The 100th Annual Meeting of The Chemical Society of Japan

Date: March 22nd - 25th, 2020

Venue: Noda Campus, Tokyo University of Science, Chiba, Japan

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Room H8

Lecture Hall Bldg. K609


[Organic Chemistry -Reaction and Synthesis- Organometallic Compounds]


Sunday, March 22, AM


Ir

Chair: IWAI, Tomohiro (09:00-10:10)

* 8:50-9:00: interval for laptop PC connection.(1H8-01, 1H8-02, 1H8-03, 1H8-04, 1H8-05, 1H8-06, 1H8-07)

1H8-01
Iridium-Catalyzed Tandem CH Transformations 1: Synthesis of 2-Methylbenzofurans through Cyclization of Ethyl 2-Methylphenyl Ethers (Grad. Sch. Eng., Kyoto Univ.) º YAGI, Kaito; OHMURA, Toshimichi; SUGINOME, Michinori

1H8-02
Iridium-Catalyzed Tandem CH Transformations 2: Synthesis of 2,3-Dihydrobenzofuran Derivatives through Cyclization of Phenyl 2-Siloxypropyl Ethers (Grad. Sch. Eng., Kyoto Univ.) º KUSAKA, Satoshi; OHMURA, Toshimichi; SUGINOME, Michinori

1H8-03
Iridium-Catalyzed Tandem CH Transformations 3: Cross-Coupling of Saturated Cyclic Ethers and Amines with Norbornene (Grad. Sch. Eng., Kyoto Univ.) º OHTANI, Naoki; OHMURA, Toshimichi; SUGINOME, Michinori

1H8-04
Iridium-Catalyzed [2+2+2] Cycloaddition of Bibenzothiophen-Linked Diynes with Nitriles (Coll. Sci. Eng., Aoyama Gakuin Univ.) SAWANO, Takahiro; º SUGIURA, Ryosuke; URASAWA, Kazuki; TAKEUCHI, Ryo

1H8-05
Asymmetric Synthesis of Dihydrobenzofurans from Allyl Phenyl Carbonate Derivatives via Sequential Allylic Substitution and Intramolecular Hydroarylation (Grad. Sch. Sci., Osaka City Univ.) º SAKAMOTO, Kana; NISHIMURA, Takahiro

1H8-06
Iridium-Catalyzed Enantioselective Addition of Benzamides to Vinyl Ethers (Grad. Sch. Sci., Osaka City Univ.) º MURAKAMI, Kotone; NISHIMURA, Takahiro

1H8-07
Iridium-Catalyzed Stereoselective [3+2] Annulation of α-Oxocarboxylic Acids with 1,3-Dienes (Grad. Sch. Sci., Osaka City Univ.) º YABE, Ryota; MURAKAMI, Kotone; NISHIMURA, Takahiro


Sunday, March 22, PM

Chair: KANYIVA, Stephen-kyalo (12:40-13:40)

* 12:30-12:40: interval for laptop PC connection.(1H8-23, 1H8-25, 1H8-26, 1H8-27, 1H8-28)

1H8-23*#
Catalytic Hydrogenation and Dehydrogenation of Heterocyclic Compounds Based on C(sp3)-H Activation (Fac. Sci., Hokkaido Univ.) º ZHANG, Deliang; IWAI, Tomohiro; SAWAMURA, Masaya

1H8-25
Hydrogen Bond-Controlled Iridium-Catalyzed ortho-selective C-H Borylation of Thioanisoles (IMCE, Kyushu Univ.; Grad. Sch. Eng. Sci., Kyushu Univ.; Coll. Sci., Rikkyo Univ.) º ZENG, Jialin; NAITO, Morio; TORIGOE, Takeru; YAMANAKA, Masahiro; KUNINOBU, Yoichiro

1H8-26
Site- and Enantioselective C-H Borylation of N-Containing 6-Membered Heterocycles by Cooperative Iridium/Chiral Lewis Acid Catalysis (Grad. Sch. Eng., Kyoto Univ.) º SHIMAZAKI, Yuto; TAKEUCHI, Koji; NAKAO, Yoshiaki

1H8-27
Iridium-Catalyzed Asymmetric Allylation of Azaindoles via Dynamic Kinetic Asymmetric Transformation (Coll. Sci. Eng., Aoyama Gakuin Univ.) SAWANO, Takahiro; º MATSUI, Takeshi; TAKEUCHI, Ryo

1H8-28
Iridium-Catalyzed Hydroalkylation of Simple Alkenes with Malonic Amides and Malonic Esters (Coll. Sci. Eng., Aoyama Gakuin Univ.) SAWANO, Takahiro; º ONO, Masaki; IWASA, Ami; TAKEUCHI, Ryo


Chair: SAWANO, Takahiro (13:50-15:00)

* 13:40-13:50: interval for laptop PC connection.(1H8-30, 1H8-32, 1H8-33, 1H8-34, 1H8-35, 1H8-36)

1H8-30*#
Iridium(III)-Catalyzed Direct C(sp2) and C(sp3)-H Alkynylation of 2-Acyl Imidazoles (Grad. Sch. Eng., Osaka Univ.) º MAHATO, Sanjit Kumar; CHATANI, Naoto

