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Bulletin of the Chemical Society of Japan Vol. 85, (2012)
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| Web Release Date:
December 23, 2011
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1-32
Nanoarchitectonics for Mesoporous Materials
Katsuhiko Ariga,* Ajayan Vinu,* Yusuke Yamauchi,* Qingmin Ji, and Jonathan P. Hill
[Full Text PDF(J-STAGE)] Open Access Article
| We introduce recent developments of mesoporous materials, including syntheses of mesoporous silica, metal oxides, semiconductors, metals, alloys, organic composites, biocomposites, carbon, carbon nitride, and boron nitride as well as film fabrication, pore alignment, and hierarchic structuring for novel functions. |
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| Web Release Date:
December 30, 2011
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124-132
Pathways and Kinetics of Anisole Pyrolysis Studied by NMR and Selective 13C Labeling. Heterolytic Carbon Monoxide Generation
Yasuo Tsujino, Yoshiro Yasaka, Nobuyuki Matubayasi, and Masaru Nakahara*
[Full Text PDF(J-STAGE)] Open Access Article
Conversion of the 13C-labeled anisole (H313COC6H5) at 500 °C was confined to the methoxy-originated fragments, 13CO (conversion fraction f = ca. 1/2) and 13CH4 (f = ca. 1/2), and the reactive intermediate, H13CHO* (f = ca. 1/20), without the phenyl ring disintegration.
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