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Web Release Date: April 25, 2013
456 Stimuli-responsive Synthetic Metallopeptides
Shohei Tashiro and Mitsuhiko Shionoya  
[ Full Text PDF(J-STAGE)]
Metal ions play vital roles in stabilizing and regulating higher-order structures of biomacromolecules. This review focuses on molecular design of synthetic metallopeptides whose structures and functions are stimuli-responsive. In the cases discussed here, secondary structures of the peptides are effectively induced and regulated with the characteristics of metal ions such as Lewis acidity, ligand-exchange ability, and redox property.

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