The 95th Annual Meeting of The Chemical Society of Japan

Date: March 26th - 29th, 2015

Venue: Funabashi Campus, College of Science and Technology, Nihon University / School of Pharmacy, Nihon University, Chiba, Japan

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Room G2

Bldg.12 1232


[Organic Chemistry -Reaction and Synthesis- Aromatic Compounds]


Thursday, March 26, AM

Chair: NISHIDA, Jun-ichi (10:10-11:10)

* 10:00-10:10: interval for laptop PC connection.(1G2-08, 1G2-09, 1G2-11, 1G2-12, 1G2-13)

1G2-08
Synthesis and Optical Properties of Non-Planar Polycyclic Aromatic Hydrocarbon Prepared by Cyclization Reaction between Biphenyl Derivatives and Diynes (Grad. Sch. Sci. Eng., Chuo Univ.) º OISHI, Anna; TOKORO, Yuichiro; FUKUZAWA, Shin-ichi

1G2-09*
Chirality Amplification and Inversion based on Host-Guest Complexation of Crown Ethers Bearing the Dynamic Thiahelicene Structure with Chiral Amine Salts (Grad. Sch. Sci., Eng., Tokyo Tech) º NAMBU, Yoko; TAKATA, Toshikazu

1G2-11
Synthesis of [16]helicene by one-step photocyclization of olefins consisting of benzene and naphthalene units (Grad. Sch. Eng., The Univ. of Tokyo; Fac. Sci., Yamagata Univ.) º MORI, Kazuyuki; MURASE, Takashi; FUJITA, Makoto

1G2-12
Azobenzene-incorporated BINOLs as stimuli-responsive catalysts (Grad. Sch. Chem. Sci. Technol., Tokyo Univ. of Sci.) º AKAURA, Syouta; TUTUI, Yuki; UCHIYAMA, Masanobu; TAKAISHI, Kazuto; IMAHORI, Tatsushi

1G2-13
Development of azobenzene diamine-based stimuli-responsive catalysts (Grad. Sch. Chem. Sci. Technol., Tokyo Univ. of Sci.) º MURATA, Daisuke; SUENAGA, Akari; KURIHARA, Seiji; IMAHORI, Tatsushi


Chair: KANNO, Ken-ichiro (11:20-12:10)

* 11:10-11:20: interval for laptop PC connection.(1G2-15, 1G2-16, 1G2-17, 1G2-18, 1G2-19)

1G2-15
Synthesis of phenacene-type aromatic compounds using AuCl(I) catalyst (Grad. Sch. Sci., Eng., Ehime Univ.) º SATO, Shiori; MORI, Shigeki; OKUJIMA, Tetsuo; UNO, Hidemitsu; NAKAE, Takahiro

1G2-16
Synthesis and Physical Properties of Polycyclic Aromatic Hydrocarbons Having an Azulene Backbone (Grad. Sch. Nat. Sci. Technol., Okayama Univ.) º IBA, Shinji; MURAI, Masahito; TAKAI, Kazuhiko

1G2-17
Synthesis and structure of benzo[k]fluoranthene-3,4-dicarboxyimides (Grad. Sch. Eng., Univ. of Hyogo) º NAGAHARA, Masaya; NISHIDA, Jun-ichi; KITAMURA, Chitoshi; KAWASE, Takeshi

1G2-18
Synthesis and optical properties of cyclic oligophenylene containing two 10-mesityl anthracene units bridged by two biphenyl linkages (Grad. Sch. Fac. Env. and Info. Sci., Yokohama Natl. Univ.) º SHIRAI, Atsumi; SHIMIZU, Hideyuki; IYODA, Masahiko; OTANI, Hiroyuki

1G2-19
Synthesis, morphology, and optical properties of π-expanded macrocyclic oligo-3,4-diphenylthiophene 6-mer (Grad. Sch. Fac. Env. and Info. Sci., Yokohama Natl. Univ.) º KARIYA, Wakana; OTANI, Hiroyuki; SHIMIZU, Hideyuki; IYODA, Masahiko


Thursday, March 26, PM

Chair: OKUJIMA, Tetsuo (13:30-14:30)

* 13:20-13:30: interval for laptop PC connection.(1G2-28, 1G2-30, 1G2-32, 1G2-33)