1H8-32
Enantioselective Formal C-H Conjugate Addition of α, β-unsaturated Amides to Electron-Deficient Alkenes by Chiral Iridium Catalysts (Sch. Advanced Sci. Eng., Waseda Univ.) º KOJIMA, Masafumi; ONODA, Sahoko; KANYIVA, Kyalo Stephen; SHIBATA, Takanori


Pt

1H8-33#
Platinum-Catalyzed anti-Markovnikov Hydrochlorination of Terminal Alkynes (Grad. Sch. Sci., Eng., Saitama Univ.) º NISHIHARA, Hiroki; MIURA, Katsukiyo; KINOSHITA, Hidenori

1H8-34
Platinum-Catalyzed anti-Markovnikov Hydrochlorination of Propargylic Alcohols (Grad. Sch. Sci., Eng., Saitama Univ.) º TOMIYAMA, Ryota; MIURA, Katsukiyo; KINOSHITA, Hidenori

1H8-35
Platinum-Catalyzed Hydrohalogenation of Internal Alkynes (Grad. Sch. Sci., Eng., Saitama Univ.) º NAKASHIMA, Satsuki; MIURA, Katsukiyo; KINOSHITA, Hidenori

1H8-36
Enantioselective Synthesis of Azepine-Fused Planar-Chiral Ferrocenes by Pt-Catalyzed Cycloisomerization (Sch. Advanced Sci. Eng., Waseda Univ.) º OKAMURA, Moeka; ITO, Mamoru; KANYIVA, Kyalo Stephen; SHIBATA, Takanori


Chair: OKAMOTO, Kazuhiro (15:10-16:20)

* 15:00-15:10: interval for laptop PC connection.(1H8-38, 1H8-39, 1H8-40, 1H8-41, 1H8-42, 1H8-44)

1H8-38
Platinum-Catalyzed Dearomative Aromatic Ene Reaction (Sch. Mater. & Chem. Tech., Tokyo Tech.) º OUCHI, Seiya; KOSHIKAWA, Takumi; TANAKA, Ken

1H8-39
Platinum-Silylene Complex-Catalyzed Cyclodimerization of Diaryl Alkynes via Carbon-Hydrogen Bond Cleavage (Grad. Sch. Eng., Osaka Univ.) º YOSHIDA, Tomoki; OTA, Masaya; KATO, Tsuyshi; TOBISU, Mamoru

1H8-40
Synthesis of Carboxylic Acid Amides by Platinum Complex-Catalyzed Reaction of Allylic Halides and Formamides without Carbon Monoxide (Grad. Sch. Eng., Kyoto Univ.) º TANAKA, Nobuyuki; KIMURA, Yu; KONDO, Teruyuki


Ce

1H8-41
Cerium(IV) Carboxylate Catalyzed Lactonization of 2-Alkylbenzoic Acids via Intramolecular C-H/O-H Oxidative Coupling (Grad. Sch. Eng. Sci., Osaka Univ.) º TAMAKI, Sota; SHIRASE, Satoru; TSURUGI, Hayato; MASHIMA, Kazushi


Si

1H8-42*
Development of Novel Synthetic Method for Trialkylsilylboranes (Grad. Sch. Eng., Hokkaido Univ.; WPI-ICReDD, Hokkaido Univ.) º SHISHIDO, Ryosuke; UESUGI, Minami; KUBOTA, Koji; ITO, Hajime

1H8-44
Zinc/Indium-Lewis-Acid-Catalyzed Dehydrogenative Silylation/Hydrosilylation Relay Reaction of Terminal Alkynes (Sch. Sci. Eng., Meiji Univ.) º TANI, Tomohiro; TANABE, Mikio; SOHMA, Yudai; TSUCHIMOTO, Teruhisa


Chair: TORIUMI, Naoyuki (16:30-17:30)

* 16:20-16:30: interval for laptop PC connection.(1H8-46, 1H8-47, 1H8-48, 1H8-49, 1H8-50, 1H8-51)

1H8-46
Development of 7-Membered Dialkoxysilyl Group and its Application (Dep. Chem., Sch. Sci., Kyoto Univ.) º SAITO, Hayate; SHIMOKAWA, Jun; YORIMITSU, Hideki

1H8-47
Regioselective Addition of Silyllithiums to Propargyl Amines (Dep. Chem., Sch. Sci., Kyoto Univ.) º SATO, Tomohiko; KARAD, Somnath; SHIMOKAWA, Jun; YORIMITSU, Hideki


Cu

1H8-48
Development of disilanolate as a new silylating reagent (Dep. Chem., Sch. Sci., Kyoto Univ.) º YAMAGISHI, Hiroki; SHIMOKAWA, Jun; YORIMITSU, Hideki

1H8-49
Cu-catalyzed Electrophilic Amination of trialkoxyarylsilane (Dep. Chem., Sch. Sci., Kyoto Univ.) º HITOSHIO, Kenshiro; SAITO, Hayate; SHIMOKAWA, Jun; YORIMITSU, Hideki

1H8-50
Copper-Catalyzed Sila-acylation of Allenes Using Esters and a Silylborane (Grad. Sch. Eng., Kyoto Univ.) º SUDA, Katsushi; TSUJI, Yasushi; FUJIHARA, Tetsuaki

