The 95th Annual Meeting of The Chemical Society of Japan

Date: March 26th - 29th, 2015

Venue: Funabashi Campus, College of Science and Technology, Nihon University / School of Pharmacy, Nihon University, Chiba, Japan

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Room E3

Bldg.10 1033


[Organic Chemistry -Reaction and Synthesis- Aliphatic and Alicyclic Compounds]


Thursday, March 26, AM

Chair: URAGUCHI, Daisuke (09:00-10:00)

* 8:50-9:00: interval for laptop PC connection.(1E3-01, 1E3-02, 1E3-03, 1E3-04, 1E3-05, 1E3-06)

1E3-01
Development of Chirarl Calcium-Catalyzed Asymmetric 1,4-Addition Reactions of Imides (Grad. Sch. Sci., The Univ. of Tokyo) º AOKI, Masanori; TSUBOGO, Tetsu; KOBAYASHI, Shu

1E3-02
Synthesis of chiral 3-methyl glutamic acid derivatives catalyzed by calcium catalyst (Grad. Sch. Sci., The Univ. of Tokyo) TSUBOGO, Tetsu; º LI, Minghao; HUTKA, Martin; KOBAYASHI, Shu

1E3-03
Tail-to-Tail Cross-Dimerization of Various Michael Acceptors Catalyzed by N-Heterocyclic Carbene (Grad Sch. Eng., Nagoya Inst. of Tech.) º FUKUMOTO, Yuki; MATSUOKA, Shinichi; SUZUKI, Masato

1E3-04
Hydrogenation using water as a proton source mediated by N-heterocyclic carbene (Grad Sch. Eng., Nagoya Inst. of Tech.) º KATO, Terumasa; MATSUOKA, Shin-ichi; SUZUKI, Masato

1E3-05
Synthesis of 2-Aminopyridinium Salts from 2-Iminopyridines as Starting Materials (Grad. Sch. Eng., Mie Univ.) º FUKUTOMI, Makoto; HACHIYA, Iwao; SHIMIZU, Makoto

1E3-06
Tandem N-Alkylation Michael Addition of α-Imino Thioester (Grad. Sch. Eng., Mie Univ.) º YUN, Tesong; MIZOTA, Isao; SHIMIZU, Makoto


Chair: HACHIYA, Iwao (10:10-11:10)

* 10:00-10:10: interval for laptop PC connection.(1E3-08, 1E3-09, 1E3-10, 1E3-11, 1E3-12)

1E3-08
Development of Asymmetric Mannich-Type Reaction with N-Boc-Protected Aminals under Phase Transfer Conditions (Grad. Sch. Sci., Kyoto Univ.) º KOBAYASHI, Ryohei; KANO, Taichi; MARUOKA, Keiji

1E3-09
Regio- and Stereoselective Conjugate Addition of Aldehydes to β-Tosyl Enones Catalyzed by Binaphthyl-Modified Chiral Amine (Grad. Sch. Sci., Kyoto Univ.) º MARUYAMA, Hiroki; SUGIMOTO, Hisashi; KANO, Taichi; MARUOKA, Keiji

1E3-10
Asymmetric Intramolecular Oxy-Michael Addition of Cyanohydrins by Bifunctional Organocatalysts (Grad. Sch. Eng., Kyoto Univ.) º YONEDA, Naoki; ASANO, Keisuke; MATSUBARA, Seijiro

1E3-11
Asymmetric Intramolecular Oxy-Michael Addition of 1,3-Diols by Bifunctional Organocatalysts (Grad. Sch. Eng., Kyoto Univ.) º FUJII, Yuki; YONEDA, Naoki; ASANO, Keisuke; MATSUBARA, Seijiro

1E3-12*
Enantioselective Synthesis of Axially Chiral Compounds by Bifunctional Organocatalysts (Grad. Sch. Eng., Kyoto Univ.) º MIYAJI, Ryota; ASANO, Keisuke; MATSUBARA, Seijiro


Chair: KANO, Taichi (11:20-12:20)

* 11:10-11:20: interval for laptop PC connection.(1E3-15, 1E3-17, 1E3-18, 1E3-19, 1E3-20)

1E3-15*
Development of Catalytic Asymmetric 1,4-Addition Reactions Using Simple Amides (Grad. Sch. Sci., The Univ. of Tokyo) º SUZUKI, Hirotsugu; YAMASHITA, Yasuhiro; KOBAYASHI, Shu

