Bldg. 11 1142
[Organic Chemistry -Reaction and Synthesis- Aliphatic and Alicyclic Compounds]
Tuesday, March 20, AM
Chair: OHMATSU, Kohsuke
(09:00-10:00)
* 8:50-9:00: interval for laptop PC connection.(1H5-01, 1H5-02, 1H5-03, 1H5-04, 1H5-05, 1H5-06)
1H5-01#
Asymmetric 1,3-Dipolar Cycloaddition by Means of Chiral Phosphoric Acid (Fac. Sci., Gakushuin Univ.) º JIN, Yuan; AKIYAMA, Takahiko
1H5-02
Organic synthesis using BDMS from HBr/ 1,4-dioxane (Grad. Sch. Sci., Osaka Pref. Univ.) º YUBATA, Kotaro; MATSUBARA, Hiroshi; ISHIKAWA, Shin-ichi
1H5-03
Enantioselective Addition Reaction of Allyl Alcohols to Imines Catalyzed by Chiral Bronsted Base (Grad. Sch. Sci., Tohoku Univ.) º TEDUKA, Hikaru; AKAHIRA, Shiori; KONDOH, Azusa; TERADA, Masahiro
1H5-04
Direct α-Acetonylation of Cyclic Nitrones Using Acetylacetone as a Pronucleophile (Tokushima Univ., Dept. Appl. Chem.) º NGUYEN, Thi Tuyet Mai; IWAI, Kensuke; ARAKAWA, Yukihiro; MINAGAWA, Keiji; IMADA, Yasushi
1H5-05
Enantioselective Propargylic Substitution Reaction Catalyzed by Chiral Brønsted Acid (Grad. Sch. Sci., Tohoku Univ.) º TAKANO, Kyohei; OTA, Yusuke; KIKUCHI, Jun; TERADA, Masahiro
1H5-06
Enantioselective Addition Reaction of Vinyl Azide as a Synthon of Amide Enolate Catalyzed by Chiral Strong Brønsted Acid (Grad. Sch. Sci., Tohoku Univ.) º NAKANISHI, Taishi; KIKUCHI, Jun; KAGA, Atsushi; CHIBA, Shunsuke; TERADA, Masahiro
Chair: HORIBE, Takahiro
(10:10-11:10)
* 10:00-10:10: interval for laptop PC connection.(1H5-08, 1H5-09, 1H5-10, 1H5-11, 1H5-12, 1H5-13)
1H5-08#
Chiral Bronsted acid catalyzed asymmetric allylic alkylation of N-Methyl Indoles (Tohoku Univ.) º GUPTA, Yogesh; KIKUCHI, Jun; TERADA, Masahiro
1H5-09
Chiral Amide-1,2,3-triazole As An Anion-Binding Supramolecular Brønsted Acid (WPI-ITbM, Nagoya Univ.; Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º SUZUKI, Ryuhei; FURUKAWA, Yukino; OHMATSU, Kohsuke; OOI, Takashi
1H5-10
Asymmetric Michael Addition to an Allenic Diester via Dynamic Kinetic Resolution (Grad. Sch. Eng., Nagoya Univ.; WPI-ITbM, Nagoya Univ.; CREST, JST) º YAMADA, Kohei; KAWAI, Yamada; URAGUCHI, Daisuke; OOI, Takashi
1H5-11
The kinetic resolution of γ-substituted 2,3-butadienoic acid esters through catalytic asymmetric Michael reaction (WPI-ITbM, Nagoya Univ.; Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º NOBORI, Yumiko; YAMADA, Kohei; URAGUCHI, Daisuke; OOI, Takashi
1H5-12
Kinetic Resolution of α-Substituted α-Nitrolactones Promoted by Brønsted Acid catalysts (Grad. Sch. Nat. Sci. Technol., Okayama Univ.) º NAKAO, Ryota; SAKAKURA, Akira
1H5-13
Thioureas and Thiophosphoric Amides as Highly Active Catalysts for Selective Bromocyclization of Geranyl Derivatives (Grad. Sch. Nat. Sci. Technol., Okayama Univ.) º TERAZAKI, Miyuki; SHIOMOTO, Keiichi; SAKAKURA, Akira
Chair: ARAKAWA, Yukihiro
(11:20-12:20)
* 11:10-11:20: interval for laptop PC connection.(1H5-15, 1H5-17, 1H5-18, 1H5-19, 1H5-20)
1H5-15*#
Chiral Strong Brønsted Acid-Catalyzed Asymmetric Addition Reaction of Azlactone to Styrene Derivatives (Grad. Sch. Sci., Tohoku Univ.) º KIKUCHI, Jun; TERADA, Masahiro
1H5-17
Enantioselective α-Fluorination Reaction Induced by Chiral π-Cu(II) Catalysts (Graduate School of Engineering, Nagoya Univ.) º NISHIMURA, Kazuki; WANG, Yanzhao; OGURA, Yoshihiro; YAMAKAWA, Katsuya; ISHIHARA, Kazuaki
1H5-18#
Chiral Cu(II) Complex-Catalyzed Enantioselective [1,3] Rearrangement of Allylnaphthyl Ethers (Grad. Sch. Eng., Nagoya Univ.) º YAO, Lu; ISHIHARA, Kazuaki
1H5-19
Chiral Iron(III)−silver(I) Cooperative Catalysts for Enantioselective Conia-ene Reaction (Grad. Sch. Eng., Nagoya Univ.) º SAKAKIBARA, Masato; HORIBE, Takahiro; ISHIHARA, Kazuaki
1H5-20