1H8-51
Copper Catalyzed C−H Amination of Amide-Substituted Ferrocenes (Fac. Sci. Eng., Chuo Univ.) º HORIKAWA, Nao; SUZUKI, Kouta; KANEMOTO, Kazuya; FUKUZAWA, Shin-ichi


Chair: KANEMOTO, Kazuya (17:40-18:50)

* 17:30-17:40: interval for laptop PC connection.(1H8-53, 1H8-55, 1H8-56, 1H8-57, 1H8-58, 1H8-59)

1H8-53*#
Copper-Catalyzed Radical Amination with N-Fluorobenzenesulfonimide (RIIS, Okayama Univ.) º IWASAKI, Masayuki; NONAKA, Kosei; IKINAGA, Yuka; NISHIHARA, Yasushi

1H8-55
Copper-Catalyzed Intermolecular Coupling between Acylsilanes and N-Alkylimines under Photoirradiation Conditions (Fac. Sci., Gakushuin Univ.) º ISHINO, Tomoki; NAKAYAMA, Hiromi; HAYASHI, Daiki; ISHIDA, Kento; KUSAMA, Hiroyuki

1H8-56
Generation and Reactions of Copper-Carbene Complex Intermediate Utilizing Photoisomerization of Acylsilanes (Fac. Sci., Gakushuin Univ.) º TAKEUCHI, Taiichi; ISHIDA, Kento; KUSAMA, Hiroyuki

1H8-57#
Synthesis of tetrahydroquinoline with site-selective C-H bond functionalization through IH-Redox CDC reaction (Sch. Life Sci. Tech., Tokyo Tech.) º YU, Guo; ZHANG, Xuhai; LI, Guangzhe; NAKAMURA, Hiroyuki

1H8-58
Cu-catalyzed Selective Three-Component Reaction of 2-Bromocarbonyls and Two Different Olefins (Fac. Eng., Yamaguchi Univ.) º SATO, Daisuke; MATSUDA, Kyosuke; HIRATA, Goki; NISHIKATA, Takashi

1H8-59
Cu/Amine/Phenol Combined Catalyst System Enables Alpha-Tertiary Alkylation of ketones (Fac. Eng., Yamaguchi Univ.) º ISHIDA, Yuto; KUROSE, Ayako; HIRATA, Goki; NISHIKATA, Takashi


Monday, March 23, AM


Ru

Chair: NAGANAWA, Yuki (09:00-10:10)

* 8:50-9:00: interval for laptop PC connection.(2H8-01, 2H8-02, 2H8-03, 2H8-04, 2H8-05, 2H8-06, 2H8-07)

2H8-01
DMF-stabilized ruthenium nanoparticles catalyzed α-alkylation of nitriles (Fac. Chem. Materials and Bioeng., Kansai Univ.) º NAGATA, Tatsuki; OBORA, Yasushi

2H8-02
Ruthenium nanoparticles catalyzed α-alkylation reaction of amide with alcohols (Fac. Chem. Materials and Bioeng., Kansai Univ.) º IGUCHI, Honami; OBORA, Yasushi

2H8-03
Hydrosilylation of alkenes catalyzed by DMF-protected Ru nanoparticles (Fac. Chem. Materials and Bioeng., Kansai Univ.) º FUJISAWA, Mizuho; OBORA, Yasushi

2H8-04#
Ruthenium(II)-Catalyzed Acyloxylation of Acyl Imidazoles with Benzoic Acid (Grad. Sch. Eng., Osaka Univ.) º WANG, Chen-an; CHATANI, Naoto

2H8-05
Catalytic Allylation Reaction Using Allylic Ethers Catalyzed by a Zero-valent Ruthenium Complex Bearing a Tetradentate Phosphine Ligand (Sch. Sci., Tokyo Tech.) º WATANABE, Yuta; HIRATAKA, Yo; TAKAHASHI, Kohei; IWASAWA, Nobuharu

2H8-06
Ruthenium-Catalyzed ortho C-H Borylation of Phenol Derivatives (Sch. Sci., Tokyo Tech.) º HOMMA, Yuki; FUKUDA, Kazuishi; IWASAWA, Nobuharu; TAKAYA, Jun

2H8-07
Ruthenium-catalyzed dehydrogenation of alcohols using carbodiimide and its kinetic analysis (Musashino Univ.) º WATANABE, Azumi; MATSUYAMA, Mizuki; ARATA, Kanemaki; KATAKAWA, Kazuaki; SUEKI, Shunsuke; ANADA, Masahiro


Chair: TAKAHASHI, Kohei (10:20-11:30)

* 10:10-10:20: interval for laptop PC connection.(2H8-09, 2H8-10, 2H8-11, 2H8-12, 2H8-13, 2H8-14, 2H8-15)

2H8-09
Highly Efficient Ruthenium-Catalyzed Addition of Disulfides to Allenes (Grad. Sch. Eng., Kyoto Univ.) º TANAKA, Ryosuke; KIMURA, Yu; KONDO, Teruyuki

