The 95th Annual Meeting of The Chemical Society of Japan

Date: March 26th - 29th, 2015

Venue: Funabashi Campus, College of Science and Technology, Nihon University / School of Pharmacy, Nihon University, Chiba, Japan

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Room E6

Bldg.10 1043


[Organic Chemistry -Reaction and Synthesis- Organometallic Compounds]


Thursday, March 26, AM


Ni

Chair: IWASAKI, Takanori (09:40-10:30)

* 9:30-9:40: interval for laptop PC connection.(1E6-05, 1E6-07, 1E6-08, 1E6-09)

1E6-05*
Nickel and copper co-catalyzed defluoroborylation of fluoroarenes for expeditious preparation of [18F]PET probes (RIKEN CLST) º NIWA, Takashi; OCHIAI, Hidenori; WATANABE, Yasuyoshi; HOSOYA, Takamitsu

1E6-07
Practical preparation method and application of benzyne-nickel complex (RIKEN CLST) º SUMIDA, Tomoe; SUMIDA, Yuto; HOSOYA, Takamitsu

1E6-08
Nickel-catalyzed reductive alkylation of aryl triflates (RIKEN CLST) º SUMIDA, Yuto; SUMIDA, Tomoe; HOSOYA, Takamitsu

1E6-09
Synthesis of Optically Active Helicenes via Nickel-Catalyzed Asymmetric Cycloisomerization of Triynes Using Helically Chiral Polymer Ligands (Grad. Sch. Eng., Kyoto Univ.) º OKITSUKA, Masumi; ADACHI, Takumi; YAMAMOTO, Takeshi; JANCARIK, Andrej; STARÝ, Ivo; STARÁ, I.g.; SUGINOME, Michinori


Chair: ONODERA, Gen (10:40-11:30)

* 10:30-10:40: interval for laptop PC connection.(1E6-11, 1E6-12, 1E6-13, 1E6-14, 1E6-15)

1E6-11
Nickel-catalyzed reaction of perfluoroarenes with 1,3-butadiene through dimerization of 1,3-butadiene (Grad. Sch. Eng., Osaka Univ.) º MIN, Xin; IWASAKI, Takanori; KUNIYASU, Hitoshi; KAMBE, Nobuaki

1E6-12
C-H coupling polymerization with controlled molecular weight leading to poly(3-substituted thiophene)s of high solubility in hexane (Fac. Eng., Kobe Univ.) º FUJITA, Keisuke; SUMINO, Yugo; MORI, Atsunori

1E6-13
C-H coupling polymerization of oligo(thienylenevinylene) (Fac. Eng., Kobe Univ.) º NAKAGAWA, Naoki; FUKUI, Yuta; TANAKA, Shota; MORI, Atsunori

1E6-14
Reactions of Aromatic Amides Using a Bidentate Directing Group by a Nickel Complex (Grad. Sch. Eng., Osaka Univ.) º YOKOTA, Ayana; CHATANI, Naoto

1E6-15
Palladium-Catalyzed Intermolecular Oxidative Coupling between Carbon-Hydrogen Bonds in Aliphatic Amides and Benzyl Carbon-Hydrogen Bonds in Toluene Derivatives. (Grad. Sch. Eng., Osaka Univ.) º KUBO, Teruhiko; AIHARA, Yoshinori; CHATANI, Naoto


Chair: SUMIDA, Yuto (11:40-12:30)

* 11:30-11:40: interval for laptop PC connection.(1E6-17, 1E6-18, 1E6-19, 1E6-20, 1E6-21)

1E6-17
Nickel-catalyzed Linear-selective Alkylation of Benzene (Grad. Sch. Eng., Kyoto Univ.; CREST, JST) º OHGI, Akito; SAITO, Teruhiko; SEMBA, Kazuhiko; NAKAO, Yoshiaki

1E6-18
Nickel/Aluminum-catalyzed para-Selective Alkylation of Benzamides (Grad. Sch. Eng., Kyoto Univ.; CREST, JST) º OKUMURA, Shogo; SAITO, Teruhiko; SEMBA, Kazuhiko; NAKAO, Yoshiaki

1E6-19
Study on the Chemoselectivity of the Ni-Catalyzed Three-Component Coupling Reaction of Conjugated Enyne, Aldehydes, and Organozinc. (Grad. Sch. Eng., Nagasaki Univ.) º KAWABATA, Toshiki; MORI, Yasuyuki; ONODERA, Gen; KIMURA, Masanari

1E6-20
Ni-Catalyzed Hydrocarboxylation of Conjugated Diene with Carbon Dioxide (Grad. Sch. Eng., Nagasaki Univ.) º OMURA, Ryosuke; MORI, Yasuyuki; ONODERA, Gen; KIMURA, Masanari

