Bldg. 11 1141
[Organic Chemistry -Reaction and Synthesis- Aliphatic and Alicyclic Compounds]
Tuesday, March 20, AM
Chair: SHIINA, Isamu
(09:00-10:00)
* 8:50-9:00: interval for laptop PC connection.(1H4-01, 1H4-02, 1H4-03, 1H4-04, 1H4-06)
1H4-01
Diastereoselective synthesis of tetralin-fused spirooxindoles by internal redox reaction (Fac. Eng., Tokyo Univ. of Agri. and Technol.) º MACHIDA, Mizuki; MORI, Keiji
1H4-02
Development of structure divergent synthesis based on minute control of coordination site by the selection of acid catalysts. (Fac. Eng., Tokyo Univ. of Agri. and Technol.) º YOKOO, Kazuma; MORI, Keiji
1H4-03
Construction of 7-6-fused-cyclic skeleton by sequential hydride shift triggered double C-H bond functionalization (Fac. Eng., Tokyo Univ. of Agri. and Technol.) º KATAOKA, Miyabi; MORI, Keiji
1H4-04*
Synthesis of Molecularly Imprinted Polymer with Halogen Bonding-based Molecular Recognition Sites and Application to Catalysis (IMS) º YAMANISHI, Katsunori; WATANABE, Taku; MOMIYAMA, Norie
1H4-06
Halogen Bond-based DMAP Imprinting Polymer Catalyzed Rearrangement Reaction of o-Acyloxy Benzofuranone in Water (LCCMS, IMS; Sch. Physical Sci., SOKENDAI) º WATANABE, Taku; YAMANISHI, Katsunori; MOMIYAMA, Norie
Chair: MORI, Keiji
(10:10-11:10)
* 10:00-10:10: interval for laptop PC connection.(1H4-08, 1H4-09, 1H4-10, 1H4-11, 1H4-12, 1H4-13)
1H4-08
Copper-Catalyzed C−N Bond Formation of Indolyl (Aryl)Iodonium Imides via Rearrangement of Imides (Grad. Sch. Sci., Chiba Univ.) º WATANABE, Kazuhiro; MORIYAMA, Katsuhiko
1H4-09
Remote Iodo-Amination of 2-Methylindole Derivatives Using Iodine Reagents (Grad. Sch. Sci., Chiba Univ.) º HAMADA, Tsukasa; ISHIDA, Kazuma; TOGO, Hideo; MORIYAMA, Katsuhiko
1H4-10
Mechanistic Studies on Copper-Catalyzed Domino Rearrangement Reaction of ortho-Substituted N-Alkoxy Anilines (Grad. Sch. Sci., Tohoku Univ.) º ISHIDA, Yasuhiro; NAKAMURA, Itaru; TERADA, Masahiro
1H4-11
Cu-catalyzed cascade-type 1,3-alkoxy rearrangement-Diels-Alder-reaction (Sch. Sci., Tohoku Univ.) º MASUKAWA, Kazuki; ISHIDA, Yasuhiro; NAKAMURA, Itaru; TERADA, Masahiro
1H4-12
Catalytic Nucleophilic Aromatic Substitution Reaction Utilizing [1,2]-Phospha-Brook Rearrangement (Grad. Sch. Sci., Tohoku Univ.) º AOKI, Takuma; KONDOH, Azusa; TERADA, Masahiro
1H4-13
Bronsted Base-Catalyzed Umpolung Intramolecular Cyclization of Alkynyl Imines (Grad. Sch. Sci., Tohoku Univ.) º KONDOH, Azusa; TERADA, Masahiro
Chair: MANDAI, Hiroki
(11:20-12:20)
* 11:10-11:20: interval for laptop PC connection.(1H4-15, 1H4-16, 1H4-17, 1H4-18, 1H4-19, 1H4-20)
1H4-15
Development of Intramolecular Diels-Alder Reaction Forming Large-Membered Ring (Grad. Sch. Advanced Sci. Eng., Waseda Univ.) º HIROKI, Shimoda; TAKAHIRO, Shibata; MASAHISA, Nakada
1H4-16
Asymmetric Aza-Diels-Alder Reaction of Imines and Dienes Utilizing In Situ Formation of Cationic Iron(III) Lewis Acid (Grad. Sch. Eng., Kyoto Univ.) º TOMIFUJI, Rei; KURAHASHI, Takuya; MATSUBARA, Seijiro
1H4-17
Optimization of the Kinetic Resolution of Racemic 2-Hydroxyacetals by the Asymmetric Esterification Using MA-BTM Combined System (Fac. Sci., TUS) º MURATA, Takatsugu; NAKATA, Kenya; TAKAMA, Manami; SHIINA, Isamu
1H4-18
Formal Total Synthesis of (+)-Dragmacidin D by the Dynamic Kinetic Resolution of Racemic 2-Arylalkanoic Acid Using MA-BTM Combined System (Fac. Sci., TUS) SHIINA, Isamu; º YOKOYAMA, Yuka; MURATA, Takatsugu; NAKATA, Kenya
1H4-19
Generation and Amplification of Solid-state Chirality of o-Tolylglycine Nitrile in the Strecker Reaction between Three Achiral Reagents (Fac. Sci., TUS) º AIBA, Shohei; TAKAMATSU, Naoya; TOKUNAGA, Yuji; KAWASAKI, Tsuneomi
