The 97th Annual Meeting of The Chemical Society of Japan

Date: March 16th - 19th, 2017

Venue: Hiyoshi Campus, Keio University, Yokohama, Japan

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Room E8

Fourth Building Independence Wing D310


[Organic Chemistry -Reaction and Synthesis- Heteroatom Compounds]


Thursday, March 16, AM

Chair: YAMAMURA, Masaki (10:10-11:10)

* 10:00-10:10: interval for laptop PC connection.(1E8-08, 1E8-09, 1E8-10, 1E8-11, 1E8-12, 1E8-13)

1E8-08
Synthesis, structure and reactivity of diborydiphosphene dianion (Grad. Sch. Sci. Eng., Chuo Univ.; Fac. Sci. Eng., Chuo Univ.; Grad. Sch. Eng., Nagoya Univ.) º ASAMI, Shun-suke; SUZUKI, Katsunori; YAMASHITA, Makoto

1E8-09
Reaction of double bonds between heavier main group elements with NHC (Fac. Sci. Eng., Kindai Univ.) º SADAMORI, Kazuya; HAYAKAWA, Naoki; TSUJIMOTO, Shota; HATANAKA, Miho; WAKABAYASHI, Tomonari; MATSUO, Tsukasa

1E8-10
Reactions of Stable Dialkylphosphinyl Radical with Borane-complexes (Grad. Sch. Sci., Tohoku Univ.) º ICHIKAWA, Hitomi; ISHIDA, Shintaro; IWAMOTO, Takeaki

1E8-11
Synthesis, Structure, and Property of Bulky 2,2,5,5-tetraaryl-1-phosphacyclopentanes (Grad. Sch. Sci., Tohoku Univ.) º MIURA, Yasunori; ISHIDA, Shintaro; IWAMOTO, Takeaki

1E8-12
Development of Electrophilic C−H Borylation of Aromatic Compounds (Sch. Sci. Tech., Kwansei Gakuin Univ.) º UEURA, Kenta; ODA, Susumu; HATAKEYAMA, Takuji

1E8-13
Mechanistic Study on the Reaction of Tetraaryldiborane(4) with Dihydrogen (Grad. Sch. Sci. Eng., Chuo Univ.; Grad. Sch. Eng., Nagoya Univ.; Hong Kong Univ. Sci. Tech.) º TSUKAHARA, Nana; ASAKAWA, Hiroki; YAMASHITA, Makoto; LEE, Ka-ho; LIN, Zhenyang


Chair: SUZUKI, Katsunori (11:20-12:20)

* 11:10-11:20: interval for laptop PC connection.(1E8-15, 1E8-17, 1E8-18, 1E8-19, 1E8-20)

1E8-15*
Structure and photosensitized reaction of chiral BODIPY derivatives with circularly polarized luminescence (CPL) (Grad. Sch. Sci. Eng., Kindai Univ.) º TAKEUCHI, Noritaka; NAKAHODO, Tsukasa; FUJIHARA, Hisashi

1E8-17
Synthesis and Properties of Chiral Phosphangulenes Having Fluorescent Units (Grad. Sch. Pure Appl. Sci., Univ. of Tsukuba) º NIN, Kazu; SUKEGAWA, Kimiya; YAMAMURA, Masaki; NABESHIMA, Tatsuya

1E8-18
Synthesis and Physical Properties of Nitrogen-Centered Triphosphatriangulenes (Sch. Sci. Tech., Kwansei Gakuin Univ.) º WATANABE, Yusuke; NAKATSUKA, Soichiro; HATAKEYAMA, Takuji

1E8-19
Redox properties of aromatic compounds containing a phosphorus atom (Fac. Sci., Fukuoka Univ.) NAGAHORA, Noriyoshi; º HANADA, Takuya; OGAWA, Tamaki; SHIOJI, Kosei; OKUMA, Kentaro

1E8-20
Synthesis and fluorescence sensing properties of (D-π) 3-A type triazine derivatives with aza-crown ethers as an electron donating group (Iwate Univ. Fac. of Sci. and Engin.) º SASAKI, Hikaru; MURAOKA, Hiroki; OGAWA, Satoshi


Thursday, March 16, PM

Chair: TAJIMA, Tomoyuki (13:30-14:30)