1E3-17
Development of Catalytic Asymmetric 1,4-Addition Reactions Using Simple Esters (Grad. Sch. Sci., The Univ. of Tokyo) º SATO, Io; SUZUKI, Hirotsugu; YAMASHITA, Yasuhiro; KOBAYASHI, Shu

1E3-18
Stereoselective Cross Pinacol-Type Coupling under Chiral Iminophosphorane Catalysis (WPI-ITbM, Nagoya Univ.; Grad. Sch. Eng., Nagoya Univ.; CREST, JST; University of North Carolina at Chapel Hill) º TANAKA, Naoya; HORWITZ, Matthew; URAGUCHI, Daisuke; OOI, Takashi; JOHNSON, Jeffery

1E3-19
E/Z-Selective Asymmetric Conjugate Addition to Electron-Deficient Internal Alkynes (WPI-ITbM, Nagoya Univ.; Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º YAMADA, Kouhei; URAGUCHI, Daisuke; OOI, Takashi

1E3-20
Molecular Design and Application of a New Brønsted Acid Possessing Hexacoordinating Chiral Phosphate (WPI-ITbM, Nagoya Univ.; Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º ITO, Takaki; URAGUCHI, Daisuke; OOI, Takashi


Thursday, March 26, PM

Chair: MORIYAMA, Katsuhiko (13:30-14:30)

* 13:20-13:30: interval for laptop PC connection.(1E3-28, 1E3-29, 1E3-30, 1E3-31, 1E3-32)

1E3-28
Studies toward Regioselective Aerobic Oxygenation of C(sp3)-H Bonds Using an N-Oxyl Radical Catalystt with a Recognition Group (Grad. Sch. Pharm., The Univ. of Tokyo) º TASHIRO, Masayuki; OISAKI, Kounosuke; KANAI, Motmu

1E3-29
Immobilization of flavin organocatalysts onto amino functionalized resins (The Univ. of Tokushima) º YAMANOMOTO, Ken; ARAKAWA, Yukihiro; MINAGAWA, Keiji; IMADA, Yasushi

1E3-30
Stereoinversion reaction of a hydroxy group in carbocyclic alcohols via formyloxylation (RIKEN CLST) º OCHIAI, Hidenori; NIWA, Takashi; HOSOYA, Takamitsu

1E3-31
Tandem N-Alkylation/Ring Opening Reaction Using Umpolung Reaction of α-Imino Thioester Having a Cyclopropyl Group (Grad. Sch. Eng., Mie Univ.) º MORIMOTO, Takayoshi; MIZOTA, Isao; SHIMIZU, Makoto

1E3-32*
Straightforward Metal Free Synthesis of α-Hydroxy-β-dicarbonyl Compounds (Sch. Env. Sci. Eng., KUT) º ASAHARA, Haruyasu; NISHIWAKI, Nagatoshi


Chair: ASANO, Keisuke (14:40-15:40)

* 14:30-14:40: interval for laptop PC connection.(1E3-35, 1E3-36, 1E3-37, 1E3-38, 1E3-39, 1E3-40)

1E3-35
Divergent Synthesis of α-Substituted Bromolactones by Bromolactonization via Umpolung of Alkali Metal Salt (Grad. Sch. Sci., Chiba Univ.) º NISHINOHARA, Chihiro; SUGIUE, Toru; MORIYAMA, Katsuhiko; TOGO, Hideo

1E3-36
Oxidative Strecker Reaction of N-Electron-withdrawing-group-protected Amines Using Nitroxyl Radical-Alkali Metal Salt System (Grad. Sch. Sci., Chiba Univ.) º KURAMOCHI, Masako; MORIYAMA, Katsuhiko; TOGO, Hideo

1E3-37
NaBr-catalyzed benzylic oxidation of aryl alkanes using hydrogen peroxide as oxidant. (Fac. Sci., Kochi Univ.) º MAEJIMA, Yukako; NAGANO, Takashi

1E3-38
GlycolCleavage Using Sodium Hypochlorite Pentahydrate (Fac. Sci. Tech., SIST) º MATSUSHIMA, Ryoji; YAMAZAKI, Kento; YONEYAMA, Shin; ICHINOSE, Kazuya; KIRIHARA, Masayuki

1E3-39
Synthesis of Sulfones Using the Oxidation of Sulfides with Sodium Hypochlorite Pentahydrate (Fac. Sci. Tech., SIST; Nippon Light Metal Company, Ltd. R&D Department of Chemicals) º KINOSHITA, Yukari; KITAGAWA, Saori; AKIYAMA, Tomomi; YAMAZAKI, Kento; OKADA, Tomohide; KIRIHARA, Masayuki

