Chishinkan3 Building 202
[Organic Chemistry -Reaction and Synthesis- Aliphatic and Alicyclic Compounds]
Thursday, March 24, AM
Chair: NAGASAWA, Kazuo
(09:30-10:30)
* 9:20-9:30: interval for laptop PC connection.(1H2-04, 1H2-06, 1H2-07, 1H2-08, 1H2-09)
1H2-04*
Asymmetric Net Cycloaddition Synthesis of 1,5-Benzothiazepines toward Library Construction (Grad. Sch. Eng., Kyoto Univ.) º FUKATA, Yukihiro; ASANO, Keisuke; MATSUBARA, Seijiro
1H2-06
Development of peptide catalysts through exploration and fine-tuning with large-scale peptide libraries (IIS, The Univ. of Tokyo) º SATOU, Junichi; AKAGAWA, Kengo; KUDO, Kazuaki
1H2-07
Development of Peptide Catalysts for Activating Substrates via Michael-Type Addition (IIS, The Univ. of Tokyo) º DU, Zhaonan; AKAGAWA, Kengo; KUDO, Kazuaki
1H2-08
Chiral amine-urea-mediated asymmetric 1,3-dipolar cycloaddition reactions of nitrile oxides with 2-hydroxystyrenes (Fac. Eng., Shinshu Univ.) º HASHIMOTO, Yohei; TODA, Yasunori; SUGA, Hiroyuki
1H2-09
Phosphonium salt-catalyzed carbon dioxide fixation at atmospheric pressure for the synthesis of cyclic carbonates (Fac. Eng., Shinshu Univ.) º KOMIYAMA, Yutaka; TODA, Yasunori; SUGA, Hiroyuki
Chair: ASANO, Keisuke
(10:40-11:40)
* 10:30-10:40: interval for laptop PC connection.(1H2-11, 1H2-13, 1H2-14, 1H2-15)
1H2-11*
Exploration of asymmetric reactions in water using water-insoluble chiral catalysts (Grad. Sch. Sci., The Univ. of Tokyo) º KITANOSONO, Taku; KOBAYASHI, Shu
1H2-13
Analytical Study of Diels-Alder Reactions under Heterogeneous Conditions Using a Real-time Reaction Monitoring Method with Mass Spectrometry (Grad. Sch. Sci., The Univ. of Tokyo) º MASUDA, Koichiro; KOBAYASHI, Shu
1H2-14
Development of oxidative kinetic resolution of β- and γ- disubstituted tetralone derivatives using guanidine-bisurea bifunctional organocatalyst (Fac. Eng., Tokyo Univ. of Agri. and Technol.) º HOSOYA, Keisuke; ODAGI, Minami; NAGASAWA, Kazuo
1H2-15*
Asymmetric fluorolactonization with a bifunctional hydroxyl carboxylate catalyst (Univ. of Shizuoka) º EGAMI, Hiromichi; ASADA, Junshi; SATO, Kentaro; HASHIZUME, Daisuke; KAWATO, Yuji; HAMASHIMA, Yoshitaka
Chair: NAGASAWA, Kazuo
(11:50-12:20)
* 11:40-11:50: interval for laptop PC connection.(1H2-18)
1H2-18 CSJ Award for Young Chemists
Development of Modular Chiral Ionic Ligands and Catalysts for Hitherto Difficult Catalytic Asymmetric Transformations (WPI-ITbM, Nagoya Univ.) º OHMATSU, Kohsuke
Thursday, March 24, PM
Chair: SUGA, Hiroyuki
(13:30-14:30)
* 13:20-13:30: interval for laptop PC connection.(1H2-28, 1H2-29, 1H2-30, 1H2-32, 1H2-33)
1H2-28
Development and Application of Catalytic Racemization of N-Unprotected Amino Esters (WPI-ITbM, Nagoya Univ.; Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º NAGATO, Yuya; OHMATSU, Kohsuke; OOI, Takashi
1H2-29
Extended Modularity of Ion-Paired Chiral Ligands for Pd-Catalyzed Asymmetric Allylations (WPI-ITbM, Nagoya Univ.; Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º KUSANO, Yuya; OHMATSU, Kohsuke; OOI, Takashi
1H2-30*
Multiple Absolute Stereocontrol in Pd-Catalyzed Asymmetric [3+2] Cycloadditions Using Chiral Onium-Phosphine Hybrid Ligand (WPI-ITbM, Nagoya Univ.; Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º IMAGAWA, Naomichi; OHMATSU, Kohsuke; OOI, Takashi
1H2-32
Enantioselective Diels-Alder Reaction Induced by Chiral Supramolecular Lewis Acid Catalysts Based on the Coordination Bond between the Cyano Moiety and Borane (Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º HAYASHI, Kazushi; SAKAMOTO, Tatsuhiro; MAKINO, Yuma; HATANO, Manabu; ISHIHARA, Kazuaki