* 13:20-13:30: interval for laptop PC connection.(1E8-28, 1E8-29, 1E8-30, 1E8-32, 1E8-33)

1E8-28
Development of Chiral Phase-Transfer Catalyzed Asymmetric Umpolung Michael Addition Reaction of α-iminoesters (Grad. Sch. Eng., Chiba Univ.) º MORIYA, Yuta; YOSHIDA, Yasushi; MINO, Takashi; SAKAMOTO, Masami

1E8-29
Development of Chiral Phase-Transfer Catalyzed Asymmetric Umpolung Domino Cyclization Reaction of α-Iminoamides (Fac. Eng., Chiba Univ.) º HIROSHIGE, Tomohiko; YOSHIDA, Yasushi; MINO, Takashi; SAKAMOTO, Masami

1E8-30*
Synthesis, Structure, and Reactivity toward Burgess Reagent of Amidinopyrroles and Amidinoimidazoles (Sch. Sci., Kitasato Univ.) KUROTAKI, Takanori; SAWAMURA, Yukihiro; KIKUCHI, Yuichi; ABE, Shinya; º UCHIYAMA, Yosuke; RUNYON, Jason; DOLPHIN, Joshua; SCHINNEN, Christoph; ARDUENGO, Anthony

1E8-32
Synthesis of an N-Heterocyclic Carbene Bearing 9-Triptycylmethyl Groups and its Metal Complexes (Coll. Sci., Rikkyo Univ.) º HARA, Natsuko; MINOURA, Mao

1E8-33
Development of modified Mitsunobu reaction using 2-arylazocarboxylates (Inst. Sci. Eng., Kanazawa Univ.; Inst. Med. Pharm. Health Sci., Kanazawa Univ.) º HIROSE, Daisuke; TANIGUCHI, Tsuyoshi


Chair: UCHIYAMA, Yosuke (14:40-15:40)

* 14:30-14:40: interval for laptop PC connection.(1E8-35, 1E8-36, 1E8-37, 1E8-38, 1E8-39, 1E8-40)

1E8-35
Synthesis and Reaction of Phosphorus- and Silicon Compounds Bearing a Bulky Aromatic Ligand (Coll. Sci., Rikkyo Univ.) º SUZUKI, Fumiaki; MINOURA, Mao

1E8-36
Binaphthyloxy-substituted phosphonoselenoates with allylic groups: synthesis, reduction, and cyclization (Fac. Eng., Gifu Univ.) º IWATA, Koji; MAEKAWA, Yuuki; MURAI, Toshiaki

1E8-37
Synthesis and applications of binaphthyloxy-substituted phosphonates and phosphonochalcogenoates having a tri- and tetrasubstituted carbon center adjacent to a phosphorus atom (Fac. Eng., Gifu Univ.) º MAEKAWA, Yuuki; MURAI, Toshiaki

1E8-38
Synthesis and Structural Determination of Novel Dication Compounds having Heavier Pnictogens as a Central Atom (Grad. Sch. Sci. Eng., TMU) º SAKABE, Masato; SATO, Soichi

1E8-39
Development of arsenic halogenation associated with removal of iodomethane and utilization for nucleophilic reaction (KIT) º TANAKA, Susumu; IMOTO, Hiroaki; NAKA, Kensuke

1E8-40
Synthesis of Pt(II) complex with 9-arsafluorene derivatives having various substituents on the arsenic atom (KIT) º SASAKI, Hiroshi; TANAKA, Susumu; IMOTO, Hiroaki; NAKA, Kensuke


Chair: SASE, Shohei (15:50-16:50)

* 15:40-15:50: interval for laptop PC connection.(1E8-42, 1E8-43, 1E8-44, 1E8-45, 1E8-46, 1E8-47)

1E8-42
Synthesis of 2,6-bisaryldithienoarsole derivatives containing various substituents (KIT) º KAWASHIMA, Ikuo; YAMAZAWA, Chieko; TANAKA, Susumu; IMOTO, Hiroaki; NAKA, Kensuke

1E8-43
Synthesis and Characterization of Aryl-functionalized Dibenzothienotetrathiophene Derivatives (Faculty of Science and Engineering, Iwate University) º SATO, Keita; MURAOKA, Hiroki; OGAWA, Satoshi