1E3-40
Synthesis of Sulfonyl Bromide Using Sodium Hypochlorite Pentahydrate and Sodium Bromide (Fac. Sci. Tech., SIST; Nippon Light Metal Company, Ltd. R&D Department of Chemicals) KINOSHITA, Yukari; OKADA, Tomohide; º KIRIHARA, Masayuki


Chair: ASAHARA, Haruyasu (15:50-16:40)

* 15:40-15:50: interval for laptop PC connection.(1E3-42, 1E3-43, 1E3-44, 1E3-45, 1E3-46)

1E3-42
IBS-Catalyzed ortho-Selective Oxidation of Phenols to 1,2-Quinols (Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º MUTSUGA, Tatsuya; UYANIK, Muhammet; ISHIHARA, Kazuaki

1E3-43
Oxidative Enantiomeric Discrimination of Biphenols Induced by Chiral Hypervalent Iodine(III) Catalysts (Sch. Eng., Nagoya Univ.; CREST, JST) º SAEDA, Kirara; UYANIK, Muhammet; ISHIHARA, Kazuaki

1E3-44
Synthesis of Oxaziridines Using the Oxidation of Imines with Sodium Hypochlorite (Fac. Sci. Tech., SIST; ISIR, Osaka Univ.) º KITAGAWA, Saori; TAKIZAWA, Shinobu; KIRIHARA, Masayuki

1E3-45
α-Oxidative C-N Coupling Reaction of Carbonyl Compounds Using Hypoiodite Catalysis (Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º TSUKAHARA, Mayuko; UYANIK, Muhammet; ISHIHARA, Kazuaki

1E3-46
Oxidative α-Chlorination of Carbonyl Compounds Using Hypoiodite Catalysis (Sch. Eng., Nagoya Univ.; CREST, JST) º SAHARA, Naoto; UYANIK, Muhammet; ISHIHARA, Kazuaki


Chair: NAGANO, Takashi (16:50-17:50)

* 16:40-16:50: interval for laptop PC connection.(1E3-48, 1E3-50, 1E3-51, 1E3-53)

1E3-48*
Nef Reaction with Molecular Oxygen in the Absence of Metal Additives, and Mechanistic Insights (Grad. Sch. Sci., Tohoku Univ.) º UMEMIYA, Shigenobu; NISHINO, Kentaro; SATO, Itaru; HAYASHI, Yujiro

1E3-50
Oxidative Halogenation by Using Hydrogen Peroxide (Grad. Sch. Eng., Osaka Univ.; ACT-C, JST) MORIUCHI, Toshiyuki; º FUKUI, Yasuhiro; HIRAO, Toshikazu

1E3-51*
Chiral Iodine(I or III)-Catalyzed Oxidative Dearomatization of Phenols (Grad. Sch. Eng., Nagoya Univ.) º SASAKURA, Niiha; UYANIK, Muhammet; ISHIHARA, Kazuaki

1E3-53
Chiral Hypervalent Iodine(III)-Catalyzed Enantioselective Spirolactonization of (4-Hydroxyphenyl)carboxylic Acid Derivatives (Grad. Sch. Eng., Nagoya Univ.) º MIZUNO, Masahiro; UYANIK, Muhammet; ISHIHARA, Kazuaki


Chair: MORIUCHI, Toshiyuki (18:00-18:30)

* 17:50-18:00: interval for laptop PC connection.(1E3-55, 1E3-56, 1E3-57)

1E3-55
Synthesis of Enantioenriched Spirocyclic Ketones via Iron-Catalyzed Aerobic Intramolecular Dearomatization of Unsymmetrical Methylenebisarenols (I2CNER, Kyushu Univ.) º KIM, Chungsik; OGUMA, Takuya; FUJITOMO, Chisaki; UCHIDA, Tatsuya; TSUTOMU, Katsuki

1E3-56
Hypoiodite-Catalyzed Oxidative Hetero-Diels-Alder Reaction of Phenols (Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º NISHIOKA, Kohei; UYANIK, Muhammet; ISHIHARA, Kazuaki

1E3-57
Hypoiodite-Catalyzed Oxidative Dearomatization of Indole Derivatives (Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º UKEGAWA, Naoya; UYANIK, Muhammet; ISHIHARA, Kazuaki


Friday, March 27, AM

Chair: NAKAMURA, Shuichi (09:00-10:00)