Chiral Diphosphine Oxide-Iron(II) Catalysts for Enantioselective Oxidative Coupling Reaction of 2-Naphthols (Grad. Sch. Eng., Nagoya Univ.) º NAKAGAWA, Keita; HORIBE, Takahiro; ISHIHARA, Kazuaki
Tuesday, March 20, PM
Chair: URAGUCHI, Daisuke
(13:30-14:20)
* 13:20-13:30: interval for laptop PC connection.(1H5-28, 1H5-29, 1H5-30, 1H5-31, 1H5-32)
1H5-28
Through Visible Light-Sensitized Triplet Energy Transfer Process. Intermolecular Coupling Reaction of Alkanoylsilanes with Boronic Esters (Fac. Sci., Gakushuin Univ.) º YAMAZAKI, Hokuto; HAGIWARA, Chihiro; ISHIDA, Kento; KUSAMA, Hiroyuki
1H5-29
C-C bond formation using Benzothiazoline as efficient benzylating agents under thermal/ photoredox condition (Fac. Sci., Gakushuin Univ.) º MORIYAMA, Kaworuko; IBANEZ SANCHEZ, Ignacio; AKIYAMA, Takahiko
1H5-30
Generation of α-Aminoalkyl Radicals from Sodium α-Aminoalkanesulfinates and a Hypervalent Iodine(III) Reagent (Dep. Chem., Sch. Sci., Kyoto Univ.) º YOSHII, Tomomi; SAKAMOTO, Ryu; MARUOKA, Keiji
1H5-31
Radical addition-cyclization of N-arylacrylamides with aliphatic aldehydes by the photolysis of hypervalent iodine(III) reagent (Dep. Chem., Sch. Sci., Kyoto Univ.) º NAOMICHI, Hirama; RYU, Sakamoto; KEIJI, Maruoka
1H5-32#
Lewis acid-catalyzed synthesis of cyclic carbamates from N-Boc-protected aminals and alkynes (Dep. Chem., Sch. Sci., Kyoto Univ.) º YASUMOTO, Kento; KANO, Taichi; MARUOKA, Keiji
Chair: FUKUYAMA, Takahide
(14:30-15:20)
* 14:20-14:30: interval for laptop PC connection.(1H5-34, 1H5-35, 1H5-36, 1H5-37, 1H5-38)
1H5-34
Photo-induced Generation of Radical Ion Pairs for Catalytic Bond Formation Reaction (WPI-ITbM, Nagoya Univ.; Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º IMAIZUMI, Naoki; ARAMAKI, Yoshitaka; OOI, Takashi
1H5-35
Development of a Hexacoordinated Chiral Phosphate Ion: Molecular Design, Synthesis, and Application to Asymmetric Catalysis (WPI-ITbM, Nagoya Univ.; Grad. Sch. Eng., Nagoya Univ.; CREST, JST) URAGUCHI, Daisuke; º SASAKI, Hitoshi; KIMURA, Yuto; OOI, Takashi
1H5-36
Synthesis and Properties of a Chiral Hexacoordinated Phosphorus Compound Directed toward Application for Catalysis (Grad. Sch. Eng., Nagoya Univ.; WPI-ITbM, Nagoya Univ.; CREST, JST) º KIMURA, Yuto; SASAKI, Hitoshi; URAGUCHI, Daisuke; OOI, Takashi
1H5-37
Reductive Coupling Reaction between Alcohols and Electron-Deficient Alkenes via Direct C-OH Bond Cleavage Utilizing Low-Valent Titanium (Grad. Sch. Nat. Sci. Technol., Kanazawa Univ.) º SHIMAZU, Shoma; SUGA, Takuya; UKAJI, Yutaka
1H5-38
Decarboxylative Oxyfunctionalization of Carboxylic Acids Using Iodine/Hypervalent Iodine System (Grad. Sch. Eng., Osaka Univ.) º OKUMATSU, Daichi; KIYOKAWA, Kensuke; MINAKATA, Satoshi
Chair: KANO, Taichi
(15:30-16:20)
* 15:20-15:30: interval for laptop PC connection.(1H5-40, 1H5-41, 1H5-42, 1H5-43, 1H5-44)
1H5-40
Transition Metal-Free Intramolecular Heck Carbonylation Reaction (Grad. Sch. Sci., Osaka Pref. Univ.) º BANDO, Takanobu; FUKUYAMA, Takahide; RYU, Ilhyong
1H5-41
Synthesis of secondary alkylboron compounds having polar functional groups by using atom-transfer radical reaction (Grad. Sch. Sci., Osaka Pref. Univ.) º MORISAKI, Takahiro; UEDA, Mitsuhiro; RYU, Ilhyong
1H5-42
Decatungstate Photocatalyzed Site-Selective Alkylation of Esters (Fac. Sci., Osaka Pref. Univ.) FUKUYAMA, Takahide; º SAKAMOTO, Karen; RYU, Ilhyong
1H5-43#
Photocatalytic Carbonylation of Hypervalent Bis-Catecholato Silicon Compounds (Grad. Sch. Sci., Osaka Pref. Univ.) º CARTIER, Alex; FUKUYAMA, Takahide; OLLIVIER, Cyril; FENSTERBANK, Louis; RYU, Illhyong
1H5-44
Nickel Complex/TiO2 Hybrid Catalysts for Photocatalytic Aminocarbonylation with Formamides (Grad. Sch. Sci., Nagoya Univ.; RCMS, Nagoya Univ.) º MORI, Shogo; AOKI, Takahiro; NAKA, Hiroshi; NOYORI, Ryoji; SAITO, Susumu
Chair: NAKA, Hiroshi