1G2-28*
Synthesis and properties of endohedral C70 encapsulating monomeric and dimeric water molecules (ICR, Kyoto Univ.; PRESTO, JST) º ZHANG, Rui; MURATA, Michihisa; WAKAMIYA, Atsushi; MURATA, Yasujiro

1G2-30*
Synthesis of cross-conjugated 2,3-bis(aryl)[2]dendralenes and their properties (Dept. Appl. Chem., Nat. Def. Acad.) º KAMEDA, Tsuyoshi; HAYASHI, Shotaro; KOIZUMI, Toshio

1G2-32
Modification of π-expanded porphyrins using Suzuki coupling (Grad. Sch. Eng., Utsunomiya Univ.) º UNO, Daiki; SASAKI, Akira; OBA, Toru; ITO, Satoshi

1G2-33
Semiconducting property and thermal stability of alkyl-substituted tetrabenzoporphyrins. (Grad. Sch. Eng., Utsunomiya Univ.) º SASAKI, Akira; UNO, Daiki; OBA, Toru; ITO, Satoshi


Chair: OBA, Toru (14:40-15:40)

* 14:30-14:40: interval for laptop PC connection.(1G2-35, 1G2-36, 1G2-37, 1G2-38, 1G2-39, 1G2-40)

1G2-35
Synthesis of chlorophyll derivatives possessing a sulfur-functional group at the C3 position and their physical properties (Ritsumeikan Univ. Graduate School of Life Sciences) TAMIAKI, Hitoshi; º KIM, Kifa; SASAKI, Shin-ichi

1G2-36
Synthesis and optical properties of chlorophyll derivatives possessing valious acyl groups at the 3-position (Grad. Sch. Life Sci., Ritsumeikan Univ.; Grad. Sch. Sci. Tech., Ryukoku Univ.) TAMIAKI, Hitoshi; º KIMURA, Yuki; MIYATAKE, Tomohiro

1G2-37
Synthesis of olefinated chlorophyll derivatives through methylenation and their photophysical properties (Grad. Sch. Life Sci., Ritsumeikan Univ.) HITOSHI, Tamiaki; º TSUJI, Kazuki; MIYATAKE, Tomohiro

1G2-38
Synthesis and Physical Properties of Diketopyrrolopyrrole Oligomers (Grad. Sch. Mat. Sci., NAIST) º ASADA, Toru; ARATANI, Naoki

1G2-39
Synthesis of cyclo[8]pyrrole dihydrogen phosphonate salts by anion exchange method (Grad. Sch. Sci., Eng., Ehime Univ.) º MATSUMOTO, Hiroki; MORI, Shigeki; UNO, Hidemitsu; OKUJIMA, Tetsuo

1G2-40
Synthesis of near infrared dyes based on the reaction of oxocarbonic acids and pyrrole derivatives (Grad. Sch. Sci., Eng., Ehime Univ.) º JOHDAI, Kazuki; KITATSUKA, Manami; MORI, Shigeki; OKUJIMA, Tetsuo; UNO, Hidemitsu


Chair: HAYASHI, Shotaro (15:50-16:50)

* 15:40-15:50: interval for laptop PC connection.(1G2-42, 1G2-43, 1G2-44, 1G2-45, 1G2-46, 1G2-47)

1G2-42
Design and synthesis of pyradino[2,3-g]quinoxaline-based molecular semiconductors for photovoltaic application (Grad. Sch. Mat. Sci., NAIST) º AOTAKE, Tatsuya; SUZUKI, Mitsuharu; YAMADA, Hiroko

1G2-43
Enantioselective Synthesis of Triphenylene-Based [9]Helicene Derivatives (Grad. Sch. Fac. Eng., Tokyo Univ. of Agri. and Technol.; Grad. Sch. Sci., Eng., Tokyo Tech; JST ACT-C) º MURAYAMA, Koichi; TANAKA, Ken

1G2-44
Design and Synthesis of fluorinated-functional group containing Subphthalocyanines (Grad Sch. Eng., Nagoya Inst. of Tech.) º NAGAI, Kenichiro; MORI, Satoru; IIDA, Norihito; SHIBATA, Norio; TOKUNAGA, Ethuko