* 8:50-9:00: interval for laptop PC connection.(2E3-01, 2E3-02, 2E3-03, 2E3-04, 2E3-05, 2E3-06)

2E3-01
Enantioselective Addition-Cyclization Cascade Reaction of Aldimines with Styrenes Catalyzed by Chiral Magnesium Binaphthyldisulfonates (Nagoya Univ. VBL; Grad. Sch. Eng., Nagoya Univ.; CREST) º NISHIKAWA, Keisuke; HATANO, Manabu; ISHIHARA, Kazuaki

2E3-02
Regio- and Enantioselective Aza-Friedel-Crafts Reaction of Imino Esters with Phenols Catalyzed by Chiral Binaphthyl-2,2’-Bis(monophosphate)s (Grad. Sch. Eng., Nagoya Univ.) º OKAMOTO, Haruka; HATANO, Manabu; ISHIHARA, Kazuaki

2E3-03
Enantioselective Addition of 2-Alkoxycarbonyl-1,3-dithiane to Imines Catalyzed by Bis(guanidino)iminophosphorane Organosuperbase Catalyst (Grad. Sch. Sci., Tohoku Univ.) º OISHI, Masafumi; TAKEDA, Tadahiro; KONDOH, Azusa; TERADA, Masahiro

2E3-04
Construction of Vicinal Quaternary Chiral Centers by Asymmetric Mannich Type Reaction Using Optically Active Bis(guanidino)iminophosphorane Organosuperbase Catalyst (Grad. Sch. Sci., Tohoku Univ.; Daiichi Sankyo Co., LTD. Process Technology Research Laboratories) º TAKEDA, Tadahiro; TERADA, Masahiro

2E3-05
Thiourea-catalyzed Generation of Trityl Cation Species: Application to Carbonyl-Ene Cyclization Reaction (Fac. Sci., Kochi Univ.) º NISHIYAMA, Nobuo; KOTSUKI, Hiyoshizo

2E3-06
Development of Enantioselective Organocatalyzed Formal [n+2] Cycloaddition of Allenic Ester with Olefins (ISIR, Osaka Univ.) º YOSHIDA, Yasushi; TAKIZAWA, Shinobu; ARTEAGA, Fernando Arteaga; KISHI, Kenta; SASAI, Hiroaki


Chair: TAKIZAWA, Shinobu (10:10-11:10)

* 10:00-10:10: interval for laptop PC connection.(2E3-08, 2E3-09, 2E3-10, 2E3-11, 2E3-12)

2E3-08
Asymmetric Mannich-type Reaction with Cyclic Ketimines Using N-Heteroarenesulfonyl Cinchona Alkaloid Amide Catalyst (Nagoya Inst. of Tech.) º TODA, Ayaka; SANO, Masahide; NAKAMURA, Shuichi

2E3-09
Synthesis of novel biisoquinolinium salt derivatives with axial chirality and their catalytic activity (Toyohashi Univ. of Tech.) º TESHIBA, Chiaki; HARAGUCHI, Naoki; ITSUNO, Shinichi

2E3-10
Enantioselective synthesis of fuzed piperidine derivatives with chiral quaternary carbon center by reductive amination with breaking symmetry. (Fac. Sci., Gakushuin Univ.) º MIYAKE, Ayaka; MORI, Keiji; AKIYAMA, Takahiko

2E3-11
Development of Novel Helically Chiral Phosphazene Organosuperbase Catalysts (Grad. Sch. Sci., Tohoku Univ.) º GOTO, Kengo; KONDOH, Azusa; TERADA, Masahiro

2E3-12*
Development of Efficient Peptide Catalysts by a Facile Library Screening Method (IIS, The Univ. of Tokyo) º AKAGAWA, Kengo; KUDO, Kazuaki


Chair: HARAGUCHI, Naoki (11:20-12:20)

* 11:10-11:20: interval for laptop PC connection.(2E3-15, 2E3-17, 2E3-18, 2E3-19, 2E3-20)

2E3-15*
Phosphite-Urea Cooperative Catalysis for Enantioselective Bromocyclization of 2-Geranylphenols (Grad. Sch. Eng., Nagoya Univ.; Grad. Sch. Nat. Sci. Technol., Okayama Univ.; CREST, JST) º SAWAMURA, Yasuhiro; SAKAKURA, Akira; ISHIHARA, Kazuaki