1E8-44
Synthesis of Benzo[1,2-b:4,3-b']dithiophene Derivatives Having Triisopropylsilylethynyl Groups. (Fac. Sys. Eng., Wakayama Univ.) º HONDA, Kazuichiro; OSUGA, Hideji; SAKAMOTO, Hidehumi

1E8-45
Photosensitizing Property of Thiocarbonyl Dyes Encapusulated in Single-Walled Carbon Nanotube (Grad. Sch. Env. Sci., Okayama Univ.) º ISHIMOTO, Kango; MIYAKE, Hideaki; TAJIMA, Tomoyuki; OTSU, Yuki; TAKAGUCHI, Yutaka

1E8-46
Synthesis and Properties of a Polyamidoamine Dendrimer Having Mercaptoundecahydrodecaborate Terminals (Grad. Sch. Env. Life Sci., Okayama Univ.) ISIMOTO, Kango; º OTSU, Yuki; TAJIMA, Tomoyuki; TAKAGUCHI, Yutaka

1E8-47
Preparation and Optical and Electrochemical Properties of Diphthalocyanine Linked with a TTF Unit (#Organization for Research Promotion, Iwate Univ.) º KIMURA, Takeshi


Friday, March 17, AM

Chair: MURAOKA, Hiroki (10:10-11:10)

* 10:00-10:10: interval for laptop PC connection.(2E8-08, 2E8-09, 2E8-10, 2E8-11, 2E8-12, 2E8-13)

2E8-08
Radical Mediated Alkylation of Tetrafluoroethylene via Minisci-type Reaction (Sch. Eng., Osaka Univ.) º KUSAKA, Shiori; KIKUSHIMA, Kotaro; OHASHI, Masato; OGOSHI, Sensuke

2E8-09
Synthetic Method of Sulfur-Substituted Difluoroalkenes via Difluoromethylenation of Dithioesters (Div. of Chem., Fac. Pure Appl. Sci., Univ. of Tsukuba) º YAMADA, Atsushi; FUCHIBE, Kohei; ICHIKAWA, Junji

2E8-10
Synthesis of Triflones by Electrophilic Trifluoromethylthiolation Reagents (Fac. Eng. Nagoya Inst. of Tech.) º JIA, Shichong; HUANG, Zhongyan; TOKUNAGA, Etsuko; SUMII, Yuji; SHIBATA, Norio

2E8-11
Elucidation of Reaction Process through β-Halogen Elimination in Vinylic Rosenmund-von Braun Reaction of (E)-(1-bromo-2-iodo-but-1-en-1-yl)benzene (Grad. Sch. Sci. Tech., Ryukoku Univ.) º ENDO, Naoki; IWASAWA, Tetsuo

2E8-12
Development of Facile-Preparable Chiral Hypervalent Iodine(V) Reagents and Their Applications (Grad. Sch. Eng., Chiba Univ.) º MAGARA, Akina; YOSHIDA, Yasushi; MINO, Takashi; SAKAMOTO, Masami

2E8-13
AsymmetricDifluoromethylthiolation Reaction of β-Keto Esters using Difluoromethanesulfonyl Hypervalent Iodonium Ylides (Fac. Eng. Nagoya Inst. of Tech.) º SATOSHI, Gondo; OKIYA, Matsubara; ETSUKO, Tokunaga; SHIBATA, Norio


Chair: NAKAHODO, Tsukasa (11:20-12:10)

* 11:10-11:20: interval for laptop PC connection.(2E8-15, 2E8-16, 2E8-17, 2E8-18, 2E8-19)

2E8-15
Dehydrogenative Coupling of Aryliodinanes with Phenols via [3,3]-Sigmatropic Rearrangement (Dep. Chem., Sch. Sci., Kyoto Univ.) º HORI, Mitsuki; YANAGI, Tomoyuki; NOGI, Keisuke; YORIMITSU, Hideki

2E8-16
Acid anhydride-mediated reactions of aryl sulfoxides with anilines (Dep. Chem., Sch. Sci., Kyoto Univ.) º YANAGI, Tomoyuki; NOGI, Keisuke; YORIMITSU, Hideki

2E8-17
Synthesis of P-chiral phosphonocalcogenoate derivertives with a binaphthyl group via axis-to-center chirality transfer reaction (Fac. Eng., Gifu Univ.) º KUWABARA, Kazuma; MAEKAWA, Yuuki; MURAI, Toshiaki