1G2-45
Synthesis of new double-decker phthalocyanines with trifluoroethoxy groups (Grad Sch. Eng., Nagoya Inst. of Tech.) º OGAWA, Naoya; MORI, Satoru; SHIBATA, Norio

1G2-46
One-pot Chemo-enzymatic process usign PDMS membrane (Osaka Municipal Technical Research Institute Biomaterials and Commodity Chemicals Division) º SATO, Hirofumi; HUMMEL, Werner; GRÖGER, Harald

1G2-47
A Catalytic Synthetic Approach to HSD-016 through Enantioselective Trifluoromethylation (Grad Sch. Eng., Nagoya Inst. of Tech.) º YASUDA, Yoshimasa; OKUSU, Satoshi; SHIBATA, Norio


Friday, March 27, AM

Chair: FUCHIBE, Kohei (09:00-10:00)

* 8:50-9:00: interval for laptop PC connection.(2G2-01, 2G2-02, 2G2-03, 2G2-04, 2G2-05, 2G2-06)

2G2-01
Synthesis of Benzocarbazole Derivatives Using Oxidative Radical Reaction with Mn(III)-Enolate Complex as a Key Reaction and Development to the New Organic EL Materials (Kumamoto Univ. Department of Science, Faculty of Science) º AKAZAKI, Chiaki; NISHINO, Hiroshi

2G2-02
Scandium Triflate-Catalyzed Arylative Desulfonation of Diarylmethyl Phenyl Sulfones (WPI-ITbM, Nagoya Univ.) º ARIKI, Zachary T.; NAMBO, Masakazu; CANSECO-GONZALEZ, Daniel; BEATTIE, Dawson; CRUDDEN, Cathleen M.

2G2-03
Microwave assisted synthesis of 4-phenylbutanoic acid analogues (Coll. Sci. Eng., Kanto Gakuin Univ.) º AKASTU, Yuusuke; MOCHIZUKI, Ryunosuke; IIDA, Hirokazu

2G2-04
Substitiuon Reactions Using α,α,α-Bromodifluorotoluene Derivatives (Sagami Chemical Research Institute) º SHIOSAKI, Masahiro; INOUE, Munenori

2G2-05
Structural effects of 1,3-dipoles in the reaction with cyclic alkynes (IBB, Tokyo Med. and Dental Univ.; JNC Petrochem. Co.) º TANAKA, Junko; YOSHIDA, Suguru; MATSUSHITA, Takeshi; HOSOYA, Takamitsu

2G2-06
Cycloaddition between alkenyl azides and cyclic alkynes (IBB, Tokyo Med. and Dental Univ.) º GOTO, Sayuri; YOSHIDA, Suguru; MATSUSHITA, Takeshi; HOSOYA, Takamitsu


Chair: UEDA, Mitsuhiro (10:10-11:10)

* 10:00-10:10: interval for laptop PC connection.(2G2-08, 2G2-09, 2G2-10, 2G2-11, 2G2-12, 2G2-13)

2G2-08
Synthesis of Substituted Acenes Based on Cationic Cyclization of Fluoroalkenes (Grad. Sch. Pure Appl. Sci., Univ. of Tsukuba) º HAKOZAKI, Tomohiro; MIURA, Keisuke; FUCHIBE, Kohei; ICHIKAWA, Junji

2G2-09
Efficient Synthesis of Polycyclic Aromatic Hydrocarbons Utilizing Arynes with Fused Structures (Grad. Sch. Pure Appl. Sci., Univ. of Tsukuba) º ABE, Masashi; FUCHIBE, Kohei; ICHIKAWA, Junji

2G2-10
Synthesis and Structure of Twisted Polycyclic Aromatic Hydrocarbon with Helicity Based on a Double Helicene Framework (Grad. Sch. Sci., Osaka Pref. Univ.) º KASHIHARA, Hitoshi; KAMIKAWA, Ken

2G2-11
Synthesis of extended π-conjugated molecules by 1,3-dialkynylisobenzofurans (Sch. Sci. Tech., Kwansei Gakuin Univ.) º ASAHINA, Kenta; HAMURA, Toshiyuki

2G2-12
Regioselective Construction of Biaryls by Catalytic Generation of Benzyne (Sch. Sci. Tech., Kwansei Gakuin Univ.) º MARUYAMA, Daisuke; TAKEDA, Asa; SUZUKI, Keisuke; HAMURA, Toshiyuki