1H2-33
Diastereo-, Enantio-, Regio-, Site-, and Substrate-Selective Diels-Alder Reaction Induced by Chiral Supramolecular Lewis Acid Catalysts (Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º SAKAMOTO, Tatsuhiro; HATANO, Manabu; ISHIHARA, Kazuaki
Chair: ASANO, Keisuke
(14:40-15:40)
* 14:30-14:40: interval for laptop PC connection.(1H2-35, 1H2-36, 1H2-37, 1H2-38, 1H2-39, 1H2-40)
1H2-35
Chiral phosphoric acid catalyzed asymmetric nucleophilic addition of trifluoromethylated ketimines (Fac. Sci., Gakushuin Univ.) º KIYOTA, Yuki; SAITO, Kodai; SUGA, Takuya; AKIYAMA, Takahiko
1H2-36
Kinetic Resolution of Secondary Alcohols through Intramolecular Transesterification Catalyzed by Chiral Bronsted Acid (Grad. Sch. Sci., Tohoku Univ.) º ITO, Shigetomo; OTA, Yusuke; KONDOH, Azusa; TERADA, Masahiro
1H2-37
Chiral Phosphinic Acid-Phosphoric Acid Catalyzed Enantioselective Hetero Diels-Alder Reaction of Aryl Glyoxal and Siloxydiene (Grad. Sch. Sci., Tohoku Univ.; LCCMS, IMS) º NARUMI, Tomohiro; MOMIYAMA, Norie; TERADA, Masahiro
1H2-38
Development of Carbon-Carbon Bond Forming Reactions Utilizing Homoenolate Equivalents Generated by [1,2]-Phospha-Brook Rearrangement (Grad. Sch. Sci., Tohoku Univ.) º AOKI, Takuma; KONDOH, Azusa; TERADA, Masahiro
1H2-39
Enantioselective Aza-Friedel-Crafts Reaction of alpha-Ketimino Esters with Furan Catalyzed by Chiral C2-Symmetric Binaphthyl-2,2’-bis(phosphate)s (Grad. Sch. Eng., Nagoya Univ.) º OKAMOTO, Haruka; HATANO, Manabu; ISHIHARA, Kazuaki
1H2-40
Enantioselective Aza-Friedel-Crafts Reaction of alpha-Ketimino Esters with Furan Catalyzed by Chiral C1-Symmetric Binaphthyl-2,2’-bis(phosphate)s (Grad. Sch. Eng., Nagoya Univ.) º KAWAKAMI, Taro; OKAMOTO, Haruka; HATANO, Manabu; ISHIHARA, Kazuaki
Chair: SUMII, Yuji
(15:50-16:50)
* 15:40-15:50: interval for laptop PC connection.(1H2-42, 1H2-44, 1H2-46, 1H2-47)
1H2-42*
Chiral Phosphoric Acid-Catalyzed Enantioselective Synthesis of 1,4-Dithiepanes from Ring-Expansion Reaction of 1,3-Dithiane Derivatives: Reaction and Mechanistic Insight (Grad. Sch. Sci., Tohoku Univ.; Grad. Sch. Eng., Iwate Univ.) º LI, Feng; KORENAGA, Toshinobu; TERADA, Masahiro
1H2-44*
Chiral Nucleophilic Amidophosphate-Catalyzed Enantioselective Iodocyclization (Grad. Sch. Eng., Nagoya Univ.) º LU, Yanhui; NAKATSUJI, Hidefumi; OKUMURA, Yukimasa; ISHIHARA, Kazuaki
1H2-46
Aryl Selenide-Iodine Cooperative Catalysts for Chlorocyclization of Tryptamine Derivatives (Grad. Sch. Eng., Nagoya Univ.) º OMURA, Shuhei; HORIBE, Takahiro; ISHIHARA, Kazuaki
1H2-47
Nucleophilic Calcogen Catalysts for Iodochlorination of Unactivated Alkenes (Grad. Sch. Eng., Nagoya Univ.) º TSUJI, Yasutaka; HORIBE, Takahiro; ISHIHARA, Kazuaki
Chair: OHMATSU, Kohsuke
(17:00-17:50)
* 16:50-17:00: interval for laptop PC connection.(1H2-49, 1H2-50, 1H2-51, 1H2-52, 1H2-53)
1H2-49
Enantioselective Formal [3+2]-Cycloaddition of β,γ-Epoxy Sulfones with Imines Catalyzed by Chiral Bronsted Base (Grad. Sch. Sci., Tohoku Univ.) º AKAHIRA, Shiori; OISHI, Masafumi; KONDOH, Azusa; TERADA, Masahiro
1H2-50
Asymmetric Decarboxylative Protonation of α-Halo-β-keto Esters with Organocatalyst (Toyohashi Univ. of Tech.) º SASAKI, Nozomi; SHIBATOMI, Kazutaka; IWASA, Seiji
1H2-51
Asymmetric synthesis of fluoroalkyl phthalides (Grad. Sch. Sci. Tech., Gunma Univ.) º SAKAI, Tatsuya; INABA, Masanori; SHIBATA, Norio; AMII, Hideki
1H2-52