2E8-18
Synthesis and properties of 2,4,6-tri(5-aryl-2-thienyl)-1,3,5-triazine derivatives modified with electron-donating groups (Faculty of Science and Engineering, Iwate University) º OBARA, Takumi; MURAOKA, Hiroki; OGAWA, Satoshi

2E8-19
Synthesis and Properties of 1,4-Diaryl-1-phosphino-1,3-butadiene Derivatives (Grad. Sch. Sci., Eng., Saitama Univ.) º KIKUSHIMA, Chiharu; NAKATA, Norio; ISHII, Akihiko


Friday, March 17, PM

Chair: SUGAMATA, Koh (14:40-15:40)

* 14:30-14:40: interval for laptop PC connection.(2E8-35, 2E8-36, 2E8-37, 2E8-38, 2E8-39, 2E8-40)

2E8-35
One-Pot Synthesis of a P-Chirogenic Three-Hindered Quadrant Phosphine Ligand (Nippon Chemical Industrial Co.,Ltd.) º IMAMOTO, Tsuneo; TAMURA, Ken

2E8-36
Buchwald-Hartwig Amination Reaction of Phosphinines Bearing Halogen Substituent (Fac. Sci., Fukuoka Univ.) º GOTO, Shoko; NAGAHORA, Noriyoshi; SHIOJI, Kosei; OKUMA, Kentaro

2E8-37
Wittig reactions of a non-stabilized phosphonium ylide bearing a bismaphosphatriptycene skeleton with benzaldehydes and observation of their intermediates (Sch. Sci., Kitasato Univ.) º WATANABE, Ryo; OHTSUKI, Takemaru; MURAKAMI, Rikiya; UCHIYAMA, Yosuke

2E8-38
Substituent Effect of Phosphonate Group in the Ring-Opening Reaction of Cyclobutenes (Grad. Sch. Eng., Kyoto Univ.) º YANO, Takaaki; ISHIDA, Naoki; MURAKAMI, Masahiro

2E8-39
Metal-free reductive deoxygenation of sulfoxides by organosilicon reducing reagent (Grad. Sch. Eng. Sci., Osaka Univ.) º BHATTACHARJEE, Argha; YURINO, Taiga; TSURUGI, Hayato; MASHIMA, Kazushi

2E8-40
A new radical cascade reactions via direct substitution reaction on tin atom (Fac. Eng., Yamaguchi Univ.) º ITAYA, Tomoyuki; FUKUSHIMA, Masato; MIYAZAKI, Koishiro; KAWAMOTO, Takuji; KAMIMURA, Akio


Chair: NAGAHORA, Noriyoshi (15:50-16:50)

* 15:40-15:50: interval for laptop PC connection.(2E8-42, 2E8-43, 2E8-44, 2E8-45, 2E8-46)

2E8-42
Reaction of alkenyl sulfoxides with phenols mediated by acid anhydrides (Dep. Chem., Sch. Sci., Kyoto Univ.) º BANNO, Rikito; NOGI, Keisuke; YORIMITSU, Hideki

2E8-43
2-(3-Pyridyl)-5-Aminothiazole and its Methylated Compounds: Synthesis and Properties (Fac. Eng., Gifu Univ.) º TSUCHIYA, Yuki; YAMAGUCHI, Kirara; MURAI, Toshiaki

2E8-44
5-Aminothiazoles having a Varieties of Substituents at the 4- and 5- positions: Synthesis and Photophysical Properties (Fac. Eng., Gifu Univ.) º NAKATSU, Yuta; YAMAGUCHI, Kirara; MURAI, Toshiaki

2E8-45
Model Study on Highly Reactive Species Derived from a Cys-Ser Dipeptide by Taking Advantage of a Large Molecular Cavity (Sch. Sci., Tokyo Tech.) º WATANABE, Nozomu; SASE, Shohei; GOTO, Kei

2E8-46*
Synthesis and Structural Characterization of a Stable Bis(methylene)sulfane (Fac. Sci. Eng., Toyo Univ.) º SUGAMATA, Koh; ISHII, Shigeru


Saturday, March 18, AM

Chair: ISHIDA, Shintaro (09:00-10:00)