(16:30-17:30)
* 16:20-16:30: interval for laptop PC connection.(1H5-46, 1H5-47, 1H5-48, 1H5-49, 1H5-51)
1H5-46
Enantioselective Electrophilic Cyanation of Boron Enolates (Grad. Sch. Eng., Osaka Univ.; Coll. Sci., Rikkyo Univ.) º NAGATA, Takaya; TAMAKI, Atsuko; KIYOKAWA, Kensuke; YAMANAKA, Masahiro; MINAKATA, Satoshi
1H5-47
Regioselective Synthesis of β,γ-Unsaturated Nitriles by the Reaction of Allylic Boranes with Electrophilic Cyanating Reagents (Grad. Sch. Eng., Osaka Univ.) º HATA, Shotaro; KIYOKAWA, Kensuke; MINAKATA, Satoshi
1H5-48
Electrophilic Cyanation of Allylic Boranes Prepared by Hydroboration of Cyclic Conjugated Dienes (Sch. Eng., Osaka Univ.) º KAINUMA, Shunpei; KIYOKAWA, Kensuke; MINAKATA, Satoshi
1H5-49*#
Enantioselective Cyanation of Ketones and alpha,beta-Unsaturated Carbonyl Compounds Catalyzed by Chiral Lithium Phosphoryl Phenoxide (Grad. Sch. Eng., Nagoya Univ.) º YAMAKAWA, Katsuya; HATANO, Manabu; ISHIHARA, Kazuaki
1H5-51
Enantioselective Strecker-type Reaction of Aldimines Catalyzed by Chiral Lithium Binaphthyldisulfonates (Grad. Sch. Eng., Nagoya Univ.) º NISHIO, Kosuke; HATANO, Manabu; ISHIHARA, Kazuaki
Chair: MINAKATA, Satoshi
(17:40-18:40)
* 17:30-17:40: interval for laptop PC connection.(1H5-53, 1H5-54, 1H5-55, 1H5-56, 1H5-57, 1H5-58)
1H5-53
Asymmetric Hydrogenation of Allylic Alcohols through Formal Dynamic Kinetic Resolution (DKR) (Grad. Sch. Chem. Sci. and Eng., Hokkaido Univ.) º OKABE, Yuki; ARAI, Noriyoshi; OHKUMA, Takeshi
1H5-54
Racemization of Axially Chiral BINAM Derivatives Catalyzed by Chiral Phosphoric acid (Fac. Sci., Gakushuin Univ.) º YAMAMOTO, Kota; EBIHARA, Takuya; MIYAGAWA, Masamichi; AKIYAMA, Takahiko
1H5-55
Dynamic Kinetic Resolution of Axially Chiral BINAM Derivatives Catalyzed by Chiral Phosphoric Acid (Fac. Sci., Gakushuin Univ.) º EBIHARA, Takuya; YAMAMOTO, Kota; MIYAGAWA, Masamichi; AKIYAMA, Takahiko
1H5-56
Kinetic resolution of planar-chiral [n]paracyclophanes catalyzed by resin-supported peptide catalysts (IIS, The Univ. of Tokyo) º HIGUCHI, Junichi; AKAGAWA, Kengo; KUDO, Kazuaki
1H5-57
Chiral hydrogen-bond donor organocatalysts to a carbon dioxide fixation reaction (Grad. Sch. Nat. Sci. Technol., Okayama Univ.) TAKAISHI, Kazuto; º OKUYAMA, Takafumi; KADOSAKI, Shota; MAEDA, Chihiro; EMA, Tadashi
1H5-58
Chiral Macrocyclic Organocatalysts for the Kinetic Resolution of Epoxides with Carbon Dioxide (Grad. Sch. Nat. Sci. Technol., Okayama Univ.) º HIYOSHI, Mahoko; OKURA, Chiaki; MAEDA, Chihiro; TAKAISHI, Kazuto; EMA, Tadashi
Wednesday, March 21, AM
Chair: UYANIK, Muhammet
(09:00-10:00)
* 8:50-9:00: interval for laptop PC connection.(2H5-01, 2H5-02, 2H5-03, 2H5-05, 2H5-06)
2H5-01
Catalytic Amide Synthesis from Ketones via Beckmann rearrangement (Grad. Sch. Sci. Tech., Ryukoku Univ.) º HASWEGAWA, Genna; OISHI, Naoki; HYODO, Kengo; UCHIDA, Kingo
2H5-02#
Diastereoselective Synthesis of α-Amino Amide Using the Umpolung Reaction of α-Hydrazono Ester (Grad. Sch. Eng., Mie Univ.) º NAKAMURA, Yusuke; MIZOTA, Isao; SHIMIZU, Makoto
2H5-03*#
New Dimension of Bronsted Base-catalyzed Addition Reactions of Weakly Acidic Carbon Pronucleophiles (Grad. Sch. Sci., The Univ. of Tokyo) º YAMASHITA, Yasuhiro; KOBAYASHI, Shu
2H5-05
Development of Strong Base-catalyzed Addition Reactions of Weakly Acidic Compounds to C-C/C-N Double Bonds (Grad. Sch. Sci., The Univ. of Tokyo) º IGARASHI, Ryo; SUZUKI, Hirotsugu; YAMASHITA, Yasuhiro; KOBAYASHI, Shu
2H5-06
Chiral Calcium-catalyzed Asymmetric Epoxidation of Olefins Using Hydrogen Peroxide (Grad. Sch. Sci., The Univ. of Tokyo) º FUSHIMI, Seiya; MACOR, Joseph; YAMASHITA, Yasuhiro; KOBAYASHI, Shu
Chair: KIYOKAWA, Kensuke
(10:10-11:10)
* 10:00-10:10: interval for laptop PC connection.(2H5-08, 2H5-10, 2H5-11, 2H5-12)