Phosphine-catalyzed Anti-Carboboration of Alkynes with Organoboranes (Fac. Sci., Hokkaido Univ.) º YAMAZAKI, Ayaka; NAGAO, Kazunori; OHMIYA, Hirohisa; SAWAMURA, Masaya
1H2-53
Synthesis of 1,1-Diborylalkenes through a Brønsted Base-Catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron (Fac. Sci., Hokkaido Univ.) º MORINAGA, Akira; NAGAO, Kazunori; OHMIYA, Hirohisa; SAWAMURA, Masaya
Chair: AMII, Hideki
(18:00-18:40)
* 17:50-18:00: interval for laptop PC connection.(1H2-55, 1H2-56, 1H2-58)
1H2-55
N-Heterocyclic Carbene-Catalyzed Mono-Acylation of Vicinal Diols (Grad. Sch. Sci., Chiba Univ.) º KUWANO, Satoru; MASUDA, Toshinobu
1H2-56*
Enantioselective Acylation of Alcohols with Highly Active Chiral Nucleophilic Catalysts (Grad. Sch. Nat. Sci. Technol., Okayama Univ.) º FUJII, Kazuki; MANDAI, Hiroki; SUGA, Seiji
1H2-58
Desymmetrization of meso-1,2-diols with Highly Active Chiral Nucleophilic Catalysts (Grad. Sch. Nat. Sci. Technol., Okayama Univ.) º YASUHARA, Hiroshi; FUJII, Kazuki; MANDAI, Hiroki; SUGA, Seiji
Friday, March 25, AM
Chair: YAMANAKA, Masahiro
(09:00-10:00)
* 8:50-9:00: interval for laptop PC connection.(2H2-01, 2H2-02, 2H2-03, 2H2-04, 2H2-05, 2H2-06)
2H2-01
Design of Chiral Brønsted Acid Catalysts for Asymmetric Diels-Alder Reaction of Trisubstituted Nitroalkenes (Grad. Sch. Nat. Sci. Technol., Okayama Univ.) º FUJII, Yudai; KUDOH, Takayuki; SAKAKURA, Akira
2H2-02
Development of Intramolecular Dehydro Diels-Alder Reaction of Indolyl-1,6-diynes for the Synthesis of Substituted Carbazoles (Grad. Sch. Nat. Sci. Technol., Okayama Univ.) º FUJISAWA, Syo; KUDOH, Takayuki; SAKAKURA, Akira
2H2-03
Substituted trans-Cyclooctenes as Novel Organic Lewis Base Catalysts (Grad. Sch. Eng., Kyoto Univ.) º EINARU, Shunsuke; ASANO, Keisuke; MATSUBARA, Seijiro
2H2-04
Synthesis of Disubstituted trans-Cyclooctenes toward the Development of Novel Organic Lewis Base Catalysts (Grad. Sch. Eng., Kyoto Univ.) º SHITAMICHI, Kenta; EINARU, Shunsuke; ASANO, Keisuke; MATSUBARA, Seijiro
2H2-05
Asymmetric Synthesis of 1,3-Polyol Building Blocks by Chiral Phosphoric Acid Catalysts (Grad. Sch. Eng., Kyoto Univ.) º MATSUMOTO, Akira; ASANO, Keisuke; MATSUBARA, Seijiro
2H2-06
The Chiral Amine-Catalyzed Enantioselective Rauhut-Currier Reaction (ISIR, Osaka Univ.) º KISHI, Kenta; TAKIZAWA, Shinobu; ARTEAGA, Fernando; SASAI, Hiroaki
Chair: KUDOH, Takayuki
(10:10-11:10)
* 10:00-10:10: interval for laptop PC connection.(2H2-08, 2H2-09, 2H2-10, 2H2-11, 2H2-12, 2H2-13)
2H2-08
Exploration of Secondary Amine Organocatalyst Using Solid-Phase Catalysis/CD HTS for Asymmetric Mannich Reaction (Grad. Sch. Sci., Chiba Univ.) º INOUE, Takahiro; ARAI, Takayoshi
2H2-09
Synthesis of main-chain polymers having chiral imidazolidinone salt for asymmetric reaction using ionic bond(IX) (Toyohashi Univ. of Tech.) º TAKENAKA, Nagisa; HARAGUCHI, Naoki; ITSUNO, Shinichi
2H2-10
Synthesis of polymers containing sulfonamide type cinchona alkaloid and their application to asymmetric reaction (Dept. Env. Life Sci., Toyohashi Univ. of Tech.) º TAKATA, Shohei; HARAGUCHI, Naoki; ITSUNO, Shinichi
2H2-11
Synthesis of polymeric chiral ligands containing TsDPEN structure and their application to enantioselective catalysis (Toyohashi Univ. of Tech.) º TAKAHASHI, Shotaro; HARAGUCHI, Naoki; ITSUNO, Shinichi
2H2-12
Enantioselective Intramolecular Cyclization of Alkynyl Esters Catalyzed by Chiral Bronsted Base (Grad. Sch. Sci., Tohoku Univ.) º TRAN, Hoa Thi Quynh; KIMURA, Kyoko; KONDOH, Azusa; TERADA, Masahiro
2H2-13
