The 99th Annual Meeting of The Chemical Society of Japan

Date: March 16th - 19th, 2019

Venue: Okamoto Campus, Konan University, Kobe, Japan

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Room H6

Bldg. 8 824


[Organic Chemistry -Reaction and Synthesis- Organometallic Compounds]


Sunday, March 17, AM


Sc

Chair: SUGA, Takuya (09:00-10:00)

* 8:50-9:00: interval for laptop PC connection.(2H6-01, 2H6-03, 2H6-05, 2H6-06)

2H6-01*#
Scandium-Catalyzed C-H Addition of Pyridines to Heteroatom-Functionalized Internal Alkenes (RIKEN CSRS) º ZHAN, Gu; HOU, Zhaomin

2H6-03*#
Rare-Earth-Catalyzed Diastereodivergent [3+2] Annulation of Aldimines with Alkenes via C-H Activation (RIKEN CSRS) º CONG, Xuefeng; HOU, Zhaomin

2H6-05
Sc(OTf)3-Catalyzed Synthesis of 2-Substituted Benzimidazoles (Grad. Sch. Eng., Kyoto Univ.) º MIYABE, Taishi; DI, Yuanjun; KIMURA, Yu; KONDO, Teruyuki


Y

2H6-06#
Yttrium-catalyzed C-H Silylation of Aromatic Heterocycles (RIKEN CSRS) º XU, Wenxuan; HOU, Zhaomin


Chair: NISHII, Yuji (10:10-11:10)

* 10:00-10:10: interval for laptop PC connection.(2H6-08, 2H6-10, 2H6-12)

2H6-08*#
Synthesis of 1,2,3-Trisubstituted Pyrrolidines by Rare-earth-catalyzed Ring Opening Coupling of Cyclopropenes with Aminoalkenes (RIKEN CSRS) º CAO, Tao; HOU, Zhaomin


Ti

2H6-10*#
Low-Valent Titanium-Mediated Direct C-OH Bond Cleavage of Benzyl Alcohol Derivatives and Its Application to C-C Bond Formation (Grad. Sch. Nat. Sci. Technol., Kanazawa Univ.) º SUGA, Takuya; SHIMAZU, Shoma; UKAJI, Yutaka

2H6-12*#
Binuclear Titanium Complex-Catalyzed Enantioselective Epoxidation of Alkenes (Mol. Cat. Res. Center, Chubu Univ.) º SAWANO, Takahiro; YAMAMOTO, Hisashi


Chair: KONDO, Teruyuki (11:20-11:50)

* 11:10-11:20: interval for laptop PC connection.(2H6-15, 2H6-16)

2H6-15
Hydroaminoalkylation of Alkenes Catalyzed by Titanium Complexes bearing a Pyrrolylaluminate Ligand (Grad. Sch. Eng. Sci., Osaka Univ.) º INOUE, Mariko; TSURUGI, Hayato; MASHIMA, Kazushi


Ce

2H6-16*#
Photo-induced decarboxylation of carboxylic acids catalyzed by cerium complexes (Sch. Eng. Sci., Osaka Univ.) º SHIRASE, Satoru; SHINOHARA, Koichi; TSURUGI, Hayato; MASHIMA, Kazushi


Rh

Chair: KAMIKAWA, Ken (12:00-12:30)

* 11:50-12:00: interval for laptop PC connection.(2H6-19)

2H6-19 Young Scholar Lectures of CSJ
Divergent Synthesis of N-Heterocyclic Compounds by Transition Metal-Catalyzed Control of Active Intermediates (Grad. Sch. Eng., Kyoto Univ.) º OKAMOTO, Kazuhiro


Sunday, March 17, PM

Chair: YASUI, Takeshi (13:40-14:40)

* 13:30-13:40: interval for laptop PC connection.(2H6-29, 2H6-30, 2H6-31, 2H6-32, 2H6-33, 2H6-34)

2H6-29#
Synthesis of Arene-Fused Thioxanthenes through Thioether Directed peri-Selective C-H Arylation under Rhodium Catalysis (Grad. Sch. Eng., Osaka Univ.) º MOON, Sanghun; NISHII, Yuji; MIURA, Masahiro