2H5-08*#
Strong Base-catalyzed C-C Bond Formation of Alkylarenes with Olefins (Grad. Sch. Sci., The Univ. of Tokyo) º SATO, Io; YAMASHITA, Yasuhiro; KOBAYASHI, Shu
2H5-10
Development of Stereoselective Addition Reactions of Alkylarenes with Imines Enabled by Strong Base Catalysts (Grad. Sch. Sci., The Univ. of Tokyo) º HIRATA, Tsubasa; SATO, Io; SUZUKI, Hirotsugu; YAMASHITA, Yasuhiro; KOBAYASHI, Shu
2H5-11
Development of Catalytic Direct-type Allylation of Imines with Propylene (Grad. Sch. Sci., The Univ. of Tokyo) º FUKUYAMA, Ryota; SATO, Io; YAMASHITA, Yasuhiro; KOBAYASHI, Shu
2H5-12*#
Umpolung Reaction of α-Imino Thioesters and the Subsequent C-C Bond Formation with the Unexpected Alkylthio Rearrangement (Grad. Sch. Eng., Mie Univ.) º MIZOTA, Isao; SHIMIZU, Makoto
Chair: HYODO, Kengo
(11:20-12:20)
* 11:10-11:20: interval for laptop PC connection.(2H5-15, 2H5-16, 2H5-17, 2H5-18, 2H5-19, 2H5-20)
2H5-15
Chiral hypoiodite-catalyzed enantioselective cascade aminocyclization to 2-acylpiperazines (Grad. Sch. Eng., Nagoya Univ.) º IWATA, Hirokazu; UYANIK, Muhammet; ISHIHARA, Kazuaki
2H5-16
Chiral hypoiodite-catalyzed enantioselective oxidative aminospirocyclization of indole derivatives (Grad. Sch. Eng., Nagoya Univ.) º TANAKA, Hiroki; UKEGAWA, Naoya; UYANIK, Muhammet; ISHIHARA, Kazuaki
2H5-17
Oxidation of Fluorine Containing Alcohols and Related Compounds Using Sodium Hypochlorite Pentahydrate (Fac. Sci. Tech., SIST; Iharanikkei Chemical Industry) º SUZUKI, Katsuya; NAKAKURA, Kana; SAITO, Katsuya; KIMURA, Yoshikazu; KIRIHARA, Masayuki
2H5-18
Bromination of Side Chains of Aromatic Ring Using Sodium Hypochlorite Pentahydrate and Bromide Ion (Fac. Sci. Tech., SIST) º ADACHI, Kouta; AKIYAMA, Tomomi; MORI, Hiromitsu; NANBA, Yuko; KIRIHARA, Masayuki
2H5-19
Oxygenation of C-H Bonds at Tertiary Carbon Centers Using Iodine Oxidants (Grad. Sch. Eng., Osaka Univ.) º KIYOKAWA, Kensuke; ITO, Ryo; MINAKATA, Satoshi
2H5-20
Catalytic Bromoetherification of Alkenylalcohols by Aerobic Oxidation of Bromide Ion (Grad. Sch. Sci., Chiba Univ.) º TOMIZUKA, Akihiko; HAMADA, Tsukasa; MORIYAMA, Katsuhiko
Wednesday, March 21, PM
Chair: KAWASAKI, Tsuneomi
(13:40-14:40)
* 13:30-13:40: interval for laptop PC connection.(2H5-29, 2H5-30, 2H5-32, 2H5-33, 2H5-34)
2H5-29
Asymmetric Acyl Rearrangement of Oxindole Derivatives Using Helically Chiral Poly(quinoxaline-2,3-diyl)s Bearing 4-Dialkylaminopyrid-3-yl Pendants (Grad. Sch. Eng., Kyoto Univ.) º TAKAHASHI, Takuya; MURAKAMI, Ryo; YAMAMOTO, Takeshi; SUGINOME, Michinori
2H5-30*#
Kinetic Resolution of Secondary Alcohols Using Chirality-Switchable Helical Poly(quinoxaline-2,3-diyl)s Bearing 4-Dialkylaminopyrid-3-yl Pendants (Grad. Sch. Eng., Kyoto Univ.) º MURAKAMI, Ryo; YAMAMOTO, Takeshi; SUGINOME, Michinori
2H5-32
Acylation Reaction by Chiral DMAP Derivatives (1): Kinetic Resolution of 3-Hydroxy-3-Substituted Oxindole Derivatives (Grad. Sch. Nat. Sci. Technol., Okayama Univ.) º MANDAI, Hiroki; SHIOMOTO, Ryuhei; SUGA, Seiji
2H5-33
Acylation Reaction by Chiral DMAP Derivatives (2): Desymmetrization of 1,3-Diols (Grad. Sch. Nat. Sci. Technol., Okayama Univ.) º ASHIHARA, Kosuke; MANDAI, Hiroki; SUGA, Seiji
2H5-34
Acylation Reaction by Chiral DMAP Derivatives (3): Site-selective Acylation of Carbohydrates (Grad. Sch. Nat. Sci. Technol., Okayama Univ.) º YAMAMOTO, Tomoya; ABE, Kenko; MANDAI, Hiroki; SUGA, Seiji
Thursday, March 22, AM
Chair: HAYASHI, Hiroki
(09:00-10:00)
* 8:50-9:00: interval for laptop PC connection.(3H5-01, 3H5-02, 3H5-03, 3H5-04, 3H5-05, 3H5-06)
3H5-01
The synthesis of bulky ethers from the reaction of 2-bromoamides and alcohols in the presence of cesium carbonate (Grad. Sch. Sci. Tech., Yamaguchi Univ.) º NISHIKATA, Takashi; TAKEUCHI, Kentaro