2E3-17
Enantioselective Cyanoethoxycarbonylation of .alpha.-Ketoesters Using Oxyanion Hole Catalyst toward Oxazolidinone Synthesis (Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º OGURA, Yoshihiro; ISHIHARA, Kazuaki

2E3-18
Chiral Phosphoric Acid Catalyzed Asymmetric Transfer Hydrogenation of Dyhydrobenzodiazepine Derivatives (Fac. Sci., Gakushuin Univ.) º HORIGUCHI, Kosaku; YAMAMOTO, Eri; SAITO, Kodai; YAMANAKA, Masahiro; AKIYAMA, Takahiko

2E3-19
Theoretical Study on the Mechanism of Stereoselectivity in Chiral Phosphoric Acid Catalyzed Asymmetric Hydrogenation of 1, 5-benzodiazepine Using benzothiazoline (Coll. Sci., Rikkyo Univ.) º YAMAMOTO, Eri; HORIGUCHI, Kousaku; SAITO, Kodai; AKIYAMA, Takahiko; YAMANAKA, Masahiro

2E3-20
Theoretical Study on Chiral Phosphoric Acid Catalyzed Asymmetric Transfer Hydrogenation of Trifluoromethylated N-H Ketimine Using Benzothiazoline (Grad. Sch. Sci., Rikkyo Univ.) º NODA, Hirofumi; YAMANAKA, Masahiro; AKIYAMA, Takahiko


Friday, March 27, PM

Chair: MORIYAMA, Katsuhiko (13:30-14:30)

* 13:20-13:30: interval for laptop PC connection.(2E3-28, 2E3-29, 2E3-30, 2E3-31, 2E3-32)

2E3-28
Development of novel preparation method of cationic flavins (The Univ. of Tokushima) º OONISHI, Takahiro; KOHDA, Takahiro; ARAKAWA, Yukihiro; MINAGAWA, Keiji; IMADA, Yasushi

2E3-29
Oxidation catalysis of cationic flavins immobilized on cation-exchange resins (The Univ. of Tokushima) º KOHDA, Takahiro; OONISHI, Takahiro; ARAKAWA, Yukihiro; MINAGAWA, Keiji; IMADA, Yasushi

2E3-30
Strategy for Vinylogous Nitronate Generation: Application to Highly Stereoselective Aza-Henry Reaction (WPI-ITbM, Nagoya Univ.; Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º OYAIZU, Keigo; URAGUCHI, Daisuke; OOI, Takashi

2E3-31
Betaine-Type Electron-Transfer Catalyst: Design and Application (WPI-ITbM, Nagoya Univ.; Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º TORII, Masahiro; URAGUCHI, Daisuke; OOI, Takashi

2E3-32*
Catalytic Asymmetric Carbon-Hetero Atom Bond-Forming Reactions at α-Position of Carbonyl Compounds (WPI-ITbM, Nagoya Univ.; Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º ANDO, Yuichiro; OHMATSU, Kohsuke; OOI, Takashi


Chair: ISHIHARA, Kazuaki (14:40-15:40)

* 14:30-14:40: interval for laptop PC connection.(2E3-35, 2E3-38, 2E3-39, 2E3-40)

2E3-35 Young Scholar Lectures of CSJ
Asymmetric Heterocycle Syntheses Utilizing Multipoint Activation by Organocatalysts (Grad. Sch. Eng., Kyoto Univ.) º ASANO, Keisuke

2E3-38
Asymmetric Michael addition reaction in water using organocatalyst tethered on thermoresponsive copolymer. (Fac. Sci., Sophia Univ.) º AKEBI, Ryuji; INOUE, Takahiro; RIKUKAWA, Masahiro; MASUYAMA, Yoshiro; SUZUKI, Noriyuki

2E3-39
Chiral Pyrrolidyl Anthranilic Acid Salt Catalyzed Enantioselective Michael Addition to β-Nitrostyrenes (Grad. Sch. Sci., Chiba Univ.) º SUGIUE, Toru; MORIYAMA, Katsuhiko; TOGO, Hideo

2E3-40
Asymmetric Organocatalytic Michael Addition Reaction of α-Aryl-substituted Lactams: Asymmetric Total Synthesis of (+)-Mesembrine (Fac. Sci., Kochi Univ.) MINAMISAWA, Masamitsu; º NUNOKAWA, Shiori; KOTSUKI, Hiyoshizo


Chair: MASE, Nobuyuki (15:50-16:50)

* 15:40-15:50: interval for laptop PC connection.(2E3-42, 2E3-43, 2E3-44, 2E3-45, 2E3-46)