1H4-20
Enantioselective Synthesis of Benzhydrylamine with Hydrogen Isotope (D/H) Chirality and Its Use for Asymmetric Strecker Amino Acids Synthesis as a Source Chirality (Fac. Sci., TUS) º KUBO, Hiroki; NISHIYAMA, Satoshi; TOKUNAGA, Yuji; KAWASAKI, Tsuneomi
Tuesday, March 20, PM
Chair: HATANO, Manabu
(13:30-14:30)
* 13:20-13:30: interval for laptop PC connection.(1H4-28, 1H4-30, 1H4-32)
1H4-28*#
Development and Mechanistic Study of Bifunctional Phosphonium Salt-Catalyzed Coupling Reactions of Carbon Dioxide with Epoxides (Fac. Eng., Shinshu Univ.; Sch. Med., Hyogo Coll. Med.) º TODA, Yasunori; KOMIYAMA, Yutaka; ESAKI, Hiroyoshi; FUKUSHIMA, Kazuaki; SUGA, Hiroyuki
1H4-30*#
Organocatalytic Decarboxylative Functionalization of Carboxylic Acids (TUT) º KITAHARA, Kazumasa; KATADA, Misaki; IWASA, Seiji; SHIBATOMI, Kazutaka
1H4-32*#
Asymmetric Total Synthesis of Latanoprost (Grad. Sch. Sci., Tohoku Univ.; Grad. Fac. Life Sci., Hokkaido Univ.) º KAWAUCHI, Genki; UMEMIYA, Shigenobu; TANIGUCHI, Tohru; MONDE, Kenji; HAYASHI, Yujiro
Chair: SHIBATOMI, Kazutaka
(14:40-15:40)
* 14:30-14:40: interval for laptop PC connection.(1H4-35, 1H4-37, 1H4-38, 1H4-39)
1H4-35*#
Chiral U-Shaped Supramolecular Catalysts for Multiselective Diels-Alder Reaction (Grad. Sch. Eng., Nagoya Univ.) º SAKAMOTO, Tatsuhiro; HATANO, Manabu; ISHIHARA, Kazuaki
1H4-37
Enantioselective Aza-Friedel-Crafts Reaction of Indoles with Ketimines Catalyzed by Chiral Potassium Binaphthyldisulfonates (Grad. Sch. Eng., Nagoya Univ.) º MOCHIZUKI, Takuya; HATANO, Manabu; ISHIHARA, Kazuaki
1H4-38
Enantioselective Aza-Friedel-Crafts Reaction of 2-Methoxyfuran with alpha-Ketimino Esters Catalyzed by Chiral C1-Symmetric Bis(phosphoric acid) (Grad. Sch. Eng., Nagoya Univ.) º KAWAKAMI, Taro; YASUKOCHI, Shotaro; HATANO, Manabu; ISHIHARA, Kazuaki
1H4-39*
Development of Chiral Organosuperbase Catalyst Consisting of Guanidine and Phosphazene (Tohoku Univ.) º OISHI, Masafumi; KONDOH, Azusa; TERADA, Masahiro
Chair: MORI, Keiji
(15:50-16:50)
* 15:40-15:50: interval for laptop PC connection.(1H4-42, 1H4-44, 1H4-45, 1H4-46, 1H4-47)
1H4-42*
Mechanistic Studies on Iodopentafluorobenzene Accelerated Addition Reactions of Allyl-, Crotyl-, and Prenylsilatranes to N-Heteroaromatics (LCCMS, IMS; Sch. Physical Sci., SOKENDAI) º IZUMISEKI, Atsuto; NAKASHIMA, Fumio; YANG, Tao; EHARA, Masahiro; TUZUKI, Seiji; MOMIYAMA, Norie
1H4-44
Synthesis and Evaluation of Halogen Bond Donor Catalysts with Diiodoperfluoroaryls as the Mother Skeleton (LCCMS, IMS; Sch. Physical Sci., SOKENDAI) º NAKASHIMA, Fumio; IZUMISEKI, Atsuto; MOMIYAMA, Norie
1H4-45
Synthesis of novel cinchona alkaloid-peptide hybrid catalyst and their application to asymmetric reaction (TUT) º KUBO, Yuki; HARAGUCHI, Naoki; ITSUNO, Shinichi
1H4-46
Asymmetric Michael addition of active methylene compounds to nitroalkens catalyzed by amino alcohol oraganocatalyst (Sch. Eng., Muroran Inst. of Tech.) º SANNABE, Haruka; NAKANO, Hiroto
1H4-47
Development of asymmetric epoxidation reaction of 2,3-disubstituted 1,4-naphthoquinone derivatives using guanidine-bisurea bifunctional organocatalyst (Fac. Eng., Tokyo Univ. of Agri. and Technol.; Fac. Sci., TUS) º ORIHARA, Tatsuya; KAWAGUCHI, Masaki; HOSOYA, Keisuke; ODAGI, Minami; NAGASAWA, Kazuo
Chair: HARAGUCHI, Naoki
(17:00-18:00)
* 16:50-17:00: interval for laptop PC connection.(1H4-49, 1H4-50, 1H4-51, 1H4-52, 1H4-53, 1H4-54)
1H4-49
Asymmetric Synthesis of 2-substituted Tetrahydroquinolines by Reduction of Nitro Compounds and Enantioselective Reductive Amination (Fac. Sci., Gakushuin Univ.) º KOBAYASHI, Nanako; SUGA, Takuya; AKIYAMA, Takahiko