2H8-10
Ruthenium-Catalyzed Allylation of Thiols with Allylic Amines via Cleavage of a C-N Bond (Grad. Sch. Eng., Kyoto Univ.) º ISHIKAWA, Yuki; KIMURA, Yu; KONDO, Teruyuki

2H8-11
Catalytic Synthesis of Silylated Conjugated Trienes by Cross-Dimerization and Their Applications to Cross-Coupling (BASE, Tokyo Univ. of Agri. and Technol.) º ARATA, Eri; SAITO, Ryo; KOMINE, Nobuyuki; HIRANO, Masafumi

2H8-12#
Kinetic Resolution of Axially Chiral 1-Arylnaphthalenes through the Arene Hydrogenation with Chiral Ruthenium Catalyst (Fac. Sci., Kyushu Univ.) º WON, Sungyong; JIN, Yushu; KUWANO, Ryoichi

2H8-13
Selective Hydrosilylation of Allyl Polyethylene Glycols (IRC3, AIST) º INOMATA, Koya; NAGANAWA, Yuki; GUO, Haiqing; SATO, Kazuhiko; NAKAJIMA, Yumiko

2H8-14
Hydrogenation of esters catalyzed by Cp*Ru(II) complexes (Grad. Sch. Chem. Sci. and Eng., Hokkaido Univ.; Grad. Sch. Eng., Hokkaido Univ.) º OZAKI, Kazuma; ARAI, Noriyoshi; OHKUMA, Takeshi

2H8-15
Ruthenium-Catalyzed Cycloisomerization of 2-Alkynylphenylboronic Acids via 1,2-Carbon Migration (Fac. Sci., TUS) º KONDA, Fumihito; WATANABE, Takuma; MUTOH, Yuichiro; SAITO, Shinichi


Monday, March 23, PM

Chair: MUTOH, Yuichiro (12:40-13:50)

* 12:30-12:40: interval for laptop PC connection.(2H8-23, 2H8-24, 2H8-26, 2H8-27, 2H8-28)

2H8-23#
Ruthenium-Catalyzed Enantioselective Propargylic Reduction of Propargylic Alcohols with Hantzsch Esters (Fac. Eng., The Univ. of Tokyo) º DING, Haowei; NAKAJIMA, Kazunari; SAKATA, Ken; NISHIBAYASHI, Yoshiaki

2H8-24*#
Ruthenium-Catalyzed Enantioselective Propargylic Substitution Reactions with Phosphine Oxides (Grad. Sch. Eng., The Univ. of Tokyo) º LIU, Shiyao; TANABE, Yoshiaki; KURIYAMA, Shogo; SAKATA, Ken; NISHIBAYASHI, Yoshiaki

2H8-26#
Degradation of β-O-4 Linkage by Cyclopentadienone Metal Complexes (Grad. Sch. Eng., The Univ. of Tokyo) º KISHINO, Masamichi; KUSUMOTO, Shuhei; NOZAKI, Kyoko


Co

2H8-27
Cobalt-Catalyzed Double [2 + 2 + 2] Cycloaddition for Trimerization of α,ω-Diynes (Fac. Sci. Technol., TUS) º NAKAMURA, Koji; NAKATSUKA, Hitoshi; OGIWARA, Yohei; SAKAI, Norio

2H8-28*#
(E)-Selective Cross-dimerization of Terminal Alkynes Catalyzed by a Cobalt Complex with a Sterically Demanding Phenanthroline Ligand (Grad. Sch. Eng. Sci., Osaka Univ.) º UEDA, Yohei; TSURUGI, Hayato; MASHIMA, Kazushi


Mn

Chair: ASAKO, Sobi (14:00-15:10)

* 13:50-14:00: interval for laptop PC connection.(2H8-31, 2H8-32, 2H8-33, 2H8-35, 2H8-36)

2H8-31
Additive Effects of Potassium Alkoxides for Transesterification Catalyzed by Manganese Complexes (Grad. Sch. Eng. Sci., Osaka Univ.) º AKEBI, Shin-ya; KATO, Daiki; HIRAI, Takahiro; NAGAE, Haruki; MASHIMA, Kazushi

2H8-32
Substrate Scope for The Esterification of Aliphatic Amides by Manganese-Potassium Catalyst (Grad. Sch. Eng. Sci., Osaka Univ.) º KATAYAMA, Shoichiro; HIRAI, Takahiro; KATO, Daiki; MAI, Binh Khanh; NAGAE, Haruki; HIMO, Fahmi; MASHIMA, Kazushi

2H8-33*#
Mechanistic study on The Esterification of Tertiary Amides Mediated by Manganese-Potassium Catalysis (Grad. Sch. Eng. Sci., Osaka Univ.) º HIRAI, Takahiro; KATO, Daiki; MAI, Binh Khanh; KATAYAMA, Shoichiro; NAGAE, Haruki; HIMO, Fahmi; MASHIMA, Kazushi

2H8-35#
Manganese-catalyzed C(sp3)-H Bromination (Grad. Sch. Eng. Sci., Kyushu Univ.) º SNEH, Kumar; TORIGOE, Takeru; KUNINOBU, Yoichiro