2H6-30
Rhodium-Catalyzed Annulative Coupling of Isothiazole Derivatives through the N-S Bond Cleavage (Grad. Sch. Eng., Osaka Univ.) º MIHARA, Gen; NOGUCHI, Teppei; NISHII, Yuji; MIURA, Masahiro

2H6-31
Acid-catalyzed synthesis of dinaphthyl ethers using naphthols (Grad. Sch. Pharm. Sci., Tohoku Univ.) º TANII, Saori; ARISAWA, Mieko; YAMAGUCHI, Masahiko

2H6-32
Rhodium-catalyzed Synthesis of Unsymmetric Tris(heteroaryl) Compounds (Grad. Sch. Pharm. Sci., Tohoku Univ.) TANII, Saori; º SATO, Kaede; ARISAWA, Mieko; YAMAGUCHI, Masahiko

2H6-33
Rhodium-Catalyzed Thiophosphorylation Reactions of Peptide Disulfides (Grad. Sch. Pharm. Sci., Tohoku Univ.) ARISAWA, Mieko; º FUKUMOTO, Kohei; YAMAGUCHI, Masahiko

2H6-34
Catalytic Asymmetric Synthesis of Planer-Chiral Ferrocenyl Complexes via Rh-Catalyzed Asymmetric Ring-Opening Reaction (Grad. Sch. Sci., Osaka Pref. Univ.) º ISODA, Takamu Isoda; OHYA, Naoki; TSURUSAKI, Akihiro; KAMIKAWA, Ken


Chair: KANYIVA, Stephen-kyalo (14:50-15:50)

* 14:40-14:50: interval for laptop PC connection.(2H6-36, 2H6-37, 2H6-38, 2H6-39, 2H6-40, 2H6-41)

2H6-36
Rh(I)-Catalyzed [2+2+1] Cyclocarbonylation of Diynes under Visible-Light Irradiation (Grad. Sch. Mat. Sci., NAIST) MORIMOTO, Tsumoru; º YAMAGUCHI, Yoshiko; YAMADA, Hiroko; KAKIUCHI, Kiyomi

2H6-37
Rhodium-catalyzed Synthesis of Unsymmetric Bis(heteroaryl) Selenides (Grad. Sch. Pharm. Sci., Tohoku Univ.) ARISAWA, Mieko; YAMAGUCHI, Masahiko; º SUZUKI, Ren

2H6-38
Rhodium-catalyzed Synthesis of Unsymmetric Bis(heteroaryl)phosphines Using Diphosphines and Pentaphenylcyclopentaphosphine (Grad. Sch. Pharm. Sci., Tohoku Univ.) ARISAWA, Mieko; º SAWAHATA, Kyosuke; OHASHI, Keichirou; YAMAGUCHI, Masahiko

2H6-39
Synthesis of Unsymmetric Bis(heteroaryl) Ureas Using Rhodium-catalyzed Heteroaryl Exchange Reaction (Grad. Sch. Pharm. Sci., Tohoku Univ.) ARISAWA, Mieko; º MIZUNO, Taro; KUMADA, Kanako; ITTO, Kaori; TANII, Saori

2H6-40
Enantioselective Synthesis of 5,6,5-Tricyclic Lactone Scaffold via Chiral Rhodium-Catalyzed [2+2+2] Cycloaddition of Enediynes (Grad. Sch. Pharm. Sci., Nagoya Univ.) º KURISAKI, Koutarou; YASUI, Takeshi; YAMAMOTO, Yoshihiko

2H6-41
Synthesis of a Helical Exocyclic Diene Scaffold via Rh-Catalyzed Cycloisomerization of 1,6-Diynes (Grad. Sch. Pharm. Sci., Nagoya Univ.) º KIKUCHI, Tomohiro; YASUI, Takeshi; YAMAMOTO, Yoshihiko


Chair: ARISAWA, Mieko (16:00-17:00)