3H5-02
Chiral Macrocyclic Lithium Binaphtholate Catalysts for Enantioselective Alkynyl Addition to Ketones (Grad. Sch. Eng., Nagoya Univ.) º TABATA, Yuji; YAMAKAWA, Katsuya; YAMASHITA, Kenji; HATANO, Manabu; ISHIHARA, Kazuaki
3H5-03
Transesterification Catalyzed by Highly Active Quaternary Ammonium Salts (Grad. Sch. Eng., Nagoya Univ.) º TOH, Kohei; TABATA, Yuji; HATANO, Manabu; ISHIHARA, Kazuaki
3H5-04
Nucleophilic Substitution Reaction of Chiral Alkoxysilane with Organometallic Reagent (IMCE, Kyushu Univ.; Fac. Eng., Kyushu Univ.; Grad. Sch. Sci., Eng., Tokyo Tech.; Grad. Sch. Eng. Sci., Kyushu Univ.) IGAWA, Kazunobu; º NOZAKI, Sora; TAKADA, Junko; SHIGEMATSU, Kazuki; MIYASAKA, Shoji; TOMOOKA, Katsuhiko
3H5-05
Asymmetric Synthesis of Hetero-functionalized Chiral Silacyclopentanes (Grad. Sch. Eng. Sci., Kyushu Univ.; IMCE, Kyushu Univ.) º KUROO, Akihiro; IGAWA, Kazunobu; TOMOOKA, Katsuhiko
3H5-06
Asymmetric Autocatalysis Initiated by Chiral Crystal of Achiral o-Terphenyl (Fac. Sci., TUS) º YONEMITSU, Kento; KAWASAKI, Tsuneomi; SOAI, Kenso
Chair: ARAKAWA, Yukihiro
(10:10-11:10)
* 10:00-10:10: interval for laptop PC connection.(3H5-08, 3H5-09, 3H5-10, 3H5-11, 3H5-12, 3H5-13)
3H5-08
Synthesis of 3-Amino-2-pyrone by Tandem N-Alkylation/vinylogous Aldol Reaction of β,γ-Alkenyl α-Iminoester (Grad. Sch. Eng., Mie Univ.) º NAKAHAMA, Kenta; MIZOTA, Isao; SHIMIZU, Makoto
3H5-09
Stereoselective substitution of alkyl phosphates with diphenylmethyl anions (Sch. Life Sci. Tech., Tokyo Tech.) º SHINOHARA, Riku; WADA, Kyohei; KAWASHIMA, Hidehisa; OGAWA, Narihito; KOBAYASHI, Yuichi
3H5-10
Asymmetric Claisen Rearrangement utilizing Umpolung Reaction of α-Imino Allyl esters (Grad. Sch. Eng., Mie Univ.) MIZOTA, Isao; º AOKI, Takashi; SHIMIZU, Makoto
3H5-11
Ruthenium-catalyzed asymmetric oxidative coupling of 2-naphthols (Grad. Sch. Sci., Kyushu Univ.; Kyushu Univ.) º UENO, Takamasa; HAYASHI, Hiroki; UCHIDA, Tatsuya
3H5-12#
Hypoiodite-catalyzed oxidative generation of quinone methides and application to tandem reactions (Grad. Sch. Eng., Nagoya Univ.) º NISHIOKA, Kohei; UYANIK, Muhammet; ISHIHARA, Kazuaki
3H5-13
Hypervalent organoiodine(V)-catalyzed highly efficient and selective oxidation of alcohols (Sch. Eng., Nagoya Univ.) º KONDO, Ryutaro; UYANIK, Muhammet; ISHIHARA, Kazuaki
Chair: KAWASHIMA, Hidehisa
(11:20-12:20)
* 11:10-11:20: interval for laptop PC connection.(3H5-15, 3H5-17, 3H5-19, 3H5-20)
3H5-15*#
Design of Peptide-Containing N5-Unmodified Neutral Flavins That Catalyze Aerobic Oxygenations (Tokushima Univ.) º YAMANOMOTO, Ken; KITA, Hazuki; ARAKAWA, Yukihiro; MINAGAWA, Keiji; IMADA, Yasushi
3H5-17*#
Hypoiodite-catalyzed oxidative α-azidation of carbonyl compounds (Grad. Sch. Eng., Nagoya Univ.) º SAHARA, Naoto; UYANIK, Muhammet; ISHIHARA, Kazuaki
3H5-19
Chiral hypohalite-catalyzed enantioselective dearomatizative cycloamination (Grad. Sch. Eng., Nagoya Univ.) º KATADE, Outa; SAHARA, Naoto; UYANIK, Muhammet; ISHIHARA, Kazuaki
3H5-20
Chiral hypohalite-catalyzed enantioselective dearomatizative spirolactonization (Sch. Eng., Nagoya Univ.) º KATO, Takehiro; SAHARA, Naoto; UYANIK, Muhammet; ISHIHARA, Kazuaki
Thursday, March 22, PM
Chair: SUZUKI, Takahiro
(13:30-14:30)
* 13:20-13:30: interval for laptop PC connection.(3H5-28, 3H5-29, 3H5-30, 3H5-31, 3H5-32, 3H5-33)
3H5-28
Synthesis, and Stereochemical Behavior of Ten-membered Diallylic Amides (IMCE, Kyushu Univ.; Grad. Sch. Eng. Sci., Kyushu Univ.) º HAYASHI, Juni-chi; HORIKAWA, Shintaro; IGAWA, Kazunobu; TOMOOKA, Katsuhiko
3H5-29
Synthesis and Stereochemical Behavior of 6-Substituted 3-aza[7]orhtopyridinophene (IMCE, Kyushu Univ.) ANO, Yusuke; YOSHIOKA, Yukari; º TANAKA, Sumire; KAWASAKI, Yuuya; IGAWA, Kazunobu; TOMOOKA, Katsuhiko
3H5-30