2E3-42
Development of catalytic asymmetric construction of spiro rings by cinchona alkaloid derivatives (Fac. Sci. Tech., Keio Univ.) YOSHIDA, Keisuke; º ITATSU, Yukihiro; FUJINO, Yuta; TAKAO, Ken-ichi

2E3-43
Development and Application of Asymmetric Conjugate Addition Reaction of α-Formylesters Involving a Chiral Quaternary Carbon Atom Construction Catalyzed by Organocatalysts (Grad. Sch. Mat. Sci., Univ. of Hyogo) º TATSUMI, Toshifumi; MISAKI, Tomonori; SUGIMURA, Takashi

2E3-44
Asymmetric Construction of 1,3-Dioxanes via Kinetic Resolution by Chiral Phosphoric Acid Catalyst (Grad. Sch. Eng., Kyoto Univ.) º MATSUMOTO, Akira; ASANO, Keisuke; MATSUBARA, Seijiro

2E3-45
Synthesis of substituted trans-cyclooctenes toward the development of novel organic Lewis base catalysts (Grad. Sch. Eng., Kyoto Univ.) º EINARU, Shunsuke; MATSUMOTO, Akira; ASANO, Keisuke; MATSUBARA, Seijiro

2E3-46*
Facile Asymmetric Synthesis of 1,5-Benzothiazepines through Cycloaddition (Grad. Sch. Eng., Kyoto Univ.) º FUKATA, Yukihiro; ASANO, Keisuke; MATSUBARA, Seijiro


Chair: TAKAO, Ken-ichi (17:00-17:50)

* 16:50-17:00: interval for laptop PC connection.(2E3-49, 2E3-51, 2E3-52, 2E3-53)

2E3-49*
Chiral Nucleophilic Amidophosphate-Catalyzed Enantioselective Iodoetherification (Grad. Sch. Eng., Nagoya Univ.) º NAKATSUJI, Hidefumi; ISHIHARA, Kazuaki

2E3-51
Chiral Nucleophilic Phosphine(V)-Catalyzed Enantioselective Iodoaminocyclization (Sch. Eng., Nagoya Univ.) º OKUMURA, Yukimasa; NAKATSUJI, Hidefumi; ISHIHARA, Kazuaki

2E3-52
Helically Chiral Poly(quinoxaline-2,3-diyl)s Bearing Pyridyl Pendants: Synthesis and Application for Asymmetric Organocatalytic Reactions (Grad. Sch. Eng., Kyoto Univ.) º MURAKAMI, Ryo; YAMAMOTO, Takeshi; SUGINOME, Michinori

2E3-53
Development of Enantiomerically-Pure Polylactide Synthesis Through Organocatalytic Polymerization in Supercritical Carbon Dioxide (Grad. Sch. Eng., Shizuoka Univ.) º YAMAMOTO, Shoji; NARUMI, Tetsuo; WATANABE, Naoharu; MASE, Nobuyuki


Chair: SUGINOME, Michinori (18:00-18:40)

* 17:50-18:00: interval for laptop PC connection.(2E3-55, 2E3-56, 2E3-57, 2E3-58)

2E3-55
Boronic Acid-Nucleophilic Base Cooperative Catalysis for Dehydrative Condensation between Carboxylic Acids and Amines (Grad. Sch. Eng., Nagoya Univ.; CREST, JST) º LU, Yanhui; ISHIHARA, Kazuaki

2E3-56
Metal-Free Tetraalkylammonium Methylcarbonate-Catalyzed Transesterification (Grad. Sch. Eng., Nagoya Univ.) º YOSHIDA, Yurika; OGURA, Yoshihiro; KAMIYA, Sho; HATANO, Manabu; ISHIHARA, Kazuaki

2E3-57
Enantioselective Steglich Rearrangement of Oxindole derivatives: Chiral Nucleophilic Catalysts Synthesized by Ugi Multicomponent Reaction in One-pot Manner (Grad. Sch. Nat. Sci. Technol., Okayama Univ.) º FUJIWARA, Takuma; NODA, Katsuaki; MANDAI, Hiroki; KORENAGA, Toshinobu; SUGA, Seiji

2E3-58
Enantioselective Steglich Rearrangement of Oxindole Derivatives (2): Chiral Nucleophilic Catalysts having a binaphthyl skeleton (Grad. Sch. Nat. Sci. Technol., Okayama Univ.) º FUJII, Kazuki; MANDAI, Hiroki; KORENAGA, Toshinobu; SUGA, Seiji


