Grad. Sch. Eng. Sci., Osaka Univ.) º TSURUGI, Hayato; KUNDU, Abhinanda; INOUE, Mariko; TSUJIMOTO, Nagataka; NAGAE, Haruki; MASHIMA, Kazushi
4A8-12
Synthesis and Structures of Group 4 Transition Metal Alkyl Complexes with Bulky Monodentate Aryloxide Ligands (Grad. Sch. Sci. Eng., Kindai Univ.) º WATAUCHI, Toshiki; KANAZAWA, Shoya; SUZUKI, Nobuhisa; MATSUO, Tsukasa
Ti, Ta, V
Chair: OHTA, Shun
(11:10-12:00)
* 11:00-11:10: interval for laptop PC connection.(4A8-14, 4A8-16, 4A8-17, 4A8-18)
4A8-14*
Activation and Olefination of Methane by Metal-Carbon Multiple Bonds (UPenn) º KUROGI, Takashi; BAIK, Mu-hyun; MINDIOLA, Daniel
4A8-16
Synthesis and Reactions of Naphthalene and Anthracene Complexes of Titanium (Grad. Sch. Sci., Eng., Tokyo Tech.) º NAKANISHI, Yusuke; ISHIDA, Yutaka; KAWAGUCHI, Hiroyuki
4A8-17#
Transformation of Metallacyclopentadiene to Metallacyclopropene on Bimetallic Ditantalum Scaffold (Grad. Sch. Eng. Sci., Osaka Univ.) º ANGA, Srinivas; LASKAR, Payel; YAMAMOTO, Keishi; TSURUGI, Hayato; MASHIMA, Kazushi
4A8-18
Preparation and Reactivity of Groups 4 and 5 Transition Metal Complexes Bearing PNP-Type Pincer Ligands Based on Pyrrole Skeleton (Grad. Sch. Eng., The Univ. of Tokyo) º SEKIGUCHI, Yoshiya; NAKAJIMA, Kazunari; NISHIBAYASHI, Yoshiaki
Friday, March 23, PM
Ru
Chair: INAGAKI, Akiko
(13:10-14:10)
* 13:00-13:10: interval for laptop PC connection.(4A8-26, 4A8-27, 4A8-29, 4A8-30)
4A8-26
Characterization and Reactivity of CpRu Chloride Complexes Obtained from Cationic CpRu η6-Naphthalene Complex and Chloride Ion (Grad. Sch. Sci., Osaka Pref. Univ.) º ISHII, Hana; TERAMOTO, Akira; TAKEMOTO, Shin; MATSUZAKA, Hiroyuki
4A8-27*#
Ru(0)-Catalyzed Direct Synthesis of Conjugated Trienes and Tetraenes by Coupling of Conjugated Dienes with Internal Alkynes (Grad. Sch. Fac. Eng., Tokyo Univ. of Agri. and Technol.) º KIYOTA, Sayori; IN, Seonyoung; KOMINE, Nobuyuki; HIRANO, Masafumi
4A8-29
Synthesis and Proto-desilylation of Silyl-substituted Conjugated Trienes Prepared by Direct Coupling of Conjugated Dienes with Silylalkynes (Grad. Sch. Fac. Eng., Tokyo Univ. of Agri. and Technol.) SAITO, Ryo; KIYOTA, Sayori; KOMINE, Nobuyuki; º HIRANO, Masafumi
4A8-30*#
Ruthenium-catalyzed Synthesis of Acrylic Acid from Ethylene and CO2 (Sch. Sci., Tokyo Tech.) º ITO, Tatsuyoshi; TAKAHASHI, Kohei; IWASAWA, Nobuharu
Chair: TAKEMOTO, Shin
(14:20-15:20)
* 14:10-14:20: interval for laptop PC connection.(4A8-33, 4A8-34, 4A8-35, 4A8-36, 4A8-37, 4A8-38)
4A8-33
Vinylidene Rearrangement of S-Substituted Internal Alkynes in a Ruthenium Complex (Grad. Sch. Sci. Eng., Chuo Univ.) º TAKAMORI, Shuhei; SAKAJIRI, Kosuke; DEGUCHI, Kazuki; KODAMA, Shintaro; KUWABARA, Takuya; ISHII, Youichi
4A8-34
Synthesis of a Ruthenium Vinlylidene Complex from an Alkynylphosphonates and its Pseudo-polymorphism (Grad. Sch. Sci. Eng., Chuo Univ.) DEGUCHI, Kazuki; SAKAJIRI, Kousuke; TAKAMORI, Shuhei; º KUWABARA, Takuya; KODAMA, Shintaro; TAKANO, Keiko; HOUJOU, Hirohiko; ISHII, Youichi
4A8-35
Synthesis of Phosphaphenalene Derivatives via P-C Reductive Elimination and Their Fluorescence Properties (Grad. Sch. Sci. Eng., Chuo Univ.) º KATO, Takahiro; KUWABARA, Takuya; KODAMA, Shintaro; MINAMI, Yasunori; HIYAMA, Tamejiro; ISHII, Youichi
4A8-36#
Synthesis of Tethered Amine-Ru Complexes via Intramolecular Defluorination and Catalytic Application to Asymmetric Transfer Hydrogenation (Sch. Mater. & Chem. Tech., Tokyo Tech.; Coll. Sci. Eng., Aoyama Gakuin Univ.) º MATSUNAMI, Asuka; NAKAMURA, Hitomi; KUWATA, Shigeki; KAYAKI, Yoshihito
4A8-37
Reactions of β-Protic Ruthenium Complexes with Unsaturated Alcohols (Sch. Mater. & Chem. Tech., Tokyo Tech.) º TASHIMA, Naoto; KUWATA, Shigeki
4A8-38
Synthesis and Reactivities of Protic Bis(pyridylidene) Ruthenium Complexes (Sch. Mater. & Chem. Tech., Tokyo Tech.) º KURASHIMA, Kenta; SAWAZAKI, Taka; KAYAKI, Yoshihito; KUWATA, Shigeki
Chair: NAKAJIMA, Yumiko
(15:30-16:20)
* 15:20-15:30: interval for laptop PC connection.(4A8-40, 4A8-41, 4A8-42, 4A8-43, 4A8-44)
4A8-40
Reactivity of a Trinuclear Ruthenium Complex Capped a m3-Oxoboryl Ligand. (Sch. Mater. & Chem. Tech., Tokyo Tech.) º NINAGAWA, Hayato; TAKAO, Toshiro
4A8-41
Reactivity of diruthenium complexes having a dihydrobipyridyl ligand (Sch. Mater. & Chem. Tech., Tokyo Tech.) º NAGAE, Ryo; TAKAO, Toshiro
4A8-42
Structure and reactivity of the Ru4Ni decahydrido cluster (Sch. Mater. & Chem. Tech., Tokyo Tech.) º KOSUKEGAWA, Takuya; TAKAO, Toshiro
4A8-43
Synthesis, Structures, and Properties of Ruthenium Carbonyl Complexes Bearing Silyl(N-Heterocyclic Carbene) Chelate Ligands (Grad. Sch. Sci., Tohoku Univ.) º TAKAHASHI, Kasumi; KOMURO, Takashi; TOBITA, Hiromi
4A8-44
Synthesis and property of organometallic multinuclear molecular wires with diethynylthiophene bridges (Lab. Chem. Life Sci., Tokyo Tech.) º KATO, Yuya; TANAKA, Yuya; AKITA, Munetaka