1E6-21
Ni-Catalyzed Selective Formation of Unsaturated Carboxylic Acids and Phenylacetic Acids via C-C Double Bond Cleavage (Grad. Sch. Eng., Nagasaki Univ.) º NINKATA, Ryo; MORI, Takamichi; KAWAHARA, Hisaho; ONODERA, Gen; KIMURA, Masanari


Thursday, March 26, PM


Ru

Chair: SEMBA, Kazuhiko (13:40-14:40)

* 13:30-13:40: interval for laptop PC connection.(1E6-29, 1E6-30, 1E6-31, 1E6-32, 1E6-33)

1E6-29
Ruthenium Complex-Controlled Catalytic Addition of Organic Disulfides to Terminal Alkynes (Grad. Sch. Eng., Kyoto Univ.; Kyoto Univ. C-PiER; ICR, Kyoto Univ.) º SAWASE, Kanae; KIMURA, Yu; TOSHIMITSU, Akio; KONDO, Teruyuki

1E6-30
Transition Metal-Catalyzed Olefin Isomerization of Alkenyl Esters (Grad. Sch. Sci., Osaka Pref. Univ.) º KUWAHARA, Takashi; FUKUYAMA, Takahide; RYU, Ilhyong

1E6-31
Ruthenium Hydride-Catalyzed Olefin Isomerization of Homoallyl Silyl Ethers to Allyl Silyl Ethers (Grad. Sch. Sci., Osaka Pref. Univ.) KUWAHARA, Takashi; º YAMAMOTO, Yuki; FUKUYAMA, Takahide; RYU, Ilhyong

1E6-32
Synthesis of Pincer Ru-Complex-Bound Norvaline Peptides (ICR, Kyoto Univ.) º ITO, Ran; YOSHIDA, Ryota; YOKOI, Tomoya; IWAMOTO, Takahiro; ISOZAKI, Katsuhiro; TAKAYA, Hikaru; NAKAMURA, Masaharu

1E6-33*
Ruthenium Complex-Bound Norvaline-Catalyzed Oxidation of Electron-Rich Aromatic Compounds (ICR, Kyoto Univ.; Grad. Sch. Eng., Kyoto Univ.) º YOSHIDA, Ryota; ISOZAKI, Katsuhiro; YOKOI, Tomoya; ITO, Ran; TAKAYA, Hikaru; NAKAMURA, Masaharu


Chair: TAKAYA, Hikaru (14:50-15:50)

* 14:40-14:50: interval for laptop PC connection.(1E6-36, 1E6-37, 1E6-39, 1E6-41)

1E6-36
Synthesis of Polyaromatic Compounds by Ruthenium-Catalyzed Cycloisomerization of o-Ethynylbiaryls (Grad. Sch. Pharm. Sci., Nagoya Univ.) º MATSUI, Kazuma; SHIBUYA, Masatoshi; YAMAMOTO, Yoshihiko

1E6-37*
Synthesis of 2,3-Fused 4-Arylnaphthalen-1-yl Esters Exploiting Hydrocarboxylative Cyclization of 1,8-Diaryl-1,6-diynes (Grad. Sch. Pharm. Sci., Nagoya Univ.) º MORI, Shota; SHIBUYA, Masatoshi; YAMAMOTO, Yoshihiko

1E6-39*
Catalytic Asymmetric Hydrogenation of Salicylic Acids (Grad. Sch. Sci., Kyushu Univ.) º IKEDA, Ryuhei; KUWANO, Ryoichi

1E6-41
Ruthenium-Catalyzed Asymmetric Hydrogenation of Azaidoles (Grad. Sch. Sci., Kyushu Univ.) º SAITA, Masahiro; ISHIZUKA, Kentaro; KUWANO, Ryoichi


Fe

Chair: ITO, Shingo (16:00-17:00)

* 15:50-16:00: interval for laptop PC connection.(1E6-43, 1E6-44, 1E6-45, 1E6-46, 1E6-47, 1E6-48)

1E6-43
Fe-mediated Cyclization of 1,2-Di(9H-fluoren-9-ylidene)-1,2-diarylethanes for Construction of New Dispirocycles (WPI-AIMR, Tohoku Univ.) º LI, Lingyu; ZHAO, Jian; ONIWA, Kazuaki; ASAO, Naoki; YAMAMOTO, Yoshinori; JIN, Tienan

1E6-44
Synthesis of Phosphabenzenes Based on Iron-Catalyzed [2+2+2] Cycloaddition Reaction (The Univ. of Tokyo Institute of Engineering Innovation, School of Engineering) º TAKATA, Shohei; NAKAJIMA, Kazunari; NISHIBAYASHI, Yoshiaki