Saturday, March 28, AM

Chair: TERADA, Masahiro (09:00-09:30)

* 8:50-9:00: interval for laptop PC connection.(3E3-01, 3E3-04, 3E3-05, 3E3-06)

3E3-01 CSJ Award for Young Chemists
C(sp3)-H Bond Functionalization Mediated by Hydride Shift/Cyclization System (Fac. Sci., Gakushuin Univ.) º MORI, Keiji


Chair: KONDOH, Azusa (09:30-10:00)

3E3-04
BBr3-Assisted Chiral Phosphoric Acid Catalysts for Enantioselective Diels-Alder Reaction of 1,2-Dihydropyridines (Grad. Sch. Eng., Nagoya Univ.; CREST) º GOTO, Yuta; HATANO, Manabu; ISHIHARA, Kazuaki

3E3-05
Boron Lewis Acids-Assisted Chiral Phosphoric Acid Catalysts for Enantioselective Diels-Alder Reaction (Grad. Sch. Eng., Nagoya Univ.; CREST) º ISHIHARA, Hideyuki; GOTO, Yuta; HATANO, Manabu; ISHIHARA, Kazuaki

3E3-06
Preparation and Evaluation of Polymer-immobilized Chiral Phosophoric Acids for Catalytic Asymmetric Intramolecular Aza-Friedel-Crafts Reaction (Grad. Sch. Sci., The Univ. of Tokyo) YOO, Woo-Jin; º CHENG, Honggang; KOBAYASHI, Shu


Chair: OISAKI, Kounosuke (10:10-11:10)

* 10:00-10:10: interval for laptop PC connection.(3E3-08, 3E3-09, 3E3-10, 3E3-11, 3E3-12, 3E3-13)

3E3-08
Enantioselective Synthesis of Chiral Biaryls by Ring Opening/Transfer Hydrogenation Sequence Involving Dynamic Kinetic Resolution (Fac. Sci., Gakushuin Univ.) º ITAKUARA, Tsubasa; MORI, Keiji; AKIYAMA, Takahiko

3E3-09
Chiral Phosphoric Acid Catalyzed Asymmetric Synthesis of Dihydroquinolones Using Aza-Michael Reaction (Fac. Sci., Gakushuin Univ.) º MORIYA, Yuka; SAITO, Kodai; AKIYAMA, Takahiko

3E3-10
Chiral Phosphoric Acid-Catalyzed Oxidative Kinetic Resolution of Tetrahydroquinolines Based on the Transfer Hydrogenation to Imines (Fac. Sci., Gakushuin Univ.) º MIYASHITA, Hiromitsu; SAITO, Kodai; AKIYAMA, Takahiko

3E3-11
Chiral Phosphoric Acid Catalyzed Enantioselective Friedel-Crafts Reaction of 2-Methoxyfuran with Aliphatic Ketimines (Grad. Sch. Sci., Tohoku Univ.) º OTA, Yusuke; KOMURO, Takazumi; KONDOH, Azusa; TERADA, Masahiro

3E3-12
Catalytic Enantioselective Mannich-type Reaction of Enamide with Azlactone Catalyzed by Optically Active Binaphthalene Diamine Derived Chiral Brønsted Acid (Grad. Sch. Sci., Tohoku Univ.; Institute for Molecular Science Life and Coordination-Complex Molecular Science) º KIKUCHI, Jun; MOMIYAMA, Norie; TERADA, Masahiro

3E3-13
Chiral Phosphoric Acid Catalyzed 1,2-Sulfur Rearrangement / Enantioselective Nucleophilic Addition of Dithioketal Derivatives (Grad. Sch. Sci., Tohoku Univ.) º LI, Feng; TERADA, Masahiro


Chair: MIZOTA, Isao (11:20-12:20)

* 11:10-11:20: interval for laptop PC connection.(3E3-15, 3E3-16, 3E3-17, 3E3-18, 3E3-19, 3E3-20)

3E3-15
A Study on the Stereocontrolling Elements of Chiral Phosphoric Acid-Catalyzed Addition Reaction of Vinylindoles with Azlactones (Grad. Sch. Sci., Tohoku Univ.) º KANOMATA, Kyohei; TERADA, Masahiro

3E3-16
1,3-Rearrangement of N-Homoallyl Aldimine by Bronsted Acid : Study on Reaction Mechanism (Grad. Sch. Sci., Tohoku Univ.) º TSUKAHARA, Yuta; MOMIYAMA, Norie; TERADA, Masahiro