Sc

2H8-36*#
Scandium-Catalyzed Diastereoselective [3+2] Annulation of Aldimines with Alkenes via sp3 C−H Activation (RIKEN CSRS) º CONG, Xuefeng; HOU, Zhaomin


Chair: SUZUKI, Itaru (15:20-16:30)

* 15:10-15:20: interval for laptop PC connection.(2H8-39, 2H8-41, 2H8-42, 2H8-43, 2H8-44, 2H8-45)

2H8-39*#
Experimental and Theoretical Studies on Regiodivergent C-H Alkylation of Quinolines with Alkenes by Rare-Earth Catalysts (RIKEN CSRS) º LOU, Shaojie; NISHIURA, Masayoshi; HOU, Zhaomin


Ge

2H8-41
Structural Determination of Allylgermanes and the Effects of the Coordination Structure on the Reactivity of Allylgermanes (Grad. Sch. Eng., Osaka Univ.) º MINAMI, Yohei; NISHIDA, Kento; KONISHI, Akihito; YASUDA, Makoto

2H8-42
Group 16 Element Introduction Reactions to Germanium(II) Center of a Stable Germylene Bearing TbtCH2 Group (ICR, Kyoto Univ.) º YUKIMOTO, Mariko; TOKITOH, Norihiro


Al

2H8-43
Synthesis of Phosphino-substituted Pheox-aluminum Complexes and Their Application to Catalysts for Regioselective Cycloaddition Reaction (Grad. Sch. Eng., Osaka Univ.) NISHIMOTO, Yoshihiro; º KIDO, Kazuki; YASUDA, Makoto


Re

2H8-44
Rhenium-catalyzed Selective Synthesis of Two Kinds of Products from ο-Ethynylphenyl Carbonyl Compounds and Elecron-rich Alkenes (Sch. Sci., Tokyo Tech.) º TAKANO, Takuto; IWASAWA, Nobuharu

2H8-45
Rhenium-Catalyzed Oxidative Cyclization of ω-Alkynylamides with Pyridine N-oxides as Oxidants Leading to Cyclic Imides (Grad. Sch. Eng., Osaka Univ.) FUKUMOTO, Yoshiya; º MONDA, Shizuki; TAKAMI, Yasuhiro; CHATANI, Naoto


In

Chair: NAGAE, Haruki (16:40-17:40)

* 16:30-16:40: interval for laptop PC connection.(2H8-47, 2H8-49, 2H8-50, 2H8-51, 2H8-52)

2H8-47*#
Mechanistic study of indium-catalyzed C-F bond transformation: New synthetic strategy of fluorinated heterocycles (Grad. Sch. Eng., Osaka Univ.) º YATA, Tetsuji; NISHIMOTO, Yoshihiro; CHIBA, Kouji; YASUDA, Makoto

2H8-49
InI3-Catalyzed Synthesis of Unprotected N-Heterocycles via the Addition of Silyl Enorates into 2H-azirines (Grad. Sch. Eng., Osaka Univ.) º TAKENAKA, Yuya; SHIBATA, Ikuya; SUZUKI, Itaru


Mg

2H8-50
Catalytic Synthesis of Oxaspiro Rings by Annulation of Methylenecyclopropanes with Benzoyl Cyanoalkenes via Intramolecular Oxa-Michael Addition of Enolates (Grad. Sch. Eng., Osaka Univ.) º OGURA, Kazuki; SUZUKI, Itaru; SHIBATA, Ikuya


Sn

2H8-51
Base-Promoted Stannylative Substitution of Aryl Halides with Silylstannanes (Grad. Sch. Eng., Hiroshima Univ.) º HIRAOKA, Yuta; OSAKA, Itaru; YOSHIDA, Hiroto

2H8-52
Binary Remote 1,5-Asymmetric Induction from Allyltin Reagent Containing Phosphate Ester and Its Application to Natural Product Synthesis (Grad. Sch. Nat. Sci. & Tech., Shimane Univ.) º HAYAMI, Kuniyuki; NISHIGAICHI, Yutaka


Tuesday, March 24, AM


Nb

Chair: KOMEYAMA, Kimihiro (09:00-09:40)

* 8:50-9:00: interval for laptop PC connection.(3H8-01, 3H8-02, 3H8-03, 3H8-04)

3H8-01
Niobium catalyzed [2+2+2] cyclization reaction from alkynes and alkenes (Fac. Chem. Materials and Bioeng., Kansai Univ.; TOHO KASEI CO.,LTD.) º SEKII, Yusaku; HATO, Wataru; ISOMURA, Yuto; UCHIDA, Akito; OBORA, Yasushi

3H8-02
Niobium catalyzed synthesis of secondary amide from alkene and nitrile (Fac. Chem. Materials and Bioeng., Kansai Univ.) º MIYAJIMA, Takahiro; OBORA, Yasushi


W

3H8-03
Synthesis and Reactivity of W(0) Complexes with N-Phosphine Oxide-Substituted Imidazolylidenes (Grad. Sch. Eng., Osaka Univ.) º KAWAKITA, Takahiro; HOSHIMOTO, Yoichi; OGOSHI, Sensuke