1E6-45
Iron-Catalyzed Selective Addition of Grignard Reagents to Enynoates and Synthetic Studies of Meloscine (Grad. Sch. Biosci. Biotech., Tokyo Tech) º OHTANI, Keisuke; IWATA, Satoshi; SHIGETA, Masayuki; HATA, Takeshi; URABE, Hirokazu

1E6-46
Iron-Catalyzed Stereoselective 1,6-Addition of Cyclopropyl Grignard Reagent to 2,4-Alkadienoates or -amides (Grad. Sch. Biosci. Biotech., Tokyo Tech) º SUGANO, Goshi; MIZUNO, Hitomi; SHIGETA, Masayuki; HATA, Takeshi; URABE, Hirokazu

1E6-47
Iron-catalyzed One-pot Stereoselective Synthesis of Cyclohexenes from Grignard Reagents and ω-Halo-α,β,γ,δ-unsaturated Esters or Amides (Grad. Sch. Biosci. Biotech., Tokyo Tech) NAKAGAWA, Kazushige; º NARIAI, Satoru; HATA, Takeshi; URABE, Hirokazu

1E6-48
Iron-catalyzed One-pot Stereoselective Synthesis of Cyclopentanes or -hexanes from Grignard Reagents and ω-Halo-α,β,γ,δ-unsaturated Esters or Amides (Grad. Sch. Biosci. Biotech., Tokyo Tech) º NARIAI, Satoru; NAKAGAWA, Kazushige; HATA, Takeshi; URABE, Hirokazu


Chair: SHIGETA, Masayuki (17:10-18:00)

* 17:00-17:10: interval for laptop PC connection.(1E6-50, 1E6-51, 1E6-52, 1E6-53, 1E6-54)

1E6-50
Synthesis and Characterization of Planar-Chiral Benzo[b]phosphaferrocene Derivatives (CRC, Hokkaido Univ.; Rigaku Corporation Application Laboratory) OGASAWARA, Masamichi; º ARAE, Sachie; WATANABE, Susumu; SUBBARAYAN, Velusamy; SATO, Hiroyasu; TAKAHASHI, Tamotsu

1E6-51
Enantioselective Synthesis of Ferrocene-Fused Planar-Chiral Phospholes (CRC, Hokkaido Univ.; Grad. Sch. Sci., Chiba Univ.) OGASAWARA, Masamichi; º HU, Hao; WU, Wei-yi; YOSHIDA, Kazuhiro; TAKAHASHI, Tamotsu

1E6-52
Iron-catalyzed allylic substitution reaction for the synthesis of trisubstituted olefins (Fac. Sci., Kochi Univ.) º NASU, Ken-ya; NAGANO, Takashi

1E6-53
Propylene polymerization under iron/diiminopyridine catalysis: Steric effect of ligands and application to copolymerization. (Grad. Sch. Eng., The Univ. of Tokyo) º KAWAKAMI, Takafumi; ITO, Shingo; NOZAKI, Kyoko

1E6-54
Fe-catalyzed cross-coupling reaction of alkenyl ethers with Grignard reagents (Grad. Sch. Eng., Osaka Univ.) º AKIMOTO, Ryo; IWASAKI, Takanori; KUNIYASU, Hitoshi; KAMBE, Nobuaki


Friday, March 27, AM


Ni

Chair: MORIUCHI, Toshiyuki (09:40-10:30)

* 9:30-9:40: interval for laptop PC connection.(2E6-05, 2E6-06, 2E6-07, 2E6-08)

2E6-05
Additive Effects of Ammonium Salts on Nickel-catalyzed Direct Amination of Allylic Alcohols (Grad. Sch. Eng. Sci., Osaka Univ.) º NAKAUCHI, Daisuke; KITA, Yusuke; HOSHIMOTO, Yoichi; SAKAGUCHI, Hironobu; NAKAHARA, Yasuhito; OGOSHI, Sensuke; MASHIMA, Kazushi

2E6-06
Synthesis and Reactivity of Penta-Coordinated π-Allyl Nickel Complex with Acetate Ligand (Grad. Sch. Eng., Osaka Univ.) º SAKAGUCHI, Hironobu; HOSHIMOTO, Yoichi; KITA, Yusuke; NAKAUCHI, Daisuke; NAKAHARA, Yasuhito; MASHIMA, Kazushi; OGOSHI, Sensuke

2E6-07
Direct Asymmetric Allylic Alkylation of β-Ketoesters with Allylic Alcohols Mediated by a Catalyst System of Ni(0) and a Chiral Diphosphine Ligand (Grad. Sch. Eng. Sci., Osaka Univ.) º ODA, Hiroaki; KAVTHE, Rahul; KITA, Yusuke; MASHIMA, Kazushi