* 15:50-16:00: interval for laptop PC connection.(2H6-43, 2H6-44, 2H6-45, 2H6-46, 2H6-47, 2H6-48)

2H6-43
Catalytic Enantioselective Synthesis of Heteroatom-Containing Medium-Ring Compounds via Intramolecular [2+2+2] Cycloaddition (Sch. Advanced Sci. Eng., Waseda Univ.) º FUSAMAE, Toru; KANYIVA, Kyalo Stephen; SHIBATA, Takanori

2H6-44
Catalytic and Enantioselective Synthesis of Axially Chiral Bis(dibenzothiophene) Derivatives by Consecutive Intramolecular Dehydro-Diels-Alder Reaction (Sch. Advanced Sci. Eng., Waseda Univ.) º SEKINE, Ayato; MITAKE, Akihito; KANYIVA, Kyalo Stephen; SHIBATA, Takanori

2H6-45#
Rhodium(I)-Catalyzed Alkylation of Aryl Sulfonamides with Alkenes through a Bidentate Chelating System and Related Mechanistic Studies (Grad. Sch. Eng., Osaka Univ.) º REJ, Supriya; CHATANI, Naoto

2H6-46
Rhodium-Catalyzed Coupling Reaction of Arylboronic Acids with α,β-Unsaturated Carboxylic Acids (Grad. Sch. Sci., Osaka City Univ.) º YOSHIMOTO, Risa; USUKI, Yoshinosuke; SATOH, Tetsuya

2H6-47
8-Quinolinolato-Rhodium-Catalyzed anti-Markovnikov Hydroamination of Terminal Alkynes with Aromatic Primary Amines (Fac. Sci. Tech., Keio Univ.) º MORIMOTO, Yoshihiko; HAMADA, Moe; KOCHI, Takuya; KAKIUCHI, Fumitoshi

2H6-48
Novel Hydroaminative Cyclization of Enynes via (Amino)carbene Intermediates Catalyzed by a Rhodium Complex (Fac. Sci. Tech., Keio Univ.) º TAKANO, Shotaro; SHIOMI, Ryosuke; KOCHI, Takuya; KAKIUCHI, Fumitoshi


Monday, March 18, AM


Rh

Chair: NISHIMURA, Takahiro (09:00-10:00)

* 8:50-9:00: interval for laptop PC connection.(3H6-01, 3H6-02, 3H6-03, 3H6-04, 3H6-06)

3H6-01
Rhodium-Silylenoid Formation-Based Catalytic Cyclization: Construction of Seven-Membered Silacarbocycles (Grad. Sch. Eng., Kyoto Univ.) º SASAKI, Ikuo; OHMURA, Toshimichi; SUGINOME, Michinori

3H6-02
Modified Cp-Rhodium(III)-Catalyzed Oxidative C-H Bond Olefination of Acrylamides (Sch. Mater. & Chem. Tech., Tokyo Tech.) º YOSHIMURA, Ryo; SHIBATA, Yu; TANAKA, Ken

3H6-03
Electron-Deficient Cp-Rhodium(III)-Catalyzed Directing Group-Free C-H Functionalization (Sch. Mater. & Chem. Tech., Tokyo Tech.) º TAKAHASHI, Hiroto; SHIBATA, Yu; HONJO, Yusaku; TANAKA, Ken

3H6-04*#
Modified Cp-Rhodium(III)-Catalyzed Coupling Reactions of Heterole-Carboxamides with Alkynes via C-H Bond Cleavage (Sch. Mater. & Chem. Tech., Tokyo Tech.) º YAMADA, Takayuki; SHIBATA, Yu; TANAKA, Ken

3H6-06
Modified Cp-Rhodium(III)-Catalyzed C-H Halogenation of O-Phenyl Carbamates (Sch. Mater. & Chem. Tech., Tokyo Tech.) º TANAKA, Jin; SHIBATA, Yu; TERASAWA, Jyunichi; JOSEPH, Anton; TANAKA, Ken


Chair: SEMBA, Kazuhiko (10:10-11:10)