1H4-50
Kolbe-Schmitt Reaction on Resorcinols mediated by Organic Base (Fac. Sci. Tech., Keio Univ.) SADAMITSU, Yuta; º OKUMURA, Akira; SAITO, Kodai; YAMADA, Tohru
1H4-51
Asymmetric Synthesis of 2-Cyclopentenones based on the Chirality Transfer of Decarboxylative Nazarov Cyclization (Fac. Sci. Tech., Keio Univ.) º KOMATSUKI, Keiichi; KOZUMA, Akane; SAITO, Kodai; YAMADA, Tohru
1H4-52
Effect of E : Z ratio of substrate in phase-transfer catalyzed asymmetric umpolung reaction of α-iminoamides (Grad. Sch. Eng., Chiba Univ.) º HIROSHIGE, Tomohiko; YOSHIDA, Yasushi; MINO, Takashi; SAKAMOTO, Masami
1H4-53
Phase-transfer catalyzed asymmetric synthesis of chiral aminals through umpolung reaction of α-iminoamides (Grad. Sch. Eng., Chiba Univ.; Fac. Eng., Chiba Univ.) º OMORI, Kazuki; YOSHIDA, Yasushi; HIROSHIGE, Tomohiko; MINO, Takashi; SAKAMOTO, Masami
1H4-54
Development of stacked-arene based organocatalyst (Fac. Eng., Tokyo Univ. of Agri. and Technol.) º OTAWA, Yuna; INOUE, Aiko; MORI, Keiji
Wednesday, March 21, AM
Chair: KUWANO, Satoru
(09:00-10:00)
* 8:50-9:00: interval for laptop PC connection.(2H4-01, 2H4-02, 2H4-03, 2H4-04, 2H4-05, 2H4-06)
2H4-01#
Asymmetric synthesis of tritylpyrrolidine derivatives and their application to asymmetric benzoyloxylation (Dep. Chem., Sch. Sci., Kyoto Univ.) º SHIMOGAKI, Mio; MARUYAMA, Hiroki; HOMMA, Chihiro; KANO, Taichi; MARUOKA, Keiji
2H4-02#
Chiral amine-catalyzed asymmetric conjugate addition of aldehydes to α-phenylselenoenones as formal Z-allylating agents (Dep. Chem., Sch. Sci., Kyoto Univ.) º HOMMA, Chihiro; MARUYAMA, Hiroki; KANO, Taichi; MARUOKA, Keiji
2H4-03#
Catalyst-controlled diastereoselectivity switch in formation of dihydropyrans (Dep. Chem., Sch. Sci., Kyoto Univ.) º MARUYAMA, Hiroki; HOMMA, Chihiro; KANO, Taichi; MARUOKA, Keiji
2H4-04
Enantioselective allylic chlorination by a chiral electrophilic selenium catalyst (Dep. Chem., Sch. Sci., Kyoto Univ.) º NAGAOKA, Hitoshi; HASHIMOTO, Takuya; MARUOKA, Keiji
2H4-05#
A chiral iodine catalyst for enantioselective hydrative dearomatization (Dep. Chem., Sch. Sci., Kyoto Univ.) º SHIMAZAKI, Yuto; OMATSU, Yamato; HASHIMOTO, Takuya; MARUOKA, Keiji
2H4-06
Organic Base-Catalyzed [5+2] Cycloadditions between Oxidopyrylium Ylides and Alkenes (Fac. Eng., Shinshu Univ.) º SHIMIZU, Masahiro; IWAI, Taichi; TODA, Yasunori; SUGA, Hiroyuki
Chair: AMII, Hideki
(10:10-11:10)
* 10:00-10:10: interval for laptop PC connection.(2H4-08, 2H4-09, 2H4-10, 2H4-11)
2H4-08
Experimental verification of stereocontrol mechanism of entropy-dependent asymmetric aza-Friedel-Crafts reaction using guanidine-bisthiourea organocatalyst (Grad. Sch. Fac. Eng., Tokyo Univ. of Agri. and Technol.; Coll. Sci., Rikkyo Univ.) º KAWAGUCHI, Masaki; NAKANO, Katsuhiro; HOSOYA, Keisuke; ODAGI, Minami; YAMANAKA, Masahiro; NAGASAWA, Kazuo
2H4-09
Theoretical Study on Guanidine-Bisthiourea Bifunctional Organocatalysis in Entropy-Driven Asymmetric Friedel-Crafts Reaction (Grad. Sch. Sci., Rikkyo Univ.; Grad. Sch. Fac. Eng., Tokyo Univ. of Agri. and Technol.) º NAKANO, Katsuhiro; KAWAGUCHI, Masaki; HOSOYA, Keisuke; ODAGI, Minami; NAGASAWA, Kazuo; YAMANAKA, Masahiro
2H4-10
Asymmetric Mannich Reaction of Malononitrile with N-Boc Imines Using Halogen Bonding Donor/Organic Base Combined Catalyst (Grad. Sch. Sci., Chiba Univ.) º KUWANO, Satoru; SUZUKI, Takumi; ARAI, Takayoshi
2H4-11 Young Scholar Lectures of CSJ
Development of Chemoselective Reactions by Exploiting Characteristic Feature of Copper(I) Catalyst (Fac. Sci., Hokkaido Univ.) º SHIMIZU, Yohei