2G2-13
Study on the aromatization of diepoxypentacenes into substituted pentacenes (Sch. Sci. Tech., Kwansei Gakuin Univ.) º EDA, Shohei; EGUCHI, Fumiaki; KUDO, Ryoji; HAMURA, Toshiyuki


Chair: KAMIKAWA, Ken (11:20-12:20)

* 11:10-11:20: interval for laptop PC connection.(2G2-15, 2G2-17, 2G2-18, 2G2-19, 2G2-20)

2G2-15*
Super Activation of Lithium Cation Based on Carborane Anion and Its Unique Reactivity (Grad. Sch. Pharm., The Univ. of Tokyo; RIKEN CSRS) º KITAZAWA, Yu; TAKITA, Ryo; MATSUBARA, Seijiro; UCHIYAMA, Masanobu

2G2-17
Pinpoint C−F Bond Activation of Trifluoromethyl Group (IBB, Tokyo Med. and Dental Univ.) º SHIMOMORI, Ken; HOSOYA, Takamitsu; YOSHIDA, Suguru

2G2-18
Cycloaddition of Thiophene S,S-Dioxide Derivatives with Cycloalkynes toward a Novel Chemical Modification of Biomolecules (IBB, Tokyo Med. and Dental Univ.) º MEGURO, Tomohiro; YOSHIDA, Suguru; HOSOYA, Takamitsu

2G2-19
Facile Synthesis of Multisubstituted Aromatic Phosphorus Compounds Based on the Michaelis-Arbuzov-Type Reaction of Aryne Intermediates (IBB, Tokyo Med. and Dental Univ.) º YOSHIDA, Suguru; TSUKAMOTO, Fumio; SHIMOMORI, Ken; HOSOYA, Takamitsu

2G2-20
Development of the Ag-mediated introduction method of a trifluoromethyl group to aromatic compounds by way of a radical species (Fac. Eng., Tokyo Univ. of Agri. and Technol.) º ONO, Kazuki; YAMAZAKI, Takashi; TAKASUKA, Tomoko


Friday, March 27, PM

Chair: HAMURA, Toshiyuki (13:30-14:30)

* 13:20-13:30: interval for laptop PC connection.(2G2-28, 2G2-31, 2G2-32, 2G2-33)

2G2-28 Young Scholar Lectures of CSJ
Novel Methods to Conjugate Molecules Based on Strained Functional Groups (IBB, Tokyo Med. and Dental Univ.) º YOSHIDA, Suguru

2G2-31
Development of C-N Ullmann-type Coupling Reactions of Carbazole Derivatives and Aryl Iodides by Merging Visible Light Photocatalysis and Copper Catalysis (Grad. Sch. Sci., The Univ. of Tokyo) YOO, Woo-Jin; º TSUKAMOTO, Tatsuhiro; KOBAYASHI, Shu

2G2-32
Synthesis of 2-Naphthylamine derivatives via Intramolecular Cyclization of o-Vinylbenzyl cyanides (Grad. Sch. Chi Sci. and Eng., Hokkaido Univ.) º ABE, Taiki; YOSHIMURA, Fumihiko; TANINO, Keiji

2G2-33
Activation of Reductive Silylation with Polycyclic Aromatic Compounds (Grad. Sch. Sci. Tech., Gunma Univ.) º KITA, Hikaru; KANNO, Ken-ichiro; KYUSHIN, Soichiro


Chair: NISHINA, Yuta (14:40-15:40)

* 14:30-14:40: interval for laptop PC connection.(2G2-35, 2G2-36, 2G2-37, 2G2-38, 2G2-39, 2G2-40)

2G2-35
Facile Synthesis of Multisubstituted Benzo[b]thiophenes Based on Transformations via Thienobenzyne Intermediates (IBB, Tokyo Med. and Dental Univ.) º MORITA, Takamoto; YOSHIDA, Suguru; HOSOYA, Takamitsu

2G2-36
Generation and Transformations of 3-Haloarynes Triggered by Iodine-Magnesium Exchange Reaction (IBB, Tokyo Med. and Dental Univ.) º NAGAI, Akira; UCHIDA, Keisuke; YOSHIDA, Suguru; HOSOYA, Takamitsu