Theoretical Study of Carboxylic Acid-Phosphoric Acid Catalyzed Asymmetric Hetero Diels-Alder Reaction (Grad. Sch. Sci., Rikkyo Univ.) º NODA, Hirofumi; TERADA, Masahiro; MOMIYAMA, Norie; YAMANAKA, Masahiro
Chair: ARAI, Takayoshi
(11:20-12:20)
* 11:10-11:20: interval for laptop PC connection.(2H2-15, 2H2-17, 2H2-18, 2H2-19, 2H2-20)
2H2-15*
Development of the First Non-enzymatic Dynamic Asymmetric Esterification of Racemic 2-(1H-Pyrrol-1-yl)alkanoic Acids Using MA-BTM Combined System (Fac. Sci., Tokyo Univ. of Sci.) º TOKUMARU, Eri; SHIINA, Isamu
2H2-17
Dynamic Asymmetric Esterification of Racemic 2-Indolylpropanoic Acids Using MA-BTM Combined System (Fac. Sci., Tokyo Univ. of Sci.) TOKUMARU, Eri; º SAITO, Takahiro; YOKOYAMA, Yuka; SHIINA, Isamu
2H2-18
Kinetic Resolution of Racemic Gentisyl Alcohol Derivatives Using Asymmetric Esterification (Fac. Sci., Tokyo Univ. of Sci.) SHIINA, Isamu; º ISHIKAWA, Ryo; NAKATA, Kenya
2H2-19
Asymmetric Synthesis of Fused Piperidine Derivatives by the Internal Redox Process (Fac. Sci., Gakushuin Univ.) º ISOGAI, Ryo; MORI, Keiji; AKIYAMA, Takahiko
2H2-20
Phosphine-Catalyzed Acylcyanation of Alkynoates (Fac. Sci., Hokkaido Univ.) º MURAYAMA, Hiroaki; NAGAO, Kazunori; OHMIYA, Hirohisa; SAWAMURA, Masaya
Friday, March 25, PM
Chair: HARAGUCHI, Naoki
(13:30-14:30)
* 13:20-13:30: interval for laptop PC connection.(2H2-28, 2H2-30, 2H2-31, 2H2-33)
2H2-28*
Boron Tribromide-assisted Chiral Phosphoric Acid Catalysts for Enantioselective Diels-Alder Reaction toward Alkaloid Synthesis (Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º GOTO, Yuta; HATANO, Manabu; ISHIHARA, Kazuaki
2H2-30
Remote Boron Lewis Acid-Assisted Chiral Phosphoric Acid Catalysts for Enantioselective Diels-Alder Reaction (Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º ISHIHARA, Hideyuki; HATANO, Manabu; ISHIHARA, Kazuaki
2H2-31*
Diastereodivergent Catalysis of Chiral Aminophosphonium Salts for Highly Regio- and Stereoselective 1,6-Additions (WPI-ITbM, Nagoya Univ.; Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º YOSHIOKA, Ken; URAGUCHI, Daisuke; OOI, Takashi
2H2-33
Stereoselective Mannich-type Reaction of Oxindoles under the Catalysis of Chiral Ammonium Betaines (WPI-ITbM, Nagoya Univ.; Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º KATO, Kohsuke; TORII, Masahiro; URAGUCHI, Daisuke; OOI, Takashi
Chair: KOIKE, Takashi
(14:40-15:40)
* 14:30-14:40: interval for laptop PC connection.(2H2-35, 2H2-36, 2H2-37, 2H2-38, 2H2-39, 2H2-40)
2H2-35
Novel Boronic Acid-catalyzed Amide Condensation Reaction (Grad. Sch. Eng., Nagoya Univ.) º WANG, Ke; LU, Yanhui; ISHIHARA, Kazuaki
2H2-36
Secondary Amine-Boronic Acid Cooperative Catalysis for [4 + 2] Dehydrative Cycloaddition of α,β,γ,δ-Unsaturated Carboxylic Acids with Ketones (Grad. Sch. Eng., Nagoya Univ.) º NAKATA, Yuto; LU, Yanhui; HORIBE, Takahiro; ISHIHARA, Kazuaki
2H2-37
Photoinduced perfluoroalkylation of aldehydes via enamines (Grad. Sch. Of Humanities and Sci., Ochanomizu Univ.) º MATSUI, Haruna; YAJIMA, Tomoko
2H2-38
Site-Selective C-H to C-C Conversion by Radicals: A Dual Approach Based on Polar and Steric Effect (Grad. Sch. Sci., Osaka Pref. Univ.) º YAMADA, Keiichi; FUKUYAMA, Takahide; RYU, Ilhyong
2H2-39
Photocatalyzed C-H Arylation of Alkanes with Heterocycles (Fac. Sci., Osaka Pref. Univ.) º FUJII, Saki; YAMADA, Keiichi; FUKUYAMA, Takahide; RYU, Ilhyong
2H2-40
Reductive Difluoromethylation of Unsaturated Hydrocarbons by Photoredox Catalyst (Grad. Sch. Sci., Osaka Pref. Univ.; Daikin Industries, Ltd.) SUMINO, Shuhei; º UNO, Misae; FUKUYAMA, Takahide; RYU, Ilhyong; MATSUURA, Makoto; YAMAMOTO, Akinori; KISHIKAWA, Yosuke