2E6-08*
Activation of Organosilanes with η2-Aldehyde Nickel Complexes: Key for Catalytic Syntheses of Benzoxasiloles (Grad. Sch. Eng., Osaka Univ.) º HOSHIMOTO, Yoichi; YABUKI, Hayato; KUMAR, Ravindra; OHASHI, Masato; OGOSHI, Sensuke


Chair: YAMAGUCHI, Junichiro (10:40-11:30)

* 10:30-10:40: interval for laptop PC connection.(2E6-11, 2E6-12, 2E6-13, 2E6-14, 2E6-15)

2E6-11
Ni(0)-Catalyzed Co-Trimerization Reactions of Tetrafluoroethylene with Simple Olefins (Grad. Sch. Eng., Osaka Univ.) º KAWASHIMA, Takuya; KIKUSHIMA, Kotaro; OHASHI, Masato; OGOSHI, Sensuke

2E6-12
Nickel-Catalyzed Borylation of Carbon-Hydrogene Bonds in Indole and Benzene Derivatives. (Grad. Sch. Eng., Osaka Univ.) TOBISU, Mamoru; º FURUKAWA, Takayuki; CHATANI, Naoto

2E6-13
Nickel-Catalyzed Alkynylation of Anisoles Using Grignard Reagents via Carbon-Oxygen Bond Cleavage. (Grad. Sch. Eng., Osaka Univ.) TOBISU, Mamoru; º TAKAHIRA, Tsuyoshi; CHATANI, Naoto

2E6-14
The Effect of Ligands on Nickel-Catalyzed Reductive Cleavage of Anisole Derivatives (Grad. Sch. Eng., Osaka Univ.) TOBISU, Mamoru; º MORIOKA, Toshifumi; CHATANI, Naoto

2E6-15
Nickel-Catalyzed Ring-Opening Arylation of Dibenzofuran (Grad. Sch. Sci., Kyoto Univ.) º KURATA, Yuto; OTSUKA, Shinya; FUKUI, Norihito; YORIMITSU, Hideki; OSUKA, Atsuhiro


Chair: KURAHASHI, Takuya (11:40-12:30)

* 11:30-11:40: interval for laptop PC connection.(2E6-17, 2E6-18, 2E6-20)

2E6-17
Reductive C-C Bond Formation by Nickel Catalysts Combined with Organosilicon Reductants (Grad. Sch. Eng. Sci., Osaka Univ.) º UEDA, Yohei; YURINO, Taiga; TSURUGI, Hayato; MASHIMA, Kazushi

2E6-18*
Facile Generation of Transition Metal Particles and Their Catalytic Application for Reductive C-C Bond Formation by Organosilicon Compounds as Reducing Reagents (Sch. Eng. Sci., Osaka Univ.; IRC3, AIST; NRI, AIST) º YURINO, Taiga; UEDA, Yohei; SHIMIZU, Yoshiki; TANAKA, Shinji; TSURUGI, Hayato; SATO, Kazuhiko; MASHIMA, Kazushi

2E6-20*
Decarbonylative Suzuki-Miyaura Coupling by Nickel Catalysis (Grad. Sch. Sci., Nagoya Univ.; WPI-ITbM, Nagoya Univ.) º MUTO, Kei; YAMAGUCHI, Junichiro; ITAMI, Kenichiro


Friday, March 27, PM


V

Chair: ISOZAKI, Katsuhiro (13:40-14:40)

* 13:30-13:40: interval for laptop PC connection.(2E6-29, 2E6-30, 2E6-31, 2E6-32, 2E6-33, 2E6-34)

2E6-29
Selective Oxidative Cross-Coupling of Boron and Silyl Enolates Induced by Oxovanadium(V) (Grad. Sch. Eng., Osaka Univ.; ACT-C, JST) AMAYA, Toru; º MAEGAWA, Yusuke; HIRAO, Toshikazu

2E6-30
Catalytic Oxidative Cross-coupling between Different Enolates with Oxovanadium(V) (Grad. Sch. Eng., Osaka Univ.; ACT-C, JST) AMAYA, Toru; º OSAFUNE, Yuma; MAEGAWA, Yusuke; HIRAO, Toshikazu

2E6-31
Oxovanadium(V)-Catalyzed Synthesis of Ureas from Amines and Carbon Dioxide (Grad. Sch. Eng., Osaka Univ.; ACT-C, JST) MORIUCHI, Toshiyuki; º KAWAI, Ryota; HIRAO, Toshikazu

2E6-32
Vanadium (V) Complex-catalyzed Enantioselective Synthesis of Oxa[9]helicene (ISIR, Osaka Univ.) º SAKO, Makoto; TAKIZAWA, Shinobu; TSUJIHARA, Tetsuya; YOSHIDA, Yasushi; KODERA, Junpei; KAWANO, Tomikazu; SASAI, Hiroaki