Wednesday, March 21, PM
Chair: YAJIMA, Tomoko
(13:00-13:50)
* 12:50-13:00: interval for laptop PC connection.(2H4-25, 2H4-26, 2H4-27, 2H4-28, 2H4-29)
2H4-25
Palladium-Catalyzed Regioselective Stannylation of Difluoroallenes (Div. of Chem., Fac. Pure Appl. Sci., Univ. of Tsukuba) º HIDANO, Tomohiro; IMAOKA, Hisanori; FUCHIBE, Kohei; ICHIKAWA, Junji
2H4-26
Synthetic application of CF3-containing allenes (Grad. Sch. Fac. Eng., Tokyo Univ. of Agri. and Technol.) º KAMURA, Yuma; KAWASAKI-TAKASUKA, Tomoko; YAMAZAKI, Takashi
2H4-27
Substitution reaction on an asymmetric sp3 carbon center attached with a fluoroalkyl group via fluorine-containing π-allylpalladium complex (KIT) º KAWAZOE, Machiko; YAMADA, Shigeyuki; KONNO, Tsutomu
2H4-28
Efficient approaches to various cyclic compounds with a tetrafluoroethylene fragment based on the intramolecular cyclization (KIT) º MORISHITABARA, Suguru; NISHI, Yuji; YAMADA, Shigeyuki; KONNO, Tsutomu
2H4-29
Novel synthesis of various fluorine-containing indenols based on cobalt-catalyzed [2+3] cycloaddition (KIT) º YOSHIDA, Kazuhiro; KUMON, Tatsuya; YAMADA, Shigeyuki; KONNO, Tsutomu
Chair: KONNO, Tsutomu
(14:00-14:40)
* 13:50-14:00: interval for laptop PC connection.(2H4-31, 2H4-32, 2H4-33, 2H4-34)
2H4-31
Trifluoromethylthiolation with CF 3-DAST under Metal-free Conditions (Grad Sch. Eng., Nagoya Inst. of Tech.) º YOSHIOKA, Takuya; SAIDALIMU, Ibrayim; TOKUNAGA, Etsuko; SHIBATA, Norio
2H4-32
Pre-Catalyst Effects in Catalytic Difluoromethylation (Sch. Mater. & Chem. Tech., Tokyo Tech.) º HORI, Kaishi; MOTOHASHI, Hirotaka; SAITOU, Daichi; MIKAMI, Koichi
2H4-33
Synthesis of o-(difluoromethyl)benzoates via benzocyclobutenone intermediates (Grad. Sch. Sci. Tech., Gunma Univ.; Grad. Sch. Sci. Tech., Gunma Univ.) º OSHIMA, Takuya; KOMODA, Kazuki; SUGIISHI, Tsuyuka; AMII, Hideki
2H4-34
Enantioselective difluoromethlylation of MBH-fluorides via C-F bond activation (Grad Sch. Eng., Nagoya Inst. of Tech.) º UNO, Hiroto; WANG, Jiandong; TOKUNAGA, Etsuko; SHIBATA, Norio
Chair: SHIBATA, Norio
(17:00-17:40)
* 16:50-17:00: interval for laptop PC connection.(2H4-49, 2H4-50, 2H4-51, 2H4-52)
2H4-49
Organic dye catalyzed Visible Light induced Perfluoroalkylation-Cyclization (Grad. Sch. Of Humanities & Sci., Ochanomizu Univ.) º SANO, Moeka; YAJIMA, Tomoko
2H4-50
Enamine Catalyzed Photoinduced Perfluoroalkylation of Olefines (Grad. Sch. Of Humanities & Sci., Ochanomizu Univ.) º MURASE, Mao; YAJIMA, Tomoko
2H4-51
Synthesis and Structure of Crown Ethers Bearing Perfluorocyclopentene Units (I) (Coll. Eng., Ibaraki Univ.) º FUKUMOTO, Hiroki; NAKASHIMA, Shinnosuke; AGO, Tomohiro; KUBOTA, Toshio
2H4-52
synthesis and structure of Crown Ethers Bearing Perfluorocyclopentene Units (Grad. Sch. Sci. Eng., Ibaraki Univ.) º NAKASHIMA, Shinnosuke; HUKUMOTO, Hiroki; KUBOTA, Toshio; AGO, Tomohiro
Thursday, March 22, AM
Chair: HIRANO, Koji
(09:00-10:00)
* 8:50-9:00: interval for laptop PC connection.(3H4-01, 3H4-02, 3H4-03, 3H4-04, 3H4-05, 3H4-06)
3H4-01
Assessment of 4-methyltetrahydropyran (4-MeTHP): Applications as an organic reaction solvent as well as degradation mechanisms under the radical reaction conditions (Fac. Eng., OIT) º TAMURA, Tomoki; MASUYAMA, Araki; KOBAYASHI, Shoji
3H4-02
Photochemical radical addition of alcohols to olefins using sunlight and t-Bu2O2 (Coll. Sci. Tech., Nihon Univ.; Coll. Sci. Tech., Nihon Univ.) º HAYAKAWA, Mamiko; MASHIMO, Hiroshi; UCHIDA, Kou; AOYAMA, Tadashi; OUCHI, Akihiko
3H4-03
Development of sp3 C-H functionalization using novel sulfonamide HAT catalysts (Grad. Sch. Pharm., The Univ. of Tokyo) º SAKAI, Kentaro; TANAKA, Hirotaka; KAWAMURA, Atsushi; OISAKI, Kounosuke; KANAI, Motomu