Chair: SASAI, Hiroaki
(15:50-16:50)
* 15:40-15:50: interval for laptop PC connection.(2H2-42, 2H2-44, 2H2-46)
2H2-42*
Photocatalytic C-N Bond Formation at Room Temperature (Grad. Sch. Sci., Nagoya Univ.; RCMS, Nagoya Univ.) º MORIOKA, Yuna; WANG, Lyuming; TSAREV, Vasily; CANER, Joaquim; WANG, Qing; USHIMARU, Richiro; KUDO, Akihiko; NOYORI, Ryoji; NAKA, Hiroshi; SAITO, Susumu
2H2-44*
Photo-radical Trifluoromethylation catalyzed by Trifluoroethoxy-coated subphthalocyanine (Fac. Eng. Nagoya Inst. of Tech.) º MATSUZAKI, Kohei; HIROMURA, Tomoya; TOKUNAGA, Etsuko; SHIBATA, Norio
2H2-46*
Regioselective photocatalytic transfer hydrogenolysis of allylic alcohols (Grad. Sch. Sci., Nagoya Univ.) º TAKADA, Yuki; CANER, Joaquim; NAKA, Hiroshi; NOYORI, Ryoji; SAITO, Susumu
Chair: MIYAKE, Yoshihiro
(17:00-17:50)
* 16:50-17:00: interval for laptop PC connection.(2H2-49, 2H2-50, 2H2-51, 2H2-53)
2H2-49
Synthesis of CF3-containing Spiroethers by Photoredox Catalysis (Chem. Res. Lab., Tokyo Tech) º NOTO, Naoki; KOIKE, Takashi; AKITA, Munetaka
2H2-50
Oxy-Trifluoromethylation of Allenes by Photoredox Catalysis (Chem. Res. Lab., Tokyo Tech) º TOMITA, Ren; KOIKE, Takashi; AKITA, Munetaka
2H2-51*
Organic Dye Catalyzed α-Allylation of α-Halo Carbonyl Compounds under Visible Light Irradiation (Grad. Sch. Eng., Osaka Univ.) º ESUMI, Naoto; SUZUKI, Itaru; YASUDA, Makoto
2H2-53
Design of Flavin-Amine Integrated Catalysts for Photoredox Reactions (Fac. Eng., Tokushima Univ.) º TAGAMI, Takuma; ARAKAWA, Yukihiro; MINAGAWA, Keiji; IMADA, Yasushi
Chair: YAJIMA, Tomoko
(18:00-18:40)
* 17:50-18:00: interval for laptop PC connection.(2H2-55, 2H2-56, 2H2-58)
2H2-55
DFT Study of BINOL-phosphoryl-boronate Catalyzed 1,4-Reduction of α, β-Unsaturated Ketone. (Grad. Sch. Sci., Rikkyo Univ.) º YAMAMOTO, Eri; YAMANA, Masahiro
2H2-56*
Highly Enantioselective Steglich Rearrangement with Poly(quinoxaline-2,3-diyl)-based Helically Chiral DMAP Derivatives (Grad. Sch. Eng., Kyoto Univ.) º MURAKAMI, Ryo; YAMAMOTO, Takeshi; SUGINOME, Michinori
2H2-58
Photoinduced C(sp3)-H azidation for installation of nitrogen functionalities to carbon skeletones (Grad. Sch. Sci. Eng., Yamaguchi Univ.) º WATANABE, Mizuki; KAMIJO, Kaori; TAO, Keisuke; MURAFUJI, Toshihiro; KAMIJO, Shin
Saturday, March 26, AM
Chair: SHIBATOMI, Kazutaka
(09:00-10:00)
* 8:50-9:00: interval for laptop PC connection.(3H2-01, 3H2-02, 3H2-03, 3H2-04, 3H2-06)
3H2-01
Development of Oxidative Dearomatization Reaction Using Hypochlorite Salt Catalysts (Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º SAHARA, Naoto; UYANIK, Muhammet; ISHIHARA, Kazuaki
3H2-02
Hypoiodite-Catalyzed Oxidative α-Azidation of Carbonyl Compounds (Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º HATTORI, Yuhei; TSUKAHARA, Mayuko; UYANIK, Muhammet; ISHIHARA, Kazuaki
3H2-03
Catalytic α-Chlorination of Carbonyl Compounds with Sodium Hypochlorite Pentahydrate (Grad. Sch. Eng., Nagoya Univ.) º NAKASHIMA, Fumio; UYANIK, Muhammet; ISHIHARA, Kazuaki; KUWAHATA, Mitsuyoshi; EJIMA, Yasukazu
3H2-04*
A Chiral Selenium Catalyst for Highly Enantioselective Oxidative Cyclization (Dep. Chem., Sch. Sci., Kyoto Univ.) º KAWAMATA, Yu; HASHIMOTO, Takuya; MARUOKA, Keiji
3H2-06
One-Pot Metal-Free Transformation of Ethylarenes into Aromatic Primary Amides via C-C Bond Cleavage (Grad. Sch. Sci., Chiba Univ.) º SHIMOKAWA, Shohei; MORIYAMA, Katsuhiko; TOGO, Hideo
Chair: URAGUCHI, Daisuke
(10:10-11:10)