Nb

2E6-33
Mechanistic Study for Radical Addition Reaction Catalyzed by Niobium and Tantalum Complexes with N,N’-Diaryl-1,4-diaza-1,3-butadiene Ligands (Grad. Sch. Eng. Sci., Osaka Univ.) º NISHIYAMA, Haruka; SAITO, Teruhiko; TSURUGI, Hayato; MASHIMA, Kazushi


Cr

2E6-34
Catalytic Enantioselective Synthesis of P-Stereogenic Phosphines by Molybdenum-Catalyzed Asymmetric Ring-Closing Metathesis Utilizing (π-Arene)chromium Complexes as a Platform (CRC, Hokkaido Univ.; Grad. Sch. Sci., Osaka Pref. Univ.) OGASAWARA, Masamichi; º IKEHATA, Ryohsuke; YA-YI, Tseng; WU, Wei-yi; ARAE, Sachie; YASUDA, Rie; TAKAHASHI, Tamotsu; KAMIKAWA, Ken


Chair: AMAYA, Toru (14:50-15:50)

* 14:40-14:50: interval for laptop PC connection.(2E6-36, 2E6-38, 2E6-39, 2E6-40, 2E6-41)

2E6-36*
Synthesis of Planar Chiral Phosphine-Olefin Ligands Based on a Transition Metal Scaffold and Application in Asymmetric Catalysis (Grad. Sch. Sci., Osaka Pref. Univ.) º TSENG, Ya-yi; OGASAWARA, Masamichi; ARAE, Sachie; TAKAHASHI, Tamotsu; KAMIKAWA, Ken


Mo

2E6-38
Dehalogenative Silylation of α-Halocarbonyl Compounds Catalyzed by Dinuclear Molybdenum Complexes (Grad. Sch. Eng. Sci., Osaka Univ.) º KANDO, Shun; TSURUGI, Hayato; MASHIMA, Kazushi

2E6-39
Molybdenum-Catalyzed Regioselective Hydrosilylation of Allenes (Grad. Sch. Nat. Sci. Technol., Okayama Univ.) º ISHIKAWA, Sae; ASAKO, Sobi; TAKAI, Kazuhiko


Re

2E6-40
Rhenium-Catalyzed Synthesis of 1,4,5,6-Tetrahydro-2H-inden-2-ones via the anti-Markovnikov Addition Reaction of Methanetricarboxylates to 1,6-Diynes (Grad. Sch. Nat. Sci. Technol., Okayama Univ.) º HORI, Shunsuke; MURAI, Masahito; TAKAI, Kazuhiko

2E6-41
Rhenium-Catalyzed Synthesis of 1,3-Diiminoisoindolinones via C-H Bond Activation (Grad. Sch. Pharm., The Univ. of Tokyo) º WANG, Zijia; SUEKI, Shunsuke; KANAI, Motomu; KUNINOBU, Yoichiro


Fe

Chair: TAKIZAWA, Shinobu (16:00-17:00)

* 15:50-16:00: interval for laptop PC connection.(2E6-43, 2E6-44, 2E6-46, 2E6-48)

2E6-43
Iron-Catalyzed Directed Arylation and Alkenylation of C(sp3)-H Bonds with Organoboron Compounds (Grad. Sch. Sci., The Univ. of Tokyo) º ITABASHI, Yuki; SHANG, Rui; ILIES, Laurean; NAKAMURA, Eiichi

2E6-44*
Selectivity Switch in Iron-Catalyzed Reaction of Amides with Alkynes via Directed C(sp2)-H Bond Activation (Grad. Sch. Sci., The Univ. of Tokyo) º MATSUBARA, Tatsuaki; ILIES, Laurean; NAKAMURA, Eiichi

2E6-46*
Iron-Catalyzed Enantioselective Cross-Coupling Reactions of Racemic α-Haloesters (ICR, Kyoto Univ.; Grad. Sch. Eng., Kyoto Univ.) º ADAK, Laksmikanta; JIN, Masayoshi; NAKAMURA, Masaharu

2E6-48
Iron-Catalyzed Enantioselective Carbometalation of Azabicyclic Alkenes (ICR, Kyoto Univ.; Grad. Sch. Eng., Kyoto Univ.) º SAITO, Shota; ISOZAKI, Katsuhiro; ADAK, Laksmikanta; GOWER, Nicholas John; KAWABATA, Tatsuya; JIN, Masayoshi; ITOH, Takuma; ITO, Shingo; NAKAMURA, Masaharu


Chair: ILIES, Laurean (17:10-18:00)