3H8-04
Electrostatic Interaction-Controlled Regioselective C(sp3)-H Functionalization Using Decatungstate Photocatalyst (IMCE, Kyushu Univ.; Grad. Sch. Eng. Sci., Kyushu Univ.) º ZENG, Jialin; TORIGOE, Takeru; KUNINOBU, Yoichiro


Tuesday, March 24, PM


Pd

Chair: HOSHIMOTO, Yoichi (12:40-13:20)

* 12:30-12:40: interval for laptop PC connection.(3H8-23, 3H8-24, 3H8-25, 3H8-26)

3H8-23
Palladium-Catalyzed Reductive Transformation of Acyl Fluorides via Ligand-Selective Decarbonylation, and the Intermediate (Fac. Sci. Technol., TUS) º HATTORI, Hiroyuki; SAKURAI, Yuka; OGIWARA, Yohei; SAKAI, Norio

3H8-24
Palladium-Catalyzed Intramolecular Cyclization of 2-Aryl-Substituted Aroyl Fluorides Leading to Fluorenones (Fac. Sci. Technol., TUS) º IKAI, Kana; SAKURAI, Yuka; OGIWARA, Yohei; SAKAI, Norio

3H8-25
Pd/Cu-Co-Catalyzed Regiodivergent Ring-Opening C-Si Bond Forming Reactions of 2-Arylaziridines with Silylborane (Grad. Sch. Eng., Osaka Univ.) º AOKI, Shohei; SHIBUTA, Kaoru; TAKEDA, Youhei; MINAKATA, Satoshi

3H8-26
Carbon-Nitrogen Bond Formation at the δ-position through a Sequential Palladium-Catalyzed Dehydrogenation of Valeronitriles (Sch. Eng., Tokyo Univ. of Tech.) º TANIMOTO, Seiji; UENO, Satoshi


Chair: TORIGOE, Takeru (13:30-14:10)

* 13:20-13:30: interval for laptop PC connection.(3H8-28, 3H8-29, 3H8-30, 3H8-31)

3H8-28
Palladium-Catalyzed 1,1-Addition of Bromoalkynes to Alkenes (Grad. Sch. Eng., Osaka Univ.) ANO, Yusuke; º KAWAI, Natsuki; CHATANI, Naoto

3H8-29#
Palladium-Catalyzed [3+2] Oxidative Annulation of Aromatic Amides with Maleimides (Grad. Sch. Eng., Osaka Univ.) º HE, Qiyuan; CHATANI, Naoto

3H8-30
Pd-Catalyzed Dearomative Alkylation of Haloarenes using Malonates as Nucleophiles (Grad. Sch. Advanced Sci. Eng., Waseda Univ.) º MUSHA, Itsuki; KATO, Hiroki; KOMATSUDA, Masaaki; MUTO, Kei; YAMAGUCHI, Junichiro

3H8-31
Pd-Catalyzed Dearomative Alkylation of Heteroaryl Halides using Malonates as Nucleophiles (Grad. Sch. Advanced Sci. Eng., Waseda Univ.) º KATO, Hiroki; MUSHA, Itsuki; KOMATSUDA, Masaaki; MUTO, Kei; YAMAGUCHI, Junichiro


Zn

Chair: TAKEDA, Youhei (16:00-16:50)

* 15:50-16:00: interval for laptop PC connection.(3H8-43, 3H8-44, 3H8-45, 3H8-46, 3H8-47)

3H8-43
Direct Transformation of Tetrafluoroethylene into Trifluorovinylzinc Reagent for Synthesis of Various Trifluorovinyl Derivatives (Grad. Sch. Eng., Osaka Univ.) º ITO, Hideki; KIKUSHIMA, Kotaro; OHASHI, Masato; KAMURA, Ryohei; TAKEDA, Ippei; IWAMOTO, Hiroaki; OGOSHI, Sensuke

3H8-44
Synthesis and Reaction of Ambiphilic Phosphine-Zinc Compounds (Sch. Sci., Tokyo Tech.) º FUKUDA, Kazuishi; IWASAWA, Nobuharu; TAKAYA, Jun

3H8-45
Zinc-catalyzed synthesis of acylsilanes using carboxylic acids and a silylborane (Grad. Sch. Eng., Kyoto Univ.) º TANABE, Sae; TSUJI, Yasushi; FUJIHARA, Tetsuaki

3H8-46
MnCl2-Mediated Preparation of Functionalized N,N-Disubstituted Hydroxylamines from Nitro Compounds and Organozinc Reagents (Sch. Life Sci. Tech., Tokyo Tech.) HATA, Takeshi; º ONODA, Satoshi; SHIGETA, Masayuki; URABE, Hirokazu

3H8-47
Zinc-Catalyzed Markovnikov Selective Hydrosulfenylation of Alkenes using Thiols (Sch. of Med., Fukushima Med. Univ.) º TANIGUCHI, Nobukazu


Sr

Chair: KODAMA, Takuya (17:00-17:50)

* 16:50-17:00: interval for laptop PC connection.(3H8-49, 3H8-50, 3H8-52)

3H8-49
The covenient synthesis of functional silicic compounds via strontium-metallacycle intermediates and their photophysical properties with the substitution effects (Fac. Integrated Arts and Sci., Tokushima Univ. Grad. Sch.) º FUJITA, Mami; NISHIZAWA, Takahiro; OHMURA, Satoshi; UENO, Masaharu; MIYOSHI, Norikazu