* 10:00-10:10: interval for laptop PC connection.(3H2-08, 3H2-09, 3H2-10, 3H2-12, 3H2-13)
3H2-08
Oxidative Dual-Functionalization of Ethers via Aerobic Oxidation of Bromide Ion (Fac. Sci., Chiba Univ.) º HAMADA, Tsukasa; MORIYAMA, Katsuhiko; TOGO, Hideo
3H2-09
I2-Catalyzed Vicinal Diamination of Olefins Utilizing Chloramine-Ns (Grad. Sch. Eng., Osaka Univ.) º HIRAYAMA, Arata; MIWA, Hayato; MINAKATA, Satoshi
3H2-10*
Chiral Hypoiodite-Catalyzed Enantioselective Oxidative Cyclization and Mechanistic Study (Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º HAYASHI, Hiroki; SUZUKI, Daisuke; UYANIK, Muhammet; ISHIHARA, Kazuaki
3H2-12
Chiral Hypoiodite-Catalyzed Enantioselective Oxidative Dearomatization of Indole Derivatives (Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º UKEGAWA, Naoya; UYANIK, Muhammet; ISHIHARA, Kazuaki
3H2-13
Chiral Hypoiodite-Catalyzed Enantioselective Oxidative Cycloetherification (Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º IWATA, Hirokazu; HAYASHI, Hiroki; UYANIK, Muhammet; ISHIHARA, Kazuaki
Chair: UYANIK, Muhammet
(11:20-12:20)
* 11:10-11:20: interval for laptop PC connection.(3H2-15, 3H2-16, 3H2-17, 3H2-18, 3H2-19, 3H2-20)
3H2-15
GlycolCleavage Using Sodium Hypochlorite Catalyzed by Iodobenzene (Fac. Sci. Tech., SIST; Fac. Sci. Tech., SIST) MATSUSHIMA, Ryoji; OSUGI, Rie; SEKIYAMA, Hideo; º KIRIHARA, Masayuki
3H2-16
Electrophilic Bromination Using Sodium Hypochlorite Pentahydrate and Sodium Bromide (Fac. Sci. Tech., SIST) º AKIYAMA, Tomomi; SUZUKI, Risa; KINOSHITA, Yukari; KIRIHARA, Masayuki
3H2-17
Fluorinative Ring-Cleavage of Cyclopropylmethanols (Fac. Sci. Tech., SIST) º MURAMATSU, Yukari; KIKKAWA, You; KITAGAWA, Saori; KIRIHARA, Masayuki
3H2-18
Nitroxyl Radical-Catalyzed Six-membered Ring Bromolactonization of Alkenyl Carboxylic Acids (Grad. Sch. Sci., Chiba Univ.) º KURAMOCHI, Masako; MORIYAMA, Katsuhiko; TOGO, Hideo
3H2-19
Aerobic Oxidation of Sulfides Catalized by N5-unsubstituted neutral flavins (Fac. Eng., Tokushima Univ.) º YAMANOMOTO, Ken; ARAKAWA, Yukihiro; MINAGAWA, Keiji; IMADA, Yasushi
3H2-20
Ritter-Type Amination of C-H Bonds at Tertiary Carbon Centers Using Iodic Acid and N-Hydroxyphthalimide (Grad. Sch. Eng., Osaka Univ.) º TAKEMOTO, Kenta; ITO, Ryo; KIYOKAWA, Kensuke; MINAKATA, Satoshi
Saturday, March 26, PM
Chair: MORIYAMA, Katsuhiko
(13:30-14:30)
* 13:20-13:30: interval for laptop PC connection.(3H2-28, 3H2-29, 3H2-30, 3H2-31, 3H2-32, 3H2-33)
3H2-28
N-Sulfonyl α-Iminoester-derived Chiral Oxaziridines: Catalytic Asymmetric Synthesis and Application as a Chiral Oxidant (WPI-ITbM, Nagoya Univ.; Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º NAOYA, Tanaka; URAGUCHI, Daisuke; OOI, Takashi
3H2-29
Development of Catalytic Asymmetric Glycolate Aldol Reaction Based on Umpolung Reactivity of Enediol Intermediate (WPI-ITbM, Nagoya Univ.; Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º YAMADA, Kohei; URAGUCHI, Daisuke; OOI, Takashi
3H2-30
Regio-, Stereo-, and Enantioselective 1,6-Addition to Conjugated Enynyl N-Acylpyrazoles (WPI-ITbM, Nagoya Univ.; Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º SHIBAZAKI, Ryo; URAGUCHI, Daisuke; OOI, Takashi
3H2-31
Theoretical Study on Guganidine-Bisthiourea Bifunctional Organocatalysts in Asymmetric Friedel-Crafts Reaction (Coll. Sci., Rikkyo Univ.) º NAKANO, Katsuhiro; ODAGI, Minami; NAGASAWA, Kazuo; YAMANAKA, Masahiro
3H2-32
Synthetic studies of gracilamine using asymmetric aza-Friedel-Crafts reaction in the presence of guanidine-bisthiourea bifunctional organocatalyst (Grad. Sch. Fac. Eng., Tokyo Univ. of Agri. and Technol.) º YAMAMOTO, Yoshiharu; ODAGI, Minami; NAKANO, Kazuhiro; YAMANAKA, Masahiro; NAGASAWA, Kazuo