2G2-37
3-Triflyloxyarynes: An Improved Generation Method, Studies on Regioselectivity in Aryne Generation, and Applications to the Synthesis of Polycyclic Arenes. (IBB, Tokyo Med. and Dental Univ.) º UCHIDA, Keisuke; YOSHIDA, Suguru; HOSOYA, Takamitsu

2G2-38
Cross-coupling of Aryl Diazonium Salts with Arenes Induced by Polyaniline (Grad. Sch. Eng., Osaka Univ.) AMAYA, Toru; º HATA, Dai; HIRAO, Toshikazu

2G2-39
Synthesis of Novel Fullerene Derivatives having Alkylidenecyclobutane Skeleton (Grad. Sch. Sci., Osaka Pref. Univ.) º SAKAGUCHI, Tsukasa; UEDA, Mitsuhiro; YOSHIDA, Syunsuke; YASUDA, Hiroshi; RYU, Ilhyong

2G2-40
[2+2] Photocycloaddition of Fullerene with Coumarin Derivatives (Fac. Sci., Osaka Pref. Univ.) º HAYAMA, Miho; UEDA, Mitsuhiro; YASUDA, Hiroshi; YOSHIDA, Syunsuke; RYU, Ilhyong


Chair: NISHINAGA, Tohru (15:50-16:50)

* 15:40-15:50: interval for laptop PC connection.(2G2-42, 2G2-43, 2G2-44, 2G2-45, 2G2-46, 2G2-47)

2G2-42
Oxidative dehydrogenative coupling reaction using graphene oxide as an oxidant (RCIS, Okayama Univ.) º MORIOKU, Kumika; MORIMOTO, Naoki; NISHINA, Yuta

2G2-43
Catalytic oxidation using reduced graphene oxide (RCIS, Okayama Univ.) º MORIMOTO, Naoki; TAKEUCHI, Yasuo; NISHINA, Yuta

2G2-44
Catalyst-Free Aminocarbonylation of Iodoarenes under Photoirradiation Conditions (Grad. Sch. Sci., Osaka Pref. Univ.) º SATO, Aoi; KAWAMOTO, Takuji; RYU, Ilhyong

2G2-45
Chiral Borate Salt Catalyzed Friedel-Crafts Alkylation of Indoles with α,β-Disubstituted Acroleins (Grad. Sch. Sci., Osaka Pref. Univ.) º YAGYU, Yoshitaka; UEDA, Mitsuhiro; RYU, Ilhyong

2G2-46
Catalytic Asymmetric 1,2-Type Friedel-Crafts Reaction of Phenols Based on Entropy-associated Stereodiscrimination (Grad. Sch. Fac. Eng., Tokyo Univ. of Agri. and Technol.) º HIRAO, Shogo; KATO, Masaru; IIDA, Keisuke; SOHTOME, Yoshihiro; NAGASAWA, Kazuo

2G2-47
Guanidinium-iodide catalyzed umpolung type coupling reaction of β-ketoamide with oxindoles (Grad. Sch. Fac. Eng., Tokyo Univ. of Agri. and Technol.) º KATO, Takanari; YASUI, Koji; NAGASAWA, Kazuo


Saturday, March 28, AM

Chair: ARAI, Noriyoshi (09:00-10:00)

* 8:50-9:00: interval for laptop PC connection.(3G2-01, 3G2-02, 3G2-03, 3G2-04, 3G2-05, 3G2-06)

3G2-01
Single Electron Transfer-Induced Coupling of Aryl Halides with Alkylzinc Reagents Prepared from Alkyllithiums by Transmetalation (Grad. Sch. Sci., Kyoto Univ.) º OKURA, Keisho; SHIRAKAWA, Eiji

3G2-02
Single Electron Transfer-Induced Coupling of Alkynylzinc Reagents with Aryl Iodides (Grad. Sch. Sci., Kyoto Univ.) º KAWASHIMA, Hitomi; OKURA, Keisyo; NISHIDA, Naoya; TAMAKUNI, Fumiko; SHIRAKAWA, Eiji

3G2-03
Single Electron Transfer-Induced Coupling of Arylboronic Acids with Aryl Iodides Using Diethylzinc as an Activator (Grad. Sch. Sci., Kyoto Univ.) º YOSHIDA, Yuto; OKURA, Keisho; SHIRAKAWA, Eiji

