The 96th Annual Meeting of The Chemical Society of Japan

Date: March 24th - 27th, 2016

Venue: Doshisha University, Kyoto, Japan

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Room F5

Chishinkan3 Building 105

[Physical Organic Chemistry Reaction Mechanism]

Friday, March 25, AM

Chair: MATSUI, Yasunori (10:00-11:00)

* 9:50-10:00: interval for laptop PC connection.(2F5-07, 2F5-08, 2F5-09, 2F5-11)

Neighboring Fluorine Substituent Effect on the Stability of (Aryl)(1,4-diphenyl-1H-1,2,3-triazol-5-yl)carbene (Grad. Sch. Eng., Mie Univ.; Community-University Research Cooperation Center, Mie Univ.) º SAKANE, Kenta; HIRAI, Katsuyuki; KITAGAWA, Toshikazu

Incorporation of di(9-anthryl)diazomethane, a precursor of the most persistent triplet carbene, into mesoporous silica and characterization of carbene generated by its photolysis. (Grad. Sch. Eng., Mie Univ.; Community-University Research Cooperation Center, Mie Univ.) º JINPO, Takashi; HIRAI, Katsuyuki; KITAGAWA, Toshikazu

Dihydroxylation of alkenes by sodium chlorite with scandium triflate (Grad. Sch. Eng., Osaka Univ.; Graduate School of Science and Technology; Acenet Inc.) º OHKUBO, Kei; HIROSE, Kensaku; SHIBATA, Takekatsu; TAKAMORI, Kiyoto; FUKUZUMI, Shunichi

Effects of 3-Amkino Substituent on the Photoinduced Bond Cleavage of 2-Benzyloxy-Naphthalene (Fac. Sci., Niigata Univ.) º USUI, Satoshi; KUNIMINE, Takuya; MUROHASHI, Takahiro; SUZUKI, Takahiro

Chair: FUJITA, Morifumi (11:10-12:10)

* 11:00-11:10: interval for laptop PC connection.(2F5-14, 2F5-16, 2F5-17, 2F5-18)

Spin-state Effect on Stereoselectivity in Photochemical Denitrogenation of Azoalkanes (Grad. Sch. Sci., Hiroshima Univ.) º ABE, Manabu; MIZUNO, Takemi

Direct oxygenation of benzene to phenol by oxygen using dihydroacridine derivatives as an electron source (Grad. Sch. Eng., Osaka Univ.; Faculty of Science and Technology; ALCA, SENTAN, JST) º HIROSE, Kensaku; OHKUBO, Kei; FUKUZUMI, Shunichi

Nitrogen atom effect on the reactivity of localized singlet diradicals (Fac. Sci., Hiroshima Univ.) º YOSHIDOMI, Shohei; ABE, Manabu

Mechanism for Generation of Phenonium Ion-Containing Salts in Single-Electron Transfer-Oxidation Reaction of Cage Compounds (Grad. Sch. Eng., Osaka Pref. Univ.; The Research Inst. for Molecular Electronic Devices, Osaka Pref. Univ.) º KURAMOTO, Yutaro; MATSUI, Yasunori; OHTA, Eisuke; IKEDA, Hiroshi

Friday, March 25, PM

Chair: OHKUBO, Kei (13:30-14:30)

* 13:20-13:30: interval for laptop PC connection.(2F5-28, 2F5-30, 2F5-31, 2F5-32, 2F5-33)

Novel transient absorption technique, RIPT method, and simultaneous measurements of transient absorption and luminescence of metal complexes with intense luminescence (UNISOKU Co., Ltd.; Grad. Sch. Eng., Osaka Univ.; Faculty of Science and Technology; SENTAN, JST) º NAKAGAWA, Tatsuo; SUENOBU, Tomoyoshi; OKAMOTO, Kido; HANADA, Hiroaki; FUKUZUMI, Shunichi

Reactivity of Diradicals in Macrocyclic Ring System (Grad. Sch. Sci., Hiroshima Univ.) º ONISHI, Keita; HATANO, Sayaka; ABE, Manabu

Cyclic structure effect on the reactivity of cyclopentane-1,3-diyl diradicals (Grad. Sch. Sci., Hiroshima Univ.) º HARADA, Yuta; ABE, Manabu

Reactions of Arenepolydiazonium Ions in Imidazolium-Based Ionic Liquid (Grad. Sch. Eng., Mie Univ.) º ENOMOTO, Yoshihito; NAKAGAWA, Nana; OKAZAKI, Takao; KITAGAWA, Toshikazu

Synthesis and Solvatochromism of 4-[2-(1-Methylpyridinium-4-yl)ethynyl]phenolate Derivatives (Fac. Eng., Mie Univ.) º NONOGAKI, Marine; OKZAKI, Takao; KITAGAWA, Toshikazu

Chair: KANENO, Daisuke (14:40-15:20)

* 14:30-14:40: interval for laptop PC connection.(2F5-35, 2F5-36, 2F5-38)

Free energy landscape and Cis-Trans isomerization reaction rate of azobenzenes : weak solute-solvent coupling cases (Ind. Tech. Ctr. Nagasaki; Grad. Sch. Eng., Nagasaki Univ.) º SHIGEMITSU, Yasuhiro; OHGA, Yasushi

Theoretical stydy of non-TST behavior for caged compounds. (Dept. Eng. Edu. Center, Chiba Inst. of Tech.) º SHUHEI, Itoh

Dynamic path bifurcation of the vinyl-type rearrangement/cyclization/fragmentation reaction of the vinyl diazonium ion derivatives (Coll. Sci., Rikkyo Univ.) º SATO, Makoto; YAMATAKA, Hiroshi

Chair: USUI, Satoshi (15:30-16:20)

* 15:20-15:30: interval for laptop PC connection.(2F5-40, 2F5-42, 2F5-43)

Computational Study of Substituent Effects on Gas-Phase Stabilities of Phenylaminomethyl Cations (Sci. Res. Ctr., Hosei Univ.; IMCE, Kyushu Univ.) º NAKATA, Kazuhide; FUJIO, Mizue

Enantioselevtive Oxyarylation of Alkenes Using Optically Active Hypervalent Iodine(III) (Grad. Sch. Mat. Sci., Univ. of Hyogo) º SHIMOGAKI, Mio; FUJITA, Morifumi; SUGIMURA, Takashi

Synthesis of Aza-Heterocyclic Compounds Using Pseudo-Intramolecular Process (Sch. Env. Sci. Eng., KUT; Res. Inst. of KUT) ASAHARA, Haruyasu; º NISHIWAKI, Nagatoshi