3H2-33
Organocatalytic decarboxylative halogenation of β-keto carboxylic acids (Dept. Env. Life Sci., Toyohashi Univ. of Tech.) º SHIBATOMI, Kazutaka; KAWASAKI, Yohei; SASAKI, Nozomi; IWASA, Seiji
Sunday, March 27, AM
Chair: MOMIYAMA, Norie
(09:00-10:00)
* 8:50-9:00: interval for laptop PC connection.(4H2-01, 4H2-02, 4H2-03, 4H2-05, 4H2-06)
4H2-01
Enantioselective Synthesis of Hexahydrochromenones through Simultaneous Construction of Three Chiral Centers (Grad. Sch. Eng., Kyoto Univ.) º FUJII, Yuki; ASANO, Keisuke; MATSUBARA, Seijiro
4H2-02
Asymmetric Synthesis of 2,2,4,6-Tetrasubstituted Tetrahydropyrans by Bifunctional Organocatalysts (Grad. Sch. Eng., Kyoto Univ.) º NASU, Teruhisa; FUJII, Yuki; ASANO, Keisuke; MATSUBARA, Seijiro
4H2-03*
Enantioselective Synthesis of Axially Chiral Hetero-biaryls by Bifunctional Organocatalysts (Grad. Sch. Eng., Kyoto Univ.) º MIYAJI, Ryota; ASANO, Keisuke; MATSUBARA, Seijiro
4H2-05
Chiral Hypervalent Iodine(III)-Catalyzed Enantioselective Oxidative Dearomatization of 1,4-Hydroquinone Derivatives (Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º MIZUNO, Masahiro; UYANIK, Muhammet; ISHIHARA, Kazuaki
4H2-06
Chiral Hypervalent Iodine(III)-catalyzed Oxidative Kinetic Resolution of Biaryl Hydroxy Carboxylic Acids (Grad. Sch. Eng., Nagoya Univ.) º SAEDA, Kirara; UYANIK, Muhammet; ISHIHARA, Kazuaki
Chair: MORI, Atsunori
(10:10-11:10)
* 10:00-10:10: interval for laptop PC connection.(4H2-08, 4H2-09, 4H2-10, 4H2-11, 4H2-13)
4H2-08
Electrophilic Cyanation of Enol Silyl Ethers Catalyzed by Boron Lewis Acid Using Hypervalent Iodine Reagent (Grad. Sch. Eng., Osaka Univ.) º MATSUBARA, Hiroki; NAGATA, Takaya; KIYOKAWA, Kensuke; MINAKATA, Satoshi
4H2-09
Direct oxidation of 1,1'-bi-2-naphthol derivatives at the 8 and/or 8' positions (Dept.of Chem. Eng., Nara National College of Technology) º MASUI, Yu; KISHIMOTO, Kouki; SHIBAJI, Kouki; KAMEI, Toshiyuki; SHIMADA, Toyoshi
4H2-10
Synthesis of β-Ketonitriles by Electrophilic Cyanation of Boron Enolates (Grad. Sch. Eng., Osaka Univ.) º NAGATA, Takaya; WATANABE, Tomoki; KIYOKAWA, Kensuke; MINAKATA, Satoshi
4H2-11*
IBS-Catalyzed Regioselective Oxidation of Phenols and Its Synthetic Application (Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º MUTSUGA, Tatsuya; UYANIK, Muhammet; ISHIHARA, Kazuaki
4H2-13
Oxidative Generation of ortho-Quinone Methides and Application to Tandem Reactions (Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º NISHIOKA, Kohei; UYANIK, Muhammet; ISHIHARA, Kazuaki
Chair: KAMEI, Toshiyuki
(11:20-12:20)
* 11:10-11:20: interval for laptop PC connection.(4H2-15, 4H2-16, 4H2-18, 4H2-19, 4H2-20)
4H2-15
C-H bond functionalization at 1-position of tetrahydroisoquinoline derivatives with azodicarboxylate as an oxidant (Fac. Sci., Gakushuin Univ.) º IIZUKA, Sunao; SUGA, Takuya; AKIYAMA, Takahiko
4H2-16*
Chiral Brønsted acid catalyzed enantioselective reaction of enamide with azlactone or thiazolone (Grad. Sch. Sci., Tohoku Univ.; LCCMS, IMS) º KIKUCHI, Jun; MOMIYAMA, Norie; TERADA, Masahiro
4H2-18
Chiral Phosphoric Acid Catalyzed Enantiodivergent Synthesis of Chiral Biaryls based on Transfer Hydrogenation (Fac. Sci., Gakushuin Univ.) º ITAKURA, Tsubasa; MORI, Keiji; AKIAMA, Takahiko
4H2-19
Construction of Quaternary Stereogenic Center via Intramolecular SN2' Reaction using Chiral Bronsted Acid Catalyst (Grad. Sch. Sci., Tohoku Univ.) º SHIMIZU, Masahiro; KONDOH, Azusa; TERADA, Masahiro