Efficient Synthesis of Medium-sized E-Cyclic Molecules via Photochemical Isomerization in the Presence of AgNO3-Impregnated Silica-gel (IMCE, Kyushu Univ.; Grad. Sch. Eng. Sci., Kyushu Univ.) º YOSHIDA, Yuki; MACHIDA, Kouhei; IGAWA, Kazunobu; TOMOOKA, Katsuhiko
3H5-31
Effect of Solvation Behavior of Ionic Liquids on Optical Properties of Aminobenzopyranoxanthenes (Grad. Sch. Eng., Oita Univ.) º ENOKI, Shinji; NOBUOKA, Kaoru; KITAOKA, Satoshi; ISHIKAWA, Yuichi
3H5-32
Synthesis of the AIE dye-DNA conjugate and the study on application possibility for biosensing. (FIRST, Konan Univ.) MURASHIMA, Takashi; º TANI, Tomoki
3H5-33
Development of a novel cleavable linker for drug delivery system (Grad. Sch. Pharm., The Univ. of Tokyo) º TATSUMI, Toshifumi; ITO, Kei; SHIMIZU, Yohei; KANAI, Motomu
Chair: YAZAKI, Ryo
(14:40-15:40)
* 14:30-14:40: interval for laptop PC connection.(3H5-35, 3H5-36, 3H5-37, 3H5-38, 3H5-39, 3H5-40)
3H5-35
Synthesis of novel ascofuranone derivatives having an alkyl type linker (Fac. Eng., Tottori Univ.) º KASAHARA, Kenta; II, Yasuyuki; YAMAMOTO, Masaichi; KITA, Kiyoshi; IZAWA, Hironori; IFUKU, Shinsuke; MORIMOTO, Minoru; SAIMOTO, Hiroyuki
3H5-36
Synthesis of novel ascofuranone derivatives having an amine type linker (Fac. Eng., Tottori Univ.) º IWASAKI, Ryo; ANBIRU, Yoshihide; YAMAMOTO, Masaichi; KITA, Kiyoshi; IZAWA, Hironori; IFUKU, Shinsuke; MORIMOTO, Minoru; SAIMOTO, Hiroyuki
3H5-37
Synthesis of novel ascofuranone derivatives having anti-trypanosome alternative oxidase activity (Fac. Eng., Tottori Univ.) º NISHIDA, Shohei; IKEDA, Kouhei; KUMAMOTO, Izumi; YAMAMOTO, Masaichi; KITA, Kiyoshi; IZAWA, Hironori; IFUKU, Shinsuke; MORIMOTO, Minoru; SAIMOTO, Hiroyuki
3H5-38
Convenient Synthesis of 3-Hydroxy-3-trifluorometyloxindoles Possessing the Electron-donating Groups (Grad. Sch. Nat. Sci. & Tech., Gifu Univ.) º NAKAJIMA, Takaya; INUZUKA, Toshiyasu; FUNABIKI, Kazumasa
3H5-39
Mechanism of the Inversion of Olefinic Stereochemistry of Lithio(bromo)enamides and Its Application to the Stereoselective Synthesis of Poly-substituted Enamides (Sch. Life Sci. Tech., Tokyo Tech.) º FUJISAWA, Kazuki; KOSAKA, Kyohei; SHIGETA, Masayuki; HATA, Takeshi; URABE, Hirokazu
3H5-40
Trifluoroacetic Acid-Water Mixture for Conversion of Esters to Carboxylic Acids (Grad. Sch. Sci., Nagoya Univ.; RCMS, Nagoya Univ.) º BANNO, Tomomi; OKABE, Hiroyuki; NOYORI, Ryoji; NAKA, Hiroshi
Chair: KENTARO, Okano
(15:50-16:50)
* 15:40-15:50: interval for laptop PC connection.(3H5-42, 3H5-43, 3H5-44, 3H5-45, 3H5-46, 3H5-47)
3H5-42
New Synthesis of Enamides from N,N-Divinylamides and 1,1-Dichloro or Dimethoxyalkanes in the Presence of TiCl4 (Sch. Life Sci. Tech., Tokyo Tech.) MIZUMOTO, Shiina; º SHIGETA, Masayuki; HATA, Takeshi; URABE, Hirokazu
3H5-43
Transfer Dehydration of Primary Amides Using Electron-Deficient Nitriles (Grad. Sch. Sci., Nagoya Univ.; RCMS, Nagoya Univ.) º OKABE, Hiroyuki; ISOGAWA, Takahiro; NARAOKA, Asuka; NOYORI, Ryoji; NAKA, Hiroshi
3H5-44
Transfer Hydration of Cyanohydrins (Grad. Sch. Sci., Nagoya Univ.; RCMS, Nagoya Univ.) º KANDA, Tomoya; NOYORI, Ryoji; NAKA, Hiroshi
3H5-45
Studies on the Asymmetric Synthesis of (S)-(-)-Ligustiphenol (Grad. Sch. Eng., Yokohama Natl. Univ.) º HAYASHI, Hiroki; FENG, Weizou; ITO, Suguru; ASAMI, Masatoshi
3H5-46
Biomimetic Synthesis of Polyketides using a Solid Support (IIS, The Univ. of Tokyo) º TAKEUCHI, Yuta; AKAGAWA, Kengo; KUDO, Kazuaki
3H5-47
Synthesis of Asymmetric Lactide with Amino Group (Sch. Eng., Tokai Univ.) º MAEKAWA, Naoki; INAZU, Toshiyuki
Chair: URABE, Hirokazu
(17:00-18:00)
* 16:50-17:00: interval for laptop PC connection.(3H5-49, 3H5-51, 3H5-52, 3H5-54)
3H5-49*