3G2-04
Enantioselective Rauhut-Currier reaction promoted by an immobilized organocatalyst (ISIR, Osaka Univ.) º HIRATA, Shuichi; KISHI, Kenta; TAKIZAWA, Shinobu; SASAI, Hiroaki

3G2-05
Iron-Catalyzed ortho Alkylation of Carboxamides with Organoalane under Low Catalyst Loading (Grad. Sch. Sci., The Univ. of Tokyo) º SHANG, Rui; ILIES, Laurean; NAKAMURA, Eiichi

3G2-06
Co-catalyzed Annulation of Alkynes with o-Methoxycarbonyl Phenylboronic Acid (Fac. Sci., Osaka Pref. Univ.) º SUYAMA, Yuki; UEDA, Mitsuhiro; RYU, Ilhyong


Chair: HOSAKAWA, Seijiro (10:10-11:10)

* 10:00-10:10: interval for laptop PC connection.(3G2-08, 3G2-09, 3G2-10, 3G2-11, 3G2-12, 3G2-13)

3G2-08
Oxidative Coupling Reaction of Aromatic Compounds Utilizing Metal Oxide Supported Gold Nanoparticles and the mechanism (Grad. Sch. Sci., Kyushu Univ.) º AKEBI, Ryota; ISHIDA, Tamao; MISE, Yoshiyuki; AIKAWA, Shohei; HAMASAKI, Akiyuki; MIYASAKA, Mitsuru; YAMAMOTO, Yasushi; TSUJI, Tetsuro; TOKUNAGA, Makoto

3G2-09
Selective Hydrogenation Catalyzed by Alkyne Derivatives-Stabilized Palladium Nanoparticles (Grad. Sch. Chi Sci. and Eng., Hokkaido Univ.) º ONODERA, Nozomi; ARAI, Noriyoshi; DEKITA, Atushi; HORI, Junichi; OHKUMA, Takeshi

3G2-10
o-Selective deiodination of o-,p-diiodophenols by using Red-Al (Grad. Sch. Biosci. Biotech., Tokyo Tech) º KONDO, Daiki; IKOMA, Atsushi; OGAWA, Narihito; KOBAYASHI, Yuichi

3G2-11
Peroxide-Promoted α-Arylation of Aliphatic Amines with Aryl Halides (Grad. Sch. Sci., Kyoto Univ.) º UENO, Ryota; SHIRAKAWA, Eiji

3G2-12
Peroxide-Promoted Reduction of Aryl Halides with 2-Propanol (Grad. Sch. Sci., Kyoto Univ.) º SHIMIZU, Takashi; UENO, Ryota; SHIRAKAWA, Eiji

3G2-13
Study of the Alternate Selectivity in the Lithiation of the Hexaphenylbenzene Framework (Grad. Sch. Arts and Sci., The Univ. of Tokyo) º KOJIMA, Tatsuo; HIRAOKA, Shuichi


Chair: KOJIMA, Tatsuo (11:20-12:10)

* 11:10-11:20: interval for laptop PC connection.(3G2-15, 3G2-17, 3G2-18, 3G2-19)

3G2-15*
Facile Synthesis of Diazido Compounds Based on the Formal C-H Azidation and Application to the Azido-type Selective Sequential Molecular Conjugation (IBB, Tokyo Med. and Dental Univ.) º HOSOYA, Takamitsu; MISAWA, Yoshihiro; YOSHIDA, Suguru

3G2-17
tert-Butoxide-Promoted Coupling of Aryl Iodides with Arenes Using tert-Butyl Hyponitrite as an Initiator (Grad. Sch. Sci., Kyoto Univ.) º KIRIYAMA, Kazuya; SHIRAKAWA, Eiji

3G2-18
Synthesis of sporochnol by using SN2’ allylic substitution for the construction of a quaternary carbon (Grad. Sch. Biosci. Biotech., Tokyo Tech) º SUGIHARA, Yusuke; TOJO, Toshifumi; KOBAYASHI, Yuichi

3G2-19
Studies toward the total synthesis of A-74528 (Grad. Sch. Advanced Sci. Eng., Waseda Univ.) º YOSHINO, Yuri; SEKINE, Daisuke; HARACHI, Mio; HOSOKAWA, Seijiro

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