Ni

3H8-50*#
Nickel-catalyzed asymmetric allylic alkylation of β-ketoesters via cleavage of C-N bond of allylic amines (Grad. Sch. Eng. Sci., Osaka Univ.) º XIA, Jingzhao; KIRILLOV, Evgueni; HIGASHIDA, Kosuke; NAGAE, Haruki; ZHANG, Wanbin; CARPENTIER, Jean-françois; MASHIMA, Kazushi

3H8-52*#
Enantioselective Construction of α-Chiral Silanes by Nickel-Catalyzed C(sp3)-C(sp3) Cross-Coupling (WPI-ITbM, Nagoya Univ.) º HONG, Yi; WENBIN, Mao; MARTIN, Oestreich


Chair: ANO, Yusuke (18:00-18:50)

* 17:50-18:00: interval for laptop PC connection.(3H8-55, 3H8-56, 3H8-57, 3H8-58, 3H8-59)

3H8-55
Ni-Catalyzed Functional Group Metathesis between Aromatic Esters and Aryl Sulfides (Grad. Sch. Advanced Sci. Eng., Waseda Univ.) º KUROSAWA, Miki; ISSHIKI, Ryota; MUTO, Kei; YAMAGUCHI, Junichiro

3H8-56
Synthesis of Sulfur-Containing Polycyclic Compounds Initiated by Nickel-Catalyzed C(sp2)-S Bond Cleavage along with Consecutive Insertion of Alkynes (Sch. Advanced Sci. Eng., Waseda Univ.) º SEKINE, Ayato; AKINO, Mika; KANYIVA, Kyalo Stephen; SHIBATA, Takanori

3H8-57
Nichel-Catalyzed Intra- and Intermolecular C-H Silylation (IMCE, Kyushu Univ.; Grad. Sch. Eng. Sci., Kyushu Univ.) º FUJI, Kazuto; SEKINE, Kohei; KUNINOBU, Yoichiro

3H8-58
Ni/Co-catalyzed cross-coupling between alkyl tosylates and vinyl sulfonates (Grad. Sch. Eng., Hiroshima Univ.) º KOISHI, Mikinao; MICHIYUKI, Takuya; OSAKA, Itaru; KOMEYAMA, Kimihiro

3H8-59
Ni/Co-catalyzed amidation of alkyl tosylates (Grad. Sch. Eng., Hiroshima Univ.) º MICHIYUKI, Takuya; OSAKA, Itaru; KOMEYAMA, Kimihiro


Wednesday, March 25, AM


Pd

Chair: MUTO, Kei (09:00-10:10)

* 8:50-9:00: interval for laptop PC connection.(4H8-01, 4H8-02, 4H8-03, 4H8-04, 4H8-06)

4H8-01#
Synthetic Study of α-Lipoic Acid using 7-Octenoatenoic Acid as Starting Material (Grad. Sch. Eng. Sci., Osaka Univ.) º NAGAE, Haruki; ABHIJIT, Mal; TSURUGI, Hayato; SEKI, Masahiko; MASHIMA, Kazushi

4H8-02#
Clarification of the Nucleophilic Species in the Carboxylation of Aryl (Pseudo)Halides with CO2 using Pd/Photoredox Dual Catalysts (Sch. Sci., Tokyo Tech.) º CANER, Joaquim; SHIMOMAKI, Katsuya; MURATA, Kei; TORIUMI, Naoyuki; MARTIN, Ruben; IWASAWA, Nobuharu

4H8-03
Synthesis and reactions of Type B mesoionic carbene palladium complexes (Grad. Sch. Eng., Nagoya Inst. of Tech.) º NAKATA, Mirai; HIRASHITA, Tsunehisa

4H8-04*#
Selective Synthesis of Benzophenanthrosilines through a New 1,4-Palladium Migration (Grad. Sch. Eng. Sci., Osaka Univ.) º TSUDA, Tomohiro; KAWAKAMI, Yuka; CHOI, Seung-min; SHINTANI, Ryo

4H8-06*#
Light/Palladium Promoted Benzylic Acylation and Allylation of 2-Alkylbenzophenones (Grad. Sch. Eng., Kyoto Univ.) º MASUDA, Yusuke; MAKITA, Katsuhiko; ISHIDA, Naoki; MURAKAMI, Masahiro


Wednesday, March 25, PM

Chair: TORIUMI, Naoyuki (12:40-13:30)

* 12:30-12:40: interval for laptop PC connection.(4H8-23, 4H8-25, 4H8-27)

4H8-23*#
Xantphos-ligated Palladium Dialkyl Complex as an Effective Precatalyst for Cross-coupling Reactions (Grad. Sch. Eng., Hokkaido Univ.; WPI-ICReDD, Hokkaido Univ.) º TAKAHASHI, Rina; KUBOTA, Koji; ITO, Hajime

4H8-25*#
Palladium-Catalyzed Regioselective C-H Alkenylation of Allylic Alcohols by Phenanthroline-Type Bidentate Auxiliary (Grad. Sch. Eng., Osaka Univ.) º XU, Shibo; HIRANO, Koji; MIURA, Masahiro