* 17:00-17:10: interval for laptop PC connection.(2E6-50, 2E6-51, 2E6-52, 2E6-53, 2E6-54)

2E6-50
Anti-Selective Carbosilylation of Alkynes under Iron Catalysis (ICR, Kyoto Univ.; Grad. Sch. Eng., Kyoto Univ.) º NISHIKORI, Tatsushi; NAKAGAWA, Naohisa; IWAMOTO, Takahiro; HATAKEYAMA, Takuji; TAKAYA, Hikaru; NAKAMURA, Masaharu

2E6-51
Synthsis of DMF-protected Iron Nanoparticle and Their Use as Catalysts in Hydrosilylation of Alkene (Fac. Chem. Materials and Bioeng., Kansai Univ.) º NAKAMICHI, Seiya; YANO, Hiroki; KAWASAKI, Hideya; OBORA, Yasushi

2E6-52
DMF-protected Iron Nanoparticles Catalyzed O-arylation (Fac. Chem. Materials and Bioeng., Kansai Univ.) º KIMURA, Jungo; NAKAMICHI, Seiya; KAWASAKI, Hideya; OBORA, Yasushi


Ba

2E6-53
Selective Propargylation of Azo Compounds Using Metallic Barium (Fac. Sci., Chiba Univ.; Grad. Sch. Sci., Chiba Univ.) º HEIMA, Toshihiko; YAMAFUJI, Seiya; SAWAE, Toshiki; YANAGISAWA, Akira


Sr

2E6-54
Development of Sr-mediated Monoalkylation of Amides (Fac. Integrated Arts and Sci., The Univ. of Tokushima) º KUBO, Shigeki; KITAKATA, Saki; OHMURA, Satoshi; MIYOSHI, Norikazu


Saturday, March 28, AM


La

Chair: OHMURA, Toshimichi (09:30-10:30)

* 9:20-9:30: interval for laptop PC connection.(3E6-04, 3E6-05, 3E6-06, 3E6-08, 3E6-09)

3E6-04
Rare Earth Complexes Bearing Metalla-crown Ether Ligand As Catalysts for Copolymerization of CO2-Epoxides (Grad. Sch. Eng. Sci., Osaka Univ.) º TAGAWA, Risa; KLEEMANN, Julian; KITA, Yusuke; OKUDA, Jun; MASHIMA, Kazushi


Sm

3E6-05
Intermolecular Barbier-type coupling reaction using SmI2 (Grad. Sch. Env. Sci., Hokkaido Univ.) º MIYANO, Natsumi; UMEZAWA, Taiki; MATSUDA, Fuyuhiko


B

3E6-06*
Anti-selective carboboration, silaboration and diboration of alkynoates through phosphine organocatalysis (Fac. Sci., Hokkaido Univ.) º NAGAO, Kazunori; OHMIYA, Hirohisa; SAWAMURA, Masaya

3E6-08
Thermally-Induced Generation of Frustrated Lewis Pairs from NHC-Borane Complexes (Grad. Sch. Eng., Osaka Univ.) º KINOSHITA, Takuya; HOSHIMOTO, Yoichi; OHASHI, Masato; OGOSHI, Sensuke

3E6-09
Synthesis of pavine alkaloids with tetra-coordinate benzylboron reagents (Grad. Sch. Fac. Sci. Eng., Shimane Univ.) OHMURO, Yuuki; º NISHIGAICHI, Yutaka


Chair: OHMIYA, Hirohisa (10:40-11:30)

* 10:30-10:40: interval for laptop PC connection.(3E6-11, 3E6-12, 3E6-13, 3E6-14, 3E6-15)

3E6-11
Copper(I)-Catalyzed Regio- and Stereoselective Silicon-Tethering Alkylboration of Unsymmetrical Alkynes (Grad. Sch. Chi Sci. and Eng., Hokkaido Univ.) º IWAMOTO, Hiroaki; KUBOTA, Koji; YAMAMOTO, Eiji; ITO, Hajime

3E6-12
Synthesis and Application of Air-Stable Silylboranes with Super Silyl Group (Sch. Eng., Hokkaido Univ.) º SHISHIDO, Ryosuke; YAMAMOTO, Eiji; ITO, Hajime

3E6-13
4,4'-Bipyridine-Catalyzed Boron-Boron Bond Activation for Diboration of Alkynes (Grad. Sch. Eng., Kyoto Univ.) OHMURA, Toshimichi; º MORIMASA, Yohei; SUGINOME, Michinori


Al

3E6-14
Hydroalumination-Triggered Cyclization of Silylated 1,3-Dien-5-ynes to Polysubstituted Benzenes (Grad. Sch. Sci., Eng., Saitama Univ.) º TOHJIMA, Takayuki; KINOSHITA, Hidenori; MIURA, Katsukiyo