Design of reversal of the diastereoselectivity in the electrophilic addition controlled by the earliness (or lateness) of the transition states. (Fac. Eng., Gifu Univ.; Grad. Sch. Nat. Sci. & Tech., Gifu Univ.) º NARUSE, Yuji
3H5-51
Development of Asymmetric Hydrolysis of Amino Acid Esters Using Ion-Pairing Catalysts and Analysis of the Reaction Mechanism by Rapid Conformation Search Method (Fac. Sci., Kyushu Univ.) º KOBAYASHI, Kaoru; WAKAFUJI, Koudai; FURUTACHI, Yuho; YAMAMOTO, Eiji; KMACHI, Takashi; TOKUNAGA, Makoto
3H5-52*
Studies on Enantioselective Total Synthesis of Cotylenin A (Sch. Advanced Sci. Eng., Waseda Univ.) º UWAMORI, Masahiro; OSADA, Ryunosuke; SUGIYAMA, Ryoji; HOSHINO, Yunosuke; TEZUKA, Haruka; NAGATANI, Kotaro; NAKADA, Masahisa
3H5-54
Stereoselective Construction of 1,2-Diol Derivatives Derived from Polyunsaturated Fatty Acids (Sch. Life Sci. Tech., Tokyo Tech.) º TANABE, Shuhei; KOBAYASHI, Yuichi
Chair: NAKA, Hiroshi
(18:10-19:00)
* 18:00-18:10: interval for laptop PC connection.(3H5-56, 3H5-57, 3H5-58, 3H5-59, 3H5-60)
3H5-56#
Ortho-Substituent Effect on 2,4-Bis(trifluoromethyl)phenylboronic Acid Which Catalyzes a Dehydrative Condensation between Carboxylic Acids and Amines (Grad. Sch. Eng., Nagoya Univ.) º WANG, Ke; LU, Yanhui; ISHIHARA, Kazuaki
3H5-57
Chiral Amine-Boronic Acid Cooperative Catalysts for Enantioselective 1,4-Addition of α,β-Unsaturated Carboxylic Acids with Cycloalkanones (Sch. Eng., Nagoya Univ.) º HAZEYAMA, Takashi; NAKATA, Yuto; LU, Yanhui; TSUJI, Yasutaka; HORIBE, Takahiro; ISHIHARA, Kazuaki
3H5-58
Umpolung Reaction of α-Hydrazonoester: Synthesis of α-Aminoamide and Total Synthesis of Bioactive Compound (Grad. Sch. Eng., Mie Univ.) º MIZUTANI, Shunsuke; MIZOTA, Isao; SHIMIZU, Makoto
3H5-59
Stereoselective ozonolysis to afford α,β-dihydroxy aldehydes from γ-TMS-allylic alcohols (Sch. Life Sci. Tech., Tokyo Tech.) º SAITO, Shun; KOBAYASHI, Yuichi
3H5-60
Catalytic Desymmetrization of meso-N-Ns Aziridines Using Chloramine Salts as Nucleophiles (Grad. Sch. Eng., Osaka Univ.) º YAMAMOTO, Kenya; MINAKATA, Satoshi
Friday, March 23, AM
Chair: IGAWA, Kazunobu
(09:00-10:00)
* 8:50-9:00: interval for laptop PC connection.(4H5-01, 4H5-02, 4H5-03, 4H5-05)
4H5-01
New method for synthesis of gem-divinyl compounds and its application to construction of bicyclic carbon skeletons (Fac. Sci., Hokkaido Univ.) º OGURA, Ryota; SATO, Kazuto; TANINO, Keiji
4H5-02
Synthetic Study of ent-Kaurene Diterpenoid Kamebanin (Grad. Sch. Chem. Sci. and Eng., Hokkaido Univ.) º KANNO, Ayaka; SUZUKI, Takahiro; TANINO, Keiji
4H5-03*#
Chemoselective Oxidative Cross-Enolate Coupling Reaction (Grad. Sch. Pharm., Kyushu Univ.) º YAZAKI, Ryo; TANAKA, Takafumi; TANAKA, Tsukushi; OHSHIMA, Takashi
4H5-05*#
Single-step synthesis of deoxypropionate motif in natural products by stereospecific oligomerization of propylene (Grad. Sch. Eng., The Univ. of Tokyo) º MURAYAMA, Toshiki; OTA, Yusuke; NOZAKI, Kyoko
Chair: SHIGETA, Masayuki
(10:10-11:10)
* 10:00-10:10: interval for laptop PC connection.(4H5-08, 4H5-10, 4H5-11, 4H5-13)
4H5-08*#
Reductive Approach to Nitrones from N-Siloxyamides and N-Hydroxyamides (Fac. Sci. Tech., Keio Univ.) º KATAHARA, Seiya; FUJITA, Kanami; KOBAYASHI, Shoichiro; MATSUMOTO, Tsutomu; SATO, Takaaki; CHIDA, Noritaka
4H5-10
Generation of cyclohexynes from enol triflate through deprotonation by Aluminate base. (Grad. Sch. Eng., Kobe Univ.) º YUKIOKA, Taro; HIOKI, Yuto; OKANO, Kentaro; MORI, Atunori
4H5-11*#
Development of generation of cycloalkyne and cycloallene using magnesium bisamides (Grad. Sch. Eng., Kobe Univ.) º HIOKI, Yuto; OKANO, Kentaro; MORI, Atsunori
4H5-13
Efficient synthesis of precursors for cycloalkyne and cycloallene by rearrangement of silyl enol ether and isomerization of enolate (Grad. Sch. Eng., Kobe Univ.) º INOUE, Kazuki; NAKURA, Ryo; OKANO, Kentaro; MORI, Atunori