4H8-27
Pd-Catalyzed Denitrative Mizoroki-Heck Reaction (Grad. Sch. Advanced Sci. Eng., Waseda Univ.) º ASAHARA, Kotaro; MUTO, Kei; YAMAGUCHI, Junichiro


Chair: UENO, Satoshi (13:40-14:30)

* 13:30-13:40: interval for laptop PC connection.(4H8-29, 4H8-30, 4H8-32, 4H8-33)

4H8-29
Arylation of Terminal Alkenes Bearing a Remote Acetoxy Group by a Pyridine-Isoxazole Palladium Catalyst (Fac. Sci. Tech., Keio Univ.) º MUTO, Kazuma; KAKIUCHI, Fumitoshi; KOCHI, Takuya

4H8-30*
Mono(phosphine)palladium(0)-Catalyzed Hydrosilylation of Electron-Deficient Alkenes 1,3-Dienes, and 1,3,5-Trienes (Grad. Sch. Fac. Eng., Tokyo Univ. of Agri. and Technol.) º KOMINE, Nobuyuki; ABE, Makoto; SUDA, Ryoko; KIKUCHI, Shu; MITSUI, Tatsuo; HIRANO, Masafumi

4H8-32
Stereoselective Synthesis of δ-Alkynylated (Z)-Homoallylic Alcohols Using Palladium-Catalyzed Three-Component Reaction (Grad. Sch. Sci. Eng. For Edu., Univ. of Toyama) º SAKAMOTO, Juri; HORINO, Yoshikazu

4H8-33
Development of catalytic reaction for efficient synthesis of polycyclic aromatic compounds containing seven-membered ring (Grad. Sch. Sci., Nagoya Univ.; WPI-ITbM, Nagoya Univ.; ERATO, JST; CREST, JST) º YAMADA, Keigo; MATSUOKA, Wataru; ITO, Hideto; ITAMI, Kenichiro


Fe

Chair: HORINO, Yoshikazu (14:40-15:40)

* 14:30-14:40: interval for laptop PC connection.(4H8-35, 4H8-37, 4H8-39, 4H8-40)

4H8-35*
Regioselective Annulative π-Extension (APEX) of Aromatic Compounds via Dearomative Activation (Grad. Sch. Sci., Nagoya Univ.; WPI-ITbM, Nagoya Univ.; ERATO, JST; department of chemistry, University of Illinois; CREST, JST) º MATSUOKA, Wataru; ITO, Hideto; SARLAH, David; ITAMI, Kenichiro

4H8-37*#
Iron-catalyzed C-H homocoupling of thiophene compounds (Org. Int. Res. Pro., The Univ. of Tokyo) º DOBA, Takahiro; ILIES, Laurean; RUI, Shang; NAKAMURA, Eiichi

4H8-39
Iron-catalyzed Regio- and Stereoselective Substitution of 2,4-Alkadienal Acetals with Aryl Grignard Reagents (Sch. Life Sci. Tech., Tokyo Tech.) º OGATA, Takato; MIYANAKA, Kento; SHIGETA, Masayuki; HATA, Takeshi; URABE, Hirokazu

4H8-40
Fe-Catalyzed Stereoconvergent tert-Alkylation of beta-Alkyl Styrenes (Fac. Eng., Yamaguchi Univ.) º MATSUMOTO, Junki; NAKASHIMA, Yusei; HIRATA, Goki; NISHIKATA, Takashi


Chair: HASHIMOTO, Toru (15:50-16:40)

* 15:40-15:50: interval for laptop PC connection.(4H8-42, 4H8-44, 4H8-45, 4H8-46)

4H8-42*#
Delineating Mechanism of Iron-catalyzed C-H Amination Reaction using DFT Method (ICR, Kyoto Univ.; FIFC, Kyoto Univ.; Grad. Sch. Eng., Kyoto Univ.) º SHARMA, Akhilesh Kumar; ISEGAWA, Miho; AOKI, Yuma; SUZUKI, Tsuyoshi; HATAKEYAMA, Takuji; TAKAYA, Hikaru; MOROKUMA, Keiji; NAKAMURA, Masaharu

4H8-44
A cationic iron catalyzed conjugate addition of indoles to bulky enones (Fac. Eng., Yamaguchi Univ.) º INISHI, Tsukasa; NISHIKATA, Takashi; HIRATA, Goki

4H8-45#
Iron-Catalyzed Cross Coupling of Organoboron Reagents with Secondary Propargyl Electrophiles (ICR, Kyoto Univ.; Grad. Sch. Eng., Kyoto Univ.) º LU, Siming; AGATA, Ryosuke; ISOZAKI, Katsuhiro; NAKAMURA, Masaharu

4H8-46#
Regio- and Stereoselective Synthesis of Urushiols by Iron-Catalyzed Cross-Coupling Reactions (ICR, Kyoto Univ.; Grad. Sch. Eng., Kyoto Univ.) AGATA, Ryosuke; MATSUDA, Hiroshi; º LU, Siming; ISOZAKI, Katsuhiro; NAKAMURA, Masaharu

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