3H4-04
Photocatalytic Keto-difluoromethylation of Olefins (Lab. Chem. Life Sci., Tokyo Tech.) º NAKAYAMA, Yoshiki; ANDO, Gaku; KOIKE, Takashi; AKITA, Munetaka
3H4-05
Catalytic photo-oxidation of saturated hydrocarbons within a photo-responsive hollow complex and an electron-accepting co-catalyst (Grad. Sch. Eng., The Univ. of Tokyo) ROTA MARTIR, Diego; º ADACHI, Kiyohiro; TAKEZAWA, Hiroki; FUJITA, Makoto
3H4-06
Organocatalytic intermolecular [2+2] cycloaddition of norbornadienes by a stable organic radical compound (Grad. Sch. Eng., Tokyo City Univ.) º KYOKANE, Shuji; TANAKA, Yusuke; SHIOTSUKI, Masashi
Chair: KOBAYASHI, Shoji
(10:10-11:10)
* 10:00-10:10: interval for laptop PC connection.(3H4-08, 3H4-09, 3H4-10, 3H4-11, 3H4-13)
3H4-08
Sequential Generation of Imidoyl Radicals from Bis(silyl)imines through Photo-Induced Single Electron Transfer Processes and Their Coupling Reaction with Unsaturated Carbonyls (Fac. Sci., Gakushuin Univ.) º MATSUDA, Ryota; OHYAMA, Tomoya; ISHIDA, Kento; KUSAMA, Hiroyuki
3H4-09#
Synthesis of Diarenopentalenes: Consecutive Photo-induced Preparation of Hydrogen Iodide and Its Addition to Sondheimer-Wong Diyne (Fac. of Eng., Okayama Univ. of Sci.) º AKIHIRO, Orita; TAKANORI, Nishida; YASUHIRO, Okuda; TAKAFUMI, Hagihara; KAN, Wakamatsu
3H4-10
vic-Diphosphination of Alkenes under Visible-Light-Promoted Photoredox Catalysis (Grad. Sch. Eng., Osaka Univ.) º OTOMURA, Nobutaka; OKUGAWA, Yuto; HIRANO, Koji; MIURA, Masahiro
3H4-11*#
Aromatic radical cations generated by iron(III) salts which induce [4 + 2] and [2 + 2] cycloadditions (Grad. Sch. Eng., Nagoya Univ.; Inst. Adv. Res., Nagoya Univ.) º HORIBE, Takahiro; OHMURA, Shuhei; ISHIHARA, Kazuaki
3H4-13
Catalytic Aminium Radical Cation-initiated Synthesis of 1-Arylcyclopent-1-enes from Styrenes and Dienes (Sch. Eng., Nagoya Univ.) º HIRAMATSU, Rin; OHMURA, Shuhei; HORIBE, Takahiro; ISHIHARA, Kazuaki
Chair: KOIKE, Takashi
(11:20-12:20)
* 11:10-11:20: interval for laptop PC connection.(3H4-15, 3H4-17, 3H4-19)
3H4-15*#
Visible green light-promoted radical cation Diels-Alder reaction catalyzed by thioxanthylium-based organophotoredox catalysts (Grad. Sch. Fac. Env. and Info. Sci., Yokohama Natl. Univ.) º TANAKA, Kenta; HOSHINO, Yujiro; HONDA, Kiyoshi
3H4-17*#
Development of Flavin-Amine Integrated Catalysts for Dual Photoredox and Enamine Catalysis (Tokushima Univ., Dept. Appl. Chem.) º TAGAMI, Takuma; ARAKAWA, Yukihiro; MINAGAWA, Keiji; IMADA, Yasushi
3H4-19*#
Generation of α-Iminyl Radicals from α-Bromo N-Sulfonylimines by Photoredox Catalyst and Application to Various Radical Reactions (Sch. Eng., Osaka Univ.) º ESUMI, Naoto; SUZUKI, Kensuke; NISHIMOTO, Yoshihiro; YASUDA, Makoto
Thursday, March 22, PM
Chair: MIYAGAWA, Masamichi
(13:30-14:30)
* 13:20-13:30: interval for laptop PC connection.(3H4-28, 3H4-29, 3H4-30, 3H4-31, 3H4-32)
3H4-28
Phthalimide for Photofluorination of C-H Bond (Univ. of Shizuoka) º EGAMI, Hiromichi; MASUDA, Shuya; KAWATO, Yuji; HAMASHIMA, Yoshitaka
3H4-29
Selective point fluorinated Carboxyrates Synthesis of using Mukaiyama aldol reaction (Fac. Eng., Tottori Univ.) º KURODA, Kana; HAYASHI, Shiho; NOKAMI, Toshiki; ITOH, Toshiyuki
3H4-30
Reactions of α-Fluorobenzyl Dianion Equivalents (Grad. Sch. Sci. Tech., Gunma Univ.) º TAGAMI, Yuta; KITAHARA, Taku; ONO, Masaki; SUGIISHI, Tsuyuka; MATSUBARA, Seijiro; AMII, Hideki
3H4-31
[4+2] Cycloaddition of fluorinated benzocyclobutenone derivatives with carbonyl compounds (Grad. Sch. Sci. Tech., Gunma Univ.) º KOMODA, Kazuki; TANAKA, Ibuki; SUGIISHI, Tsuyuka; AMII, Hideki