3E6-15
Hydroalumination-Triggered Cyclization of o-(silylethynyl)styrenes to substituted Naphthalenes (Grad. Sch. Sci., Eng., Saitama Univ.) º YAGUCHI, Kazuki; KINOSHITA, Hidenori; MIURA, Katsukiyo


Chair: MITSUDO, Koichi (11:40-12:30)

* 11:30-11:40: interval for laptop PC connection.(3E6-17, 3E6-18, 3E6-19, 3E6-20, 3E6-21)

3E6-17
Hydroalumination-Triggered Cyclization of o-(Silylethynyl)benzyl Ethers to Substituted Indenes (Grad. Sch. Sci., Eng., Saitama Univ.) º FUKUMOTO, Hiroki; KINOSHITA, Hidenori; MIURA, Katsukiyo

3E6-18
Development of Cross-Coupling between Phenol Derivatives and Organo-aluminum Reagents (Grad. Sch. Pharm., The Univ. of Tokyo) º OGAWA, Hiroyuki; WANG, Chao; UCHIYAMA, Masanobu


In

3E6-19
Indium-Catalyzed Reductive Monoalkylation of Aromatic Compounds Using Carboxylic Acids (Fac. Sci. Technol., Tokyo Univ. of Sci.) º TAKAYAMA, Kentaro; MORIYA, Toshimitsu; KONAKAHARA, Takeo; OGIWARA, Yohei; SAKAI, Norio

3E6-20
Indium-Catalyzed Reductive Sulfidation of Esters with Thiols (Fac. Sci. Technol., Tokyo Univ. of Sci.) º KASAI, Shinsei; MIYAZAKI, Takahiro; KONAKAHARA, Takeo; OGIWARA, Yohei; SAKAI, Norio

3E6-21
In-promoted decarboxylative etherification of benzylic carbonates. (Shimane Univ.) º TOKUMARU, Tatsuya; NAKATA, Kenya


Saturday, March 28, PM

Chair: SAKAI, Norio (13:40-14:40)

* 13:30-13:40: interval for laptop PC connection.(3E6-29, 3E6-30, 3E6-31, 3E6-32, 3E6-33, 3E6-34)

3E6-29
Intramolecular Reaction of Alkynes with Silyl Enolates Using Indium Tribromide and Electrophiles (Grad. Sch. Sci., Eng., Saitama Univ.) º NEGISHI, Kenta; KINOSHITA, Hidenori; MIURA, Katsukiyo


Si

3E6-30
Cross-coupling of aryl- and alkenyldimethylsilanes promoted by copper(I) iodide-sodium hydride-ethylene glycol system (Grad. Sch. Fac. Eng., Tokyo Univ. of Agri. and Technol.) TAKEDA, Takeshi; º TAKEDA, Yuichiro; TSUBOUCHI, Akira

3E6-31
Synthesis and Physical Properties of Silicon-Bridged π-Extended Benzodithiophene Derivatives (Grad. Sch. Nat. Sci. Technol., Okayama Univ.) º SATO, Hidehiko; ISOBUCHI, Ryota; MITSUDO, Koichi; SUGA, Seiji


Sn

3E6-32
Development of Stille coupling with quaternary ammonium salts as electrophiles (Grad. Sch. Pharm., The Univ. of Tokyo; RIKEN CSRS) º WANG, Chao; WANG, Dong-yu; UCHIYAMA, Masanobu

3E6-33
Catalytic Dehydrogenative Stannylation of Terminal Alkynes (Sch. Sci. Eng., Meiji Univ.) º OKU, Shinya; TSUCHIMOTO, Teruhisa

3E6-34
Tin-catalyzed Addition-cyclization Reaction of Methylenecyclopropanes (Grad. Sch. Eng., Osaka Univ.) º YAMASHITA, Sho; SHIBATA, Ikuya


Sunday, March 29, AM


Co

Chair: KOIKE, Takashi (09:30-10:30)

* 9:20-9:30: interval for laptop PC connection.(4E6-04, 4E6-05, 4E6-06, 4E6-07, 4E6-08, 4E6-09)

4E6-04
Cobalt-catalyzed Homocoupling of Benzyl Halides (Hiroshima Univ. Graduate School of Engineering) KOMEYAMA, Kimihiro; º IWASHITA, Kento; TAKAKI, Ken

4E6-05
Cobalt-catalyzed Three-Component Coupling Reaction of Aryl Iodides, Allenes, and Aldehydes (Hiroshima Univ. Graduate School of Engineering) KOMEYAMA, Kimihiro; º SAKIYAMA, Shunsuke; TAKAKI, Ken