* 8:50-9:00: interval for laptop PC connection.(3E8-01, 3E8-02, 3E8-03, 3E8-04, 3E8-05, 3E8-06)

3E8-01
Synthesis of Diboryl-substituted Tetraselanylbenzene and Theoretical Investigation on its Electronic State (Grad. Sch. Sci., Eng., Saitama Univ.) FUJITA, Masahiro; FURUKAWA, Shunsuke; º SAITO, Masaichi

3E8-02
Synthesis, Structure and Fluorescence Behavior of Various Selenoesters with Imidazo[1,5-a]pyridine Skeleton (Coll. Eng., Chubu Univ.) º SAWAYANAGI, Dai; NIYOMURA, Osamu

3E8-03
Reactions of Nitrogen Ylides Substituted with a Selenocarbonyl Group with Heteroatom Nucleophiles or Alkynes (Grad. Sch. Nat. Sci. Technol., Kanazawa Univ.) º MATUNO, Misato; FURUYAMA, Taniyuki; MAEDA, Hajime; SEGI, Masahito

3E8-04
Synthesis and Oxidation of Fluorescent 1,4-Diaryl-1,3-butadiene Derivatives having Phenylseleno Groups (Grad. Sch. Sci., Eng., Saitama Univ.) º OSHIMA, Yusuke; NAKATA, Norio; ISHII, Akihiko

3E8-05
Elucidation of the Stability and Reactivity of a Selenocysteine-derived Selenenic Acid by Taking Advantage of a Large Molecular Cavity (Sch. Sci., Tokyo Tech.) º KIMURA, Ryutaro; SASE, Shohei; GOTO, Kei

3E8-06
Building a seleno-sugar skeleton from water-soluble 5-membered cyclic selenide DHS (Sch. Sci., Tokai Univ.) º HIYOSHI, Yuta; IWAOKA, Michio


Chair: NIYOMURA, Osamu (10:10-11:10)

* 10:00-10:10: interval for laptop PC connection.(3E8-08, 3E8-10, 3E8-11, 3E8-12, 3E8-13)

3E8-08*
Novel N-alkylation by carboxylic acids with borohydride reagents (Sch. Pharm., Iwate Med. Univ.) º TAMURA, Satoru; SATO, Keigo; KAWANO, Tomikazu

3E8-10
Reactions of a Phosphoranide-Trihydroborate with Iodo-Substituted Aliphatic Hydrocarbons (Grad. Sch. Sci., The Univ. of Tokyo) º O'BRIEN, Nathan; KANO, Naokazu

3E8-11
Synthesis and Applications of Various Chiral Selenazoline Ligands (Fac. Eng., Gifu Univ.) º FUKUNAGA, Tomoki; SHIBAHARA, Fumitoshi; MURAI, Toshiaki

3E8-12
Synthetic application of α-(trimethylsilyl)vinylphosphonates. (Fac. Eng., Kindai Univ.) º HATTORI, Takuya; OKADA, Yoshiharu; NOMURA, Masato

3E8-13
Development of novel synthesis of β-Lactone promoted by N,N--4-dimethylaminopyridine N-oxide (DMAPO) (Grad. Sch. Nat. Sci. Technol., Okayama Univ.) º HONGO, Kohei; SHIMOWAKI, Keita; MANDAI, Hiroki; SUGA, Seiji


Chair: YORIMITSU, Hideki (11:20-12:20)

* 11:10-11:20: interval for laptop PC connection.(3E8-15, 3E8-17, 3E8-19, 3E8-20)

3E8-15*
Salt-free Generation of Silyl Enol Ethers from a-Halocarbonyl Derivatives by Organosilicon Reducing Agents for Synthesizing a-Functionalized Carbonyl Derivatives (Grad. Sch. Eng. Sci., Osaka Univ.) º REJ, Supriya; PRAMANIK, Suman; TSURUGI, Hayato; MASHIMA, Kazushi

3E8-17*
Development of Novel LASC-SWNT Catalysts and Their Applications Toward Asymmetric Reactions in Water. (Grad. Sch. Sci., The Univ. of Tokyo) º XU, Pengyu; KITANOSONO, Taku; KOBAYASHI, Shu