3H4-32*#
Fluorinated diazoalkanes and beyond (RWTH Aachen University) º HOCK, Katharina Julia; KOENIGS, Rene Michael
Chair: ITOH, Toshiyuki
(14:40-15:40)
* 14:30-14:40: interval for laptop PC connection.(3H4-35, 3H4-36, 3H4-37, 3H4-38, 3H4-39, 3H4-40)
3H4-35
Stereochemistry of α-fluoro-β,γ-unsaturated esters by Horner-Wadsworth-Emmons reaction (Grad. Sch. Sci. Eng., Univ. of Toyama) º YOKOYAMA, Hajime; NAKAI, Yuya; MIYAZAWA, Masahiro
3H4-36#
Development of Tandem Enantioselective Intramolecular Rauhut Currier Reaction and Aldol Condensation Promoted by Peptide Catalyst (IIS, The Univ. of Tokyo) º YINGQI, Tian; ZHAONAN, Du; KENGO, Akagawa; KAZUAKI, Kudo
3H4-37#
Enantioselective Direct Mannich-Type Reaction of 2-Benzylpyridine N-Oxide Catalyzed by Chiral Bis(guanidino)iminophosphorane Organosuperbase (Grad. Sch. Sci., Tohoku Univ.) º HU, Qiupeng; KONDOH, Azusa; TERADA, Masahiro
3H4-38#
Enantioselective Friedel-Crafts Alkylation Reaction of Indoles with non-activated β-Alkyl-β-Nitrostyrenes Catalyzed by Chiral BINOL Phosphates (Fac. Sci., Gakushuin Univ.) º KANEKO, Mio; IBÁÑEZ SÁNCHEZ, Ignacio; AKIYAMA, Takahiko
3H4-39
1,3-Dipolar Cycloadditions between Carbonyl Ylides and Imines Catalyzed by a Rhodium Complex and Lewis Acid Binary System (Fac. Eng., Shinshu Univ.) º KAKU, Wakatake; TURUOKA, Makoto; TODA, Yasunori; SUGA, Hiroyuki
3H4-40
Chiral Lewis Acid-Catalyzed Asymmetric Cycloaddition Reactions between Cyclic Azomethine Ylides and N-Acryloyl Pyrazolidinone (Fac. Eng., Shinshu Univ.) º YOSHIWARA, Masahiro; YAMAGUCHI, Takaaki; TODA, Yasunori; SUGA, Hiroyuki
Chair: SAITO, Akio
(15:50-16:50)
* 15:40-15:50: interval for laptop PC connection.(3H4-42, 3H4-44, 3H4-46, 3H4-47)
3H4-42*#
Site-selective Transformation of Carbonyl-neighboring Azido Group to Clickable Functional Group (Grad. Sch. Mat. Sci., NAIST) º YOKOI, Taiki; UEDA, Tomomi; TANIMOTO, Hiroki; KAKIUCHI, Kiyomi
3H4-44*#
Chiral Nucleophilic Amidophosphate-Catalyzed Enantioselective Halocyclization (Grad. Sch. Eng., Nagoya Univ.) º LU, Yanhui; NAKATSUJI, Hidefumi; OKUMURA, Yukimasa; ISHIHARA, Kazuaki
3H4-46
Selenium-Iodine Cooperative Catalysts for Chlorocyclization of Tryptamine Derivatives with NCS (Grad. Sch. Eng., Nagoya Univ.) º OHMURA, Shuhei; HORIBE, Takahiro; ISHIHARA, Kazuaki
3H4-47
Halogen-Based Lewis Acid-Thiourea Lewis Base Cooperative Catalysts for Iodochlorination of Alkenes with In-situ Generated Iodine Monochloride (Grad. Sch. Eng., Nagoya Univ.) º TSUJI, Yasutaka; HORIBE, Takahiro; ISHIHARA, Kazuaki
Chair: TANIMOTO, Hiroki
(17:00-17:30)
* 16:50-17:00: interval for laptop PC connection.(3H4-49, 3H4-51)
3H4-49*
Halogen Atom Controlled Dehalolactonization Reaction of Keto Acids using Basic Catalyst (R-GIRO; Coll. Pharm. Sci., Ritsumeikan Univ.) º CHINA, Hideyasu; NISHIGUCHI, Kaishi; KOJIMA, Yusuke; DOHI, Toshifumi
3H4-51#
3-Aryl-2,3,4,5,6,7-hexahydro-1H-inden-1-ones: Novel one-pot methodology for synthesis and evaluation of antimicrobial activity (Dept. of Chem., Advinus Therapeutics Ltd., India) º PATI, Hari; MOGER, Manjunath
Friday, March 23, AM
Chair: HORIBE, Takahiro
(09:00-10:00)
* 8:50-9:00: interval for laptop PC connection.(4H4-01, 4H4-02, 4H4-03, 4H4-05, 4H4-06)
4H4-01
EtAlCl2 and 2,6-dibromopyridine-mediated acylation of alkenes with acid chlorides (Grad. Sch. Eng., Tohoku Univ.) º KUNISAWA, Tsukasa; YOSHII, Yuuji; TANAKA, Shinya; HATTORI, Tetsutaro
4H4-02#
N-PFB-PyBidine- Zn(OAc)2 -Catalyzed Asymmetric Chlorination of β-Ketoesters. (Grad. Sch. Sci., Chiba Univ.) º MA, Junma; ARAI, Takayoshi; SHIRASUGI, Mayu
4H4-03*#