4E6-06
Cobalt-catalyzed Electrophilic Borylation of Aryl Halides (Hiroshima Univ. Graduate School of Engineering) KOMEYAMA, Kimihiro; º KIGUCHI, Shinnosuke; TAKAKI, Ken

4E6-07
Cobalt-Catalyzed Reductive Three-Component Coupling Reaction of Alkynes, Acrylates and Carbon Dioxide (Grad. Sch. Eng., Kyoto Univ.) º NOGI, Keisuke; FUJIHARA, Tetsuaki; TERAO, Jun; TSUJI, Yasushi

4E6-08
trans -Azobenzene-Tethered Bis(Co(III)-salen) as a Self-Assembly Cooperative Catalyst for Asymmetric Epoxide Ring-Opening Reaction (Grad. Sch. Chem. Sci. Technol., Tokyo Univ. of Sci.) º DOI, Masato; HAYASI, Yusuke; IRIE, Ryo; KUWAHARA, Yutaka; KURIHARA, Seiji; IMAHORI, Tatsushi

4E6-09
Withdrawn


Ru

Chair: KOCHI, Takuya (10:40-11:30)

* 10:30-10:40: interval for laptop PC connection.(4E6-11, 4E6-12, 4E6-13, 4E6-14, 4E6-15)

4E6-11
Metalo-Porphyrin-Catalyzed [4+2} cycloaddition of Ketones with Dienes (Grad. Sch. Eng., Kyoto Univ.) º KURODA, Daiki; KURAHASHI, Takuya; MATSUBARA, Seijiro

4E6-12
Metal-Porphyrin-Catalyzed Dehydrative [4+2] Cycloaddition of Unsaturated Imines and Aldehydes (Grad. Sch. Eng., Kyoto Univ.) º MAEDA, Kazuki; KURAHASHI, Takuya; MATSUBARA, Seijiro

4E6-13
Highly Diastereoselective Synthesis of CF3-Subustituted Spirooxazolines by Photoredox Catalysis (Chem. Res. Lab., Tokyo Tech) º NOTO, Naoki; MIYAZAWA, Kazuki; KOIKE, Takashi; AKITA, Munetaka

4E6-14
Ru(II)-Pheox catalyzed asymmetric intramolecular cyclopropanation of diazoesters containing α, β-unsaturated carbonyl group and computational analysis as for the transition state. (Toyohashi Univ. of Tech.; CONFLEX Corporation) º NAKAGAWA, Yoko; CHANTHAMATH, Soda; NAKAYAMA, Naofumi; GOTO, Hitoshi; SHIBATOMI, Kazutaka; IWASA, Seiji

4E6-15
Tandem asynmmetry α,β-unsaturated carbonyl compound and aldehyde catalyzed by chiral Phebox-Ru complexes. (Grad. Sch. Eng., Nagoya Univ.) º UBUKATA, Shino; ITO, Jun-ichi; NISHIYAMA, Hisao


Chair: KOMEYAMA, Kimihiro (11:40-12:30)

* 11:30-11:40: interval for laptop PC connection.(4E6-17, 4E6-18, 4E6-19, 4E6-20, 4E6-21)

4E6-17
Control of the Regioselectivity in Ruthenium-catalyzed Allylic Substitution Reactions (Grad. Sch. Eng., Kyoto Univ.; Kyoto Univ. C-PiER; ICR, Kyoto Univ.) KONDO, Teruyuki; º IURA, Yoshihito; KIMURA, Yu; TOSHIMITSU, Akio

4E6-18
Selectivity and Substituent Effect of Ruthenium-Catalyzed Monoalkenylation of Aromatic Ketones via Cleavage of Carbon-Heteroatom Bonds (Fac. Sci. Tech., Keio Univ.) º KONDO, Hikaru; KOCHI, Takuya; KAKIUCHI, Fumitoshi

4E6-19
Efficient Synthesis of Polycyclic Aromatic Hydrocarbons Using Ruthenium-catalyzed C-O Arylation (Fac. Sci. Tech., Keio Univ.) º SUZUKI, Yusuke; KOCHI, Takuya; KAKIUCHI, Fumitoshi

4E6-20
Enantioselective Propargylic Substitution Reaction Using Hybrid Ruthenium Complexes Bearing Chiral Phosphoramide Moiety (The University of Tokyo Institute of Engineering Innovation, School of Engineering) º SENDA, Yasushi; NAKAJIMA, Kazunari; NISHIBAYASHI, Yoshiaki

4E6-21
Ruthenium-Catalyzed Intermolecular Annulation of Naphthyl Silanes and Alkynes via Si-H and C-H bonds cleavage (Fac. Sci. Eng., Chuo Univ.) º SUGITA, Kengo; TOKORO, Yuichiro; FUKUZAWA, Shin-ichi

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