3E3-17
Aryl Phosphinic Acid-Phosphoric Acid Catalyzed Hetero Diels-Alder Reaction of Aldehydes and Danishefsky's Diene (Grad. Sch. Sci., Tohoku Univ.; Institute for Molecular Science Life and Coordination-Complex Molecular Science) º NARUMI, Tomohiro; MOMIYAMA, Norie; TERADA, Masahiro

3E3-18
Catalytic Enantioselective [4+2] Cyclization Reaction of N-Benzoyl Imines with Alkenes Catalyzed by Perfluoroaryl Introduced Chiral Phosphoric Acid (Grad. Sch. Sci., Tohoku Univ.) º OKAMOTO, Hiroshi; MOMIYAMA, Norie; TERADA, Masahiro

3E3-19
Research on Catalytic Asymmetric Friedel-Crafts Reactions Utilizing α-Alkylidene β-Oxo Imides (Fac. Sci. Eng., Waseda Univ.) º OYAMA, Harufumi; ENOMOTO, Kazuaki; NAKADA, Masahisa

3E3-20
Catalytic asymmetric [2+2] cycloaddition reactions of α-alkylidene β-oxo imides (Grad. Sch. Advanced Sci. Eng., Waseda Univ.) º ENOMOTO, Kazuaki; OYAMA, Harufumi; NAKADA, Masahisa


Saturday, March 28, PM

Chair: KOMEYAMA, Kimihiro (13:30-14:30)

* 13:20-13:30: interval for laptop PC connection.(3E3-28, 3E3-30, 3E3-31, 3E3-33)

3E3-28*
Sequential N-Alkylation/Vinylogous Aldol Reaction of β,γ-Alkenyl-α-iminoester (Grad. Sch. Eng., Mie Univ.) º MIZOTA, Isao; SHIMIZU, Makoto

3E3-30
De Novo synthesis of partially fluorinated carbohydrates using Reformatsky reaction and Mukaiyama aldol reaction as key reactions. (Grad. Sch. Eng., Tottori Univ.) º TAKAYANAGI, Keisuke; HARADA, Akinori; NOKAMI, Toshiki; ITOH, Toshiyuki

3E3-31*
Development of Catalytic Asymmetric Consecutive Aldol Reaction (Grad. Sch. Pharm., The Univ. of Tokyo; ERATO-JST; ACT-C, JST) º YAMAMOTO, Kumiko; LIN, Luqing; MITSUNUMA, Harunobu; IDA, Takashi; MATSUNAGA, Shigeki; KANAI, Motomu

3E3-33
Development of Catalytic Asymmetric Cross-Aldol Reaction Using Acetaldehyde-Derived Silyl Enol Ethers (Grad. Sch. Pharm., The Univ. of Tokyo; ERATO-JST; ACT-C, JST) º IDA, Takashi; YAMAMOTO, Kumiko; MITSUNUMA, Harunobu; MATSUNAGA, Shigeki; KANAI, Motomu


Chair: MATSUMOTO, Arimasa (17:00-17:40)

* 16:50-17:00: interval for laptop PC connection.(3E3-49, 3E3-50, 3E3-51, 3E3-52)

3E3-49
Development of chemoselective Mannich-type reaction of carboxylic acids (Grad. Sch. Pharm., The Univ. of Tokyo) º YAMAMOTO, Tomohiro; MORITA, Yuya; SHIMIZU, Yohei; KANAI, Motomu

3E3-50
Synthesis of 1,2-dicyanoalkanes from nitroalkenes and silyl cyanide mediated by tetrabutylammonium fluoride (Grad. Sch. Eng., Osaka Univ.) º NAGATA, Takaya; KIYOKAWA, Kensuke; MINAKATA, Satoshi

3E3-51
NHC-Catalyzed Double Acylation of Ynones with Benzils and Aromatic Aldehydes (Grad. Sch. Eng., Hiroshima Univ.) º HINO, Makoto; OHNO, Akira; OKINAGA, Kousuke; KOMEYAMA, Kimihiro; YOSHIDA, Hiroto; TAKAKI, Ken

3E3-52
Regioselective Transacylation by the Pseudo-Intramolecular Process (Sch. Env. Sci. Eng., KUT) º SHIBAUCHI, Hiroshi; HIRAI, Sho; ASAHARA, Haruyasu; NISHIWAKI, Nagatoshi

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