Chiral Lewis Acid-Single Walled Carbon Nanotube (SWNT)-Integrated Catalysts Enabled an Efficient Reaction in Water (Grad. Sch. Sci., The Univ. of Tokyo) º KITANOSONO, Taku; XU, Pengyu; KOBAYASHI, Shu
4H4-05
Development of immobilized chiral 2,2’-bipyridine ligands for enantioselective reactions in water (Grad. Sch. Sci., The Univ. of Tokyo) º LU, Fangqiu; MASUDA, Koichiro; KITANOSONO, Taku; KOBAYASHI, Shu
4H4-06
Development of photo-responsive chiral 2,2'-bipyridine ligands for photochemical reactions in water (Grad. Sch. Sci., The Univ. of Tokyo) º NISHIMURA, Yuma; KITANOSONO, Taku; KOBAYASHI, Shu
Chair: ASANO, Keisuke
(10:10-11:10)
* 10:00-10:10: interval for laptop PC connection.(4H4-08, 4H4-09, 4H4-10, 4H4-11, 4H4-12, 4H4-13)
4H4-08
Function of chiral bis(aminoimino)binaphthol-zinc trinuclear complex in catalytic asymmetric iodolactonization and its application to desymmetrization (Grad. Sch. Sci., Chiba Univ.) º HORIGANE, Kodai; KAMEI, Yuto; YAMANAKA, Masahiro; ARAI, Takayoshi
4H4-09
Pictet-Spengler Reaction Promoted by Halogen Bond Donor (Fac. Sci., Gakushuin Univ.) º TANAKA, Yoshihiro; MIYAGAWA, Masamichi; AKIYAMA, Takahiko
4H4-10#
Development of Pyrene-based Scandium Lewis Acid Catalyst (School of Science, The University of Tokyo) º ZHANG, Dongxin; KITANOSONO, Taku; KOBAYASHI, Shu
4H4-11#
Cyclocondensation reactions in water catalyzed by solid acid catalysts (School of Science, The University of Tokyo) º CHO, Soo Min; KITANOSONO, Taku; KOBAYASHI, Shu
4H4-12
Intramolecular Cyclopropanation Using Immobilized Chiral Catalyst (Grad. Sch. Advanced Sci. Eng., Waseda Univ.) º HOSHINO, Yunosuke; UWAMORI, Masahiro; NAKADA, Masahisa
4H4-13
Aziridination of Olefins with Sulfamate Esters as Nitrogen Sources Using tert-butyl hypoiodite (Sch. Eng., Osaka Univ.) º NAKAMURA, Shogo; KIYOKAWA, Kensuke; MINAKATA, Satoshi
Chair: KIYOKAWA, Kensuke
(11:20-12:20)
* 11:10-11:20: interval for laptop PC connection.(4H4-15, 4H4-16, 4H4-17, 4H4-18, 4H4-19, 4H4-20)
4H4-15
trans-Cyclooctenes as Catalysts in Halolactonization (Grad. Sch. Eng., Kyoto Univ.) º SHITAMICHI, Kenta; ASANO, Keisuke; MATSUBARA, Seijiro
4H4-16
Optically Active trans-Cyclooctenes as Ligands in Rhodium-catalyzed Asymmetric 1,4-Addition (Grad. Sch. Eng., Kyoto Univ.) º NAGANO, Tagui; EINARU, Shunsuke; SHITAMICHI, Kenta; ASANO, Keisuke; MATSUBARA, Seijiro
4H4-17
Acid-catalyzed Chirality-transferring Intramolecular Friedel-Crafts Reaction of α-Hydroxy-α-alkenylsilanes (Grad. Sch. Sci., Osaka City Univ.) º KUBOTA, Shunnichi; AKAGI, Wataru; IKEDA, Naoko; HIGASHINO, Masato; SHINADA, Teturo; OHUNE, Yasuhumi; NISHIMURA, Takahiro; SAKAGUCHI, Kazuhiko
4H4-18
Synthesis of Spiro[2.3]hexane by Catalytic Annulation of Methylenecyclopropane with Activated Alkene (Grad. Sch. Eng., Osaka Univ.) º SHIMAZU, Junya; SUZUKI, Itaru; SHIBATA, Ikuya
4H4-19
the unprecedented thermal cyclization reaction between diazoketone and olefin (Sch. Advanced Sci. Eng., Waseda Univ.) º UDAGAWA, Yutaro; HOSOKAWA, Seijiro
4H4-20
Me3P-promoted alcoholysis of α,β-unsaturated imides and α,β-unsaturated ester (Grad. Sch. Advanced Sci. Eng., Waseda Univ.) º SATO, Haruka; HOSOKAWA, Seijiro
Friday, March 23, PM
Chair: HACHIYA, Iwao
(13:40-14:40)
* 13:30-13:40: interval for laptop PC connection.(4H4-29, 4H4-30, 4H4-31, 4H4-33, 4H4-34)
4H4-29
Construction of Axial Chirality via Halogenation of 1-(3-Hydroxyphenyl)-2-naphthonitriles Using Bifunctional Organocatalysts (Grad. Sch. Eng., Kyoto Univ.) º WADA, Yuuki; MATSUMOTO, Akira; ASANO, Keisuke; MATSUBARA, Seijiro
4H4-30