* 10:00-10:10: interval for laptop PC connection.(3H6-08, 3H6-09, 3H6-10, 3H6-11, 3H6-12, 3H6-13)

3H6-08
Enantioselective Synthesis of Unsymmetrical Helicene-Like Molecules by Rhodium-Catalyzed Cycloaddition Reactions (Sch. Mater. & Chem. Tech., Tokyo Tech.) º KINOSHITA, Suzuka; SHIBATA, Yu; TANAKA, Ken

3H6-09
Enantioselective Synthesis of Aza[7]helicene-like Molecules by Rhodium-Catalyzed Cycloaddition Reactions (Sch. Mater. & Chem. Tech., Tokyo Tech.) º HANADA, Kyoichi; HAYASE, Norihiko; SHIBATA, Yu; TANAKA, Ken

3H6-10
Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to 2H-Chromene (Grad. Sch. Sci., Osaka City Univ.) º UMEDA, Moeko; SAKAMOTO, Kana; NAGAI, Tomotaka; NAGAMOTO, Midori; EBE, Yusuke; NISHIMURA, Takahiro

3H6-11
Rhodium-Catalyzed Asymmetric [2+2+2] Cycloaddition of 1,6-Enynes with Secondary Allyl Alcohols (Sch. Mater. & Chem. Tech., Tokyo Tech.) º SUZUKI, Shunsuke; SHIBATA, Yu; TANAKA, Ken

3H6-12
Rhodium Complex-Catalyzed Decarbonylative Coupling of 1H-indan-1,2,3-triones with 2-Norbornene (Grad. Sch. Eng., Kyoto Univ.) º ITO, Daiki; KIMURA, Yu; KONDO, Teruyuki

3H6-13
Synthesis of Dibenzotetracenediones by Rhodium-Catalyzed [2+2+2] Cycloaddition/Aromatization Reaction (Sch. Mater. & Chem. Tech., Tokyo Tech.) º AIDA, Yukimasa; SHIBATA, Yu; TANAKA, Ken


Chair: SHIBATA, Yu (11:20-12:30)

* 11:10-11:20: interval for laptop PC connection.(3H6-15, 3H6-16, 3H6-17, 3H6-18, 3H6-19, 3H6-21)

3H6-15
Synthesis and Reactions of Cp-Rhodium and Iridium Complexes Having Group 13 Metalloligands (Sch. Sci., Tokyo Tech.) º YAMADA, Ryosuke; IWASAWA, Nobuharu; TAKAYA, Jun

3H6-16
Enantioselective Synthesis of Axially Chiral Benzofluoranthene Derivatives by Intramolecular Reaction via C-C bond Activation of Biphenylenes (Sch. Advanced Sci. Eng., Waseda Univ.) º SHIOZAWA, Natsumi; TAKANO, Hideaki; ITO, Takeharu; KANYIVA, Kyalo Stephen; SHIBATA, Takanori

3H6-17
Enantioselective intramolecular oxyamination reaction using Cp*Rh(III)/chiral anion hybrid catalyst (Fac. Pharm., Hokkaido Univ.) º HIROSE, Jumpei; SATAKE, Shun; KOJIMA, Masahiro; HATANO, Manabu; ISHIHARA, Kazuaki; YOSHINO, Tatsuhiko; MATSUNAGA, Shigeki

3H6-18
Synthesis of Fluorenes by Rhodium-Catalyzed Stitching Reaction (Grad. Sch. Eng. Sci., Osaka Univ.) º NISHIDA, Masaki; SHINTANI, Ryo

3H6-19*#
C2-Selective Alkylation and Silylation of Pyridines by a Rhodium Complex Bearing an X-Type Aluminyl ligand (Grad. Sch. Eng., Kyoto Univ.) º HARA, Naofumi; UEMURA, Nao; ASO, Koki; NAKAO, Yoshiaki

3H6-21
Magnesiation of Aryl Fluorides Catalyzed by Rhodium-Aluminum Bimetallic Complexes (Grad. Sch. Eng., Kyoto Univ.) º FUJII, Ikuya; SEMBA, Kazuhiko; NAKAO, Yoshiaki

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