Chair: SATO, Takaaki
(11:20-12:20)
* 11:10-11:20: interval for laptop PC connection.(4H5-15, 4H5-17, 4H5-18, 4H5-19, 4H5-20)
4H5-15*#
Copper-catalyzed Carboxylation Reactions of Aryl Silanes with Carbon Dioxide (Grad. Sch. Sci., The Univ. of Tokyo) º YOO, Woo-jin; KOBAYASHI, Shu
4H5-17#
Synthesis of Butenolides via trans-Hydroalumination/Carboxylation of Propargyl Alcohols (Grad. Sch. Sci., The Univ. of Tokyo) º CHEN, Wenlong; NGUYEN, Thanh Vu Quang; YOO, Woo-jin; KOBAYASHI, Shu
4H5-18#
Efficient Synthesis of α-Trifluorinated Carboxylic Acids via Fluorocarboxylation of β,β-Difluoroalkenes (Grad. Sch. Sci., The Univ. of Tokyo) º RODRIGUEZ-SANTAMARIA, Jose Alberto; NGUYEN, Thanh Vu Quang; YOO, Woo-jin; KOBAYASHI, Shu
4H5-19
Biological Evaluation of the Modified Tamoxifen Derivatives Prepared by the Reductive Coupling Reaction in the Presence of the Low-valent Titanium Reagent (Fac. Sci., TUS) SHIINA, Isamu; SHIBATA, Natsumi; º TSUCHIYA, Kaho; NAKATA, Kenya
4H5-20
Synthesis of the Modified Tamoxifen Derivatives Having Amino Group and Its Peptide Conjugated Compounds (Fac. Sci., TUS) SHIINA, Isamu; º SHIBATA, Natsumi; TSUCHIYA, Kaho; NAKATA, Kenya
Friday, March 23, PM
Chair: TANABE, Yoo
(13:30-14:30)
* 13:20-13:30: interval for laptop PC connection.(4H5-28, 4H5-30, 4H5-31, 4H5-32)
4H5-28*#
Controlling regioselectivity in the aerobic oxidative hetero-coupling of catechols (Syn. Org. Chem. Lab., RIKEN; RIKEN CSRS; RIKEN CEMS) º SUGAWARA, Masumi; HOJO, Daiki; SAWAMURA, Miki; HASHIZUME, Daisuke; SOHTOME, Yoshihiro; SODEOKA, Mikiko
4H5-30
Preparation of 3-Aryl-2-germyl-1,3-butadiene Using gem-Dizinc Species (Grad. Sch. Eng., Kyoto Univ.) º TAKAHASHI, Satoshi; MATSUBARA, Seijiro
4H5-31
Development of selective synthetic reaction of multi-substituted cubane (Grad. Sch. Eng., Kyoto Univ.) º KATO, Yumi; MATSUBARA, Seijiro
4H5-32*#
Insertion reactions in C-H bonds - from chemical applications towards promiscuous enzymes (RWTH Aachen University) º KOENIGS, Rene Michael
Chair: IMAHORI, Tatsushi
(14:40-15:40)
* 14:30-14:40: interval for laptop PC connection.(4H5-35, 4H5-37, 4H5-38, 4H5-39, 4H5-40)
4H5-35*#
Ester metathesis overview and cyclopropanation of aliphatic esters and alcohols with a homogeneous Ru(II) catalyst. (OIST) º KHASKIN, Eugene; JANKINS, Tanner; DUBEY, Abhishek; FAYZULLIN, Robert
4H5-37#
Direct Catalytic Alcoholysis of Unactivated 8-Aminoquinoline Amides (Grad. Sch. Pharm., Kyushu Univ.) DEGUCHI, Toru; º XIN, Hailong; MORIMOTO, Hiroyuki; OHSHIMA, Takashi
4H5-38
Practical syntheses of (Z)-3-arylbut-2-enoates and (Z)-2-arylbut-2-enoates: Two subjects in Organic Syntheses (Sch. Sci. Tech., Kwansei Gakuin Univ.) º TSUTSUMI, Takeshi; ASHIDA, Yuichiro; NAKATSUJI, Hidefumi; TANABE, Yoo
4H5-39
(E)-, (Z)-stereocomplementary syntheses of tetra-substituted conjugated dienes using one-pot Miyaura-Ishiyama borylation of enol tosyletes and Suzuki-Miyaura cross-coupling (Sch. Sci. Tech., Kwansei Gakuin Univ.) º HANATANI, Yutaro; TAKEMOTO, Taichi; TANABE, Yoo; NAKATSUJI, Hidefumi
4H5-40
(E), (Z)-Stereocomplementary syntheses of multi-substituted conjugated dienes utilizing stereoretentive Miyaura-Ishiyama borylation and Suzuki-Miyaura cross-coupling (Sch. Sci. Tech., Kwansei Gakuin Univ.) º TAKEMOTO, Taichi; HANATANI, Yutaro; NAKATSUJI, Hidefumi; TANABE, Yoo
Chair: NAKATSUJI, Hidefumi
(15:50-16:20)
* 15:40-15:50: interval for laptop PC connection.(4H5-42, 4H5-44)
4H5-42*
It is method to create from Ethanol to Methanol. (Office kano) º KANO, Hiroshi
4H5-44
Stimuli-responsive acid-base combined catalyst switching intermolecular self deactivation and intramolecular cooperative activation (Grad. Sch. Eng., TUS) º KAWAGUCHI, Akihiro; IMAHORI, Tatsushi