4H2-20
Brønsted Acid Catalyzed Aerobic Hydrogenation of Olefins by In Situ Generated Diimide (Fac. Eng., Tokushima Univ.) º KOHDA, Takahiro; ARAKAWA, Yukihiro; MINAGAWA, Keiji; IMADA, Yasushi
Sunday, March 27, PM
Chair: NOKAMI, Toshiki
(13:30-14:30)
* 13:20-13:30: interval for laptop PC connection.(4H2-28, 4H2-29, 4H2-30, 4H2-31, 4H2-32, 4H2-33)
4H2-28
Development of Hydration Reactions in Water with New Photo-Harvesting Catalysts (Grad. Sch. Sci., The Univ. of Tokyo) º XU, Pengyu; KITANOSONO, Taku; KOBAYASHI, Shu
4H2-29
Chiral Palladium(II)-Catalyzed Asymmetric 1,4-Addition Reactions of Indoles in Water. (Grad. Sch. Sci., The Univ. of Tokyo) º MIYO, Masumi; KITANOSONO, Taku; KOBAYASHI, Shu
4H2-30
Synthesis and Application of Immobilized Chiral 2,2'-Bipyridine Ligands (Grad. Sch. Sci., The Univ. of Tokyo) º ZHU, Lei; KITANOSONO, Taku; KOBAYASHI, Shu
4H2-31
Oxidation of secondary alcohols using a photo-exited ketone (Grad. Sch. Sci. Eng., Yamaguchi Univ.) º TAKAO, Go; TAO, Keisuke; MURAFUJI, Toshihiro; KAMIJO, Shin
4H2-32
New Methodology for Construction of trans-Fused Skeletons by means of Photochemically Promoted Coupling Reaction between Acylsilanes and Boronates (Fac. Sci., Gakushuin Univ.) º SHIMIZU, Tsukasa; ISHIDA, Kento; KUSAMA, Hiroyuki
4H2-33
Zinc Iodide(II)-Catalyzed Intermolecular Coupling of Acylsilanes with Aldehydes under Photoirradiation Conditions (Fac. Sci., Gakushuin Univ.) º TOBITA, Fumiya; ISHIDA, Kento; KUSAMA, Hiroyuki
Chair: ISHIDA, Kento
(14:40-15:40)
* 14:30-14:40: interval for laptop PC connection.(4H2-35, 4H2-36, 4H2-37, 4H2-38, 4H2-39, 4H2-40)
4H2-35
Trityl Halides / Thioureas: A Convenient Source for Trityl Cation-Catalyzed Intramolecular Carbonyl-Ene Cyclization and [2+2]-Cycloaddition (Fac. Sci., Kochi Univ.) º HORINOUCHI, Ryo; NOMOTO, Yuya; NISHIYAMA, Nobuo; KOTSUKI, Hiyoshizo
4H2-36
Synthesis of fluorinated cycloalkenes via radical ring opening reaction of gem-difluorocyclopropane and subsequent RCM reaction (Grad. Sch. Eng., Tottori Univ.) º MASUHARA, Yoshihiro; NOKAMI, Toshiki; ITOH, Toshiyuki
4H2-37
Synthesis of mono-fluorocycloalkenes via SN2' type allylation or vinylation of gem-difluoroalkenes and subsequent RCM reaction (Fac. Eng., Tottori Univ.) º TANAKA, Toshiki; MASUHARA, Yoshihiro; ITOH, Toshiyuki; NOKAMI, Toshiki
4H2-38
Reductive Decyanation Reactions of Marononitriles Using TTMSS (Grad. Sch. Med., Yamaguchi Univ.) º SHIMAYA, Yudai; KAWAMOTO, Takuji; KAMIMURA, Akio
4H2-39
Synthetic application of the redox type isomerization of γ-trifluoromethylated allylic alcohols (Grad. Sch. Fac. Eng., Tokyo Univ. of Agri. and Technol.) º HAMADA, Yoko; YAMAZAKI, Takashi; TAKASUKA, Tomoko
4H2-40
Radical Reductive Decyanation of Aliphatic Nitriles Using Borohydride (Grad. Sch. Med., Yamaguchi Univ.) º ORITANI, Kyohei; KAWAMOTO, Takuji; KAMIMURA, Akio
Chair: KITANOSONO, Taku
(15:50-16:20)
* 15:40-15:50: interval for laptop PC connection.(4H2-42, 4H2-43, 4H2-44)
4H2-42
Radical Trifluoromethylation Using Vinyl Triflates (Grad. Sch. Med., Yamaguchi Univ.) º SASAKI, Rio; KAWAMOTO, Takuji; KAMIMURA, Akio
4H2-43
Visible photoinduced iodoperfluoroalkylation of terminal alkene and alkyne using organic dyes as photoredox catalysts (Grad. Sch. Of Humanities and Sci., Ochanomizu Univ.) º IKEGAMI, Mako; YAJIMA, Tomoko
4H2-44
Peroxydisulphate Mediated C-C bond Formation via Single Electron Oxidation of Alkenes (Grad. Sch. Sci., Osaka Pref. Univ.) º NAKAKOJI, Daiki; UEDA, Mitsuhiro; RYU, Ilhyong