3E8-19
Oxidation of active methylene compounds in water (Grad. Sch. Sci., The Univ. of Tokyo) º KITANOSONO, Taku; KOBAYASHI, Shu

3E8-20
Palladium-catalyzed C-H functionalization at sp3 carbon of 3-methylindole in water. (Grad. Sch. Sci., The Univ. of Tokyo) º MIYO, Masumi; KITANOSONO, Taku; KOBAYASHI, Shu


Saturday, March 18, PM

Chair: SASAMORI, Takahiro (13:30-14:30)

* 13:20-13:30: interval for laptop PC connection.(3E8-28, 3E8-29, 3E8-30, 3E8-31, 3E8-32)

3E8-28
Approach to seleno-aroma π belt (Grad. Sch. Sci. Eng., Kindai Univ.) º PAN, Yang; NAKAHODO, Tsukasa; FUJIHARA, Hisashi

3E8-29
Synthesis and Property of Polytellurophene Nanotubes (Grad. Sch. Sci. Eng., Kindai Univ.) º AKAMATSU, Fumiya; NAKAHODO, Tsukasa; FUJIHARA, Hisashi

3E8-30
Synthesis and Reaction of Hexaaryltellurium using tetraphenyltellurium dication (Coll. Sci., Rikkyo Univ.) º KOBAYASHI, Sho; MINOURA, Mao

3E8-31
Studies on the stability and reactivity of tellurols (Grad. Sch. Eng., Kyoto Univ.) º SEKI, Toyomitsu; LU, Yangtian; YU, Mengmeng; NAKAMURA, Yasuyuki; YAMAGO, Shigeru

3E8-32*
One pot synthesis of dendritic hyperbranched polymers by using vinyl tellurides (ICR, Kyoto Univ.) º LU, Yangtian; YAMAGO, Shigeru


Chair: HATAKEYAMA, Takuji (14:40-15:40)

* 14:30-14:40: interval for laptop PC connection.(3E8-35, 3E8-37, 3E8-39)

3E8-35*
Cyclotrimerization of Arylacetylenes Using a Germanium Catalyst and the Reaction Mechanism (ICR, Kyoto Univ.; FIFC, Kyoto Univ.) º SUGAHARA, Tomohiro; SASAMORI, Takahiro; GUO, Jing-dong; NAGASE, Shigeru; TOKITOH, Norihiro

3E8-37*
Structure and Property of a Bis(ferrocenyl)germylene (ICR, Kyoto Univ.; FIFC, Kyoto Univ.) º SUZUKI, Yuko; SASAMORI, Takahiro; GUO, Jing-dong; NAGASE, Shigeru; TOKITOH, Norihiro

3E8-39*
Synthesis and Behaviors of a Novel Low Coordinate Boron Compound and Diboranes with Bulky Amino Groups (Grad. Sch. Sci., Hiroshima Univ.; Grad. Sch. Eng. Sci., Osaka Univ.) º MORISAKO, Shogo; SHANG, Rong; YAMAMOTO, Yohsuke; MATSUI, Hiroshi; NAKANO, Masayoshi


Chair: YAMASHITA, Makoto (15:50-16:50)

* 15:40-15:50: interval for laptop PC connection.(3E8-42, 3E8-44, 3E8-46, 3E8-47)

3E8-42*
Synthesis and Reaction of Ferrocenylstannylenes (ICR, Kyoto Univ.) º MAJHI, Paresh; SASAMORI, Takahiro; TOKITOH, Norihiro

3E8-44*
Synthesis and Reaction of Reactive Silicon Species Bearing Triptycylmethyl Framework (Coll. Sci., Rikkyo Univ.) º YUKIMOTO, Mariko; MINOURA, Mao

3E8-46
Synthesis and Reaction of Silane Derivatives Bearing 9-Triptycylmethyl Group and Bulky Aryl Group. (Coll. Sci., Rikkyo Univ.) º SHINOZAWA, Miho; YUKIMOTO, Mariko; MINOURA, Mao

3E8-47
Synthesis and Physical Properties of Triangulenes Containing Group 14 Elements at the Center (Sch. Sci. Tech., Kwansei Gakuin Univ.) º GOTO, Hajime; KINOSHITA, Keisuke; NAKATSUKA, Soichiro; HATAKEYAMA, Takuji

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