Asymmetric Formation of Optically Active Tetrahydropyrans via Simultaneous Construction of Three Chiral Centers (Grad. Sch. Eng., Kyoto Univ.) º KURIMOTO, Yosuke; ASANO, Keisuke; MATSUBARA, Seijiro
4H4-31*#
Asymmetric Cycloetherification via Cyanation of Acylsilanes Using Bifunctional Organocatalysts (Grad. Sch. Eng., Kyoto Univ.) º MATSUMOTO, Akira; ASANO, Keisuke; MATSUBARA, Seijiro
4H4-33
Substituent effect of anilines or benzylamine toward Michael addition using under microwave irradiation (Graduate School of Engineering, Kanto Gakuin University) º OKAWA, Mitsuki; TAKAHASHI, Kie; IIDA, Hirokazu
4H4-34#
Direct asymmetric Michael reaction of α,β-unsaturated aldehydes and ketones catalyzed by two secondary amine catalysts (Grad. Sch. Sci., Tohoku Univ.) º UMEKUBO, Nariyoshi; TERUNUMA, Takahiro; HAYASHI, Yujiro
Chair: IIDA, Hirokazu
(14:50-15:50)
* 14:40-14:50: interval for laptop PC connection.(4H4-36, 4H4-37, 4H4-38, 4H4-39, 4H4-40, 4H4-41)
4H4-36
Highly stereoselective oxy-homo-Michael reaction and 1,5-addition to enantioenriched donor-acceptor cyclopropanes (Fac. Textile Sci. Technol., Shinshu Univ.) º SAITO, Taichi; NISHII, Yoshinori
4H4-37
Chiral transfer ring opening cyclization of enantioenriched donor-acceptor cyclopropanes and its application to total synthesis of bioactive lignin amide. (Fac. Textile Sci. Technol., Shinshu Univ.) º TAKAKI, Naoya; YAMADA, Satoshi; NISHII, Yoshinori
4H4-38
Hidrogenolysis of enantioenriched donor-acceptor cyclopropanes using Pd-catalysts or other metal catalysts. (Fac. Textile Sci. Technol., Shinshu Univ.) NISHII, Yoshinori; º OTA, Ryotaro
4H4-39
Synthesis of DACN Derivatives with Thia-Michael Reactive Moiety and Their Reactions (IMCE, Kyushu Univ.; Grad. Sch. Eng. Sci., Kyushu Univ.) KAWASAKI, Yuuya; º SETO, Yuuki; KAWAHARA, Shintarou; AOYAMA, Shin; IGAWA, Kazunobu; TOMOOKA, Katsuhiko
4H4-40
Synthesis of N-Fmoc-amino-acid-DACN and Its Application (IMCE, Kyushu Univ.; Fac. Eng., Kyushu Univ.) KAWASAKI, Yuuya; º KAWAHARA, Shintarou; SETO, Yuuki; IGAWA, Kazunobu; TOMOOKA, Katsuhiko
4H4-41
Synthesis of DACN-containing Polymer and Click Reaction Thereof (IMCE, Kyushu Univ.; Grad. Sch. Eng. Sci., Kyushu Univ.) IGAWA, Kazunobu; º YAMANAKA, Yuki; AOYAMA, Shin; KAWASAKI, Yuuya; TOMOOKA, Katsuhiko
Chair: IGAWA, Kazunobu
(16:00-17:00)
* 15:50-16:00: interval for laptop PC connection.(4H4-43, 4H4-44, 4H4-45, 4H4-46, 4H4-47, 4H4-48)
4H4-43
Desymmetrization of meso-1,4-Dioxane Derivatives by Asymmetric Reductions and Its Application (Grad. Sch. Eng., Mie Univ.) º YAMAMOTO, Kenta; HACHIYA, Iwao; SHIMIZU, Makoto
4H4-44
Nanoporous Gold Catalyst for Hydrogen-Transfer Reductive Amination of Carbonyl Compounds with Formic Acid (Fac. Textile Sci. Technol., Shinshu Univ.) º MIYAUCHI, Masato; KAVTHE, Rahul; ASAO, Naoki
4H4-45#
Development of Bidentate Diphosphine Ligands of Highly Active Ru Catalysts for Practical Hydrogenation of Carboxylic Acids (Grad. Sch. Sci., Nagoya Univ.) º YOSHIOKA, Shota; NARUTO, Masayuki; NOYORI, Ryoji; SAITO, Susumu
4H4-46
Development of Hydrogenation of α-Amino Alcids to Optically Active β-Amino Alcohols via Ru-α-Aminocarboxylates as Catalyst Prototypes (Grad. Sch. Sci., Nagoya Univ.) º SAITO, Akari; YOSHIOKA, Shota; NOYORI, Ryoji; SAITO, Susumu
4H4-47
Asymmetric Reduction of Trifluoromethylated Alkynylketimine by Chiral Phosphoric Acid (Fac. Sci., Gakushuin Univ.) º TAKASHIMA, Kensuke; MIYAGAWA, Masamichi; AKIYAMA, Takahiko
4H4-48
Enantioselective Nucleophilic Addition Reaction of Heteroaromatics to Trifluoromethylated N-H Ketimines by Means of Chiral Phosphoric Acid (Fac. Sci., Gakushuin Univ.) º YOSHIDA, Masaru; MIYAGAWA, Masamichi; AKIYAMA, Takahiko