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 Vol. 86, No. 5 (May, 2013)

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Award Accounts
The Chemical Society of Japan Award for Creative Work for 2008
  Web Release Date: April 6, 2013
 547-556  DNA-Conjugated Polymers for Reliable SNP Genotyping Based on Affinity Capillary Electrophoresis
 Tohru Takarada and Mizuo Maeda*
[Full Text PDF(J-STAGE)]  Free Access Article

Affinity capillary electrophoresis for single-nucleotide polymorphism (SNP) genotyping was developed using a diblock copolymer probe composed of an allele-specific oligodeoxyribonucleotide and a synthetic polymer. The peak area ratio allowed accurate estimation of the SNP allele frequency.

BCSJ Award Article
  Web Release Date: March 23, 2013
 557-568  C–F Bond Breaking through Aromatic Nucleophilic Substitution with a Hydroxo Ligand Mediated via Water Bifunctional Activation
 Pavel A. Dub, Hui Wang, Asuka Matsunami, Ilya D. Gridnev, Shigeki Kuwata, and Takao Ikariya*
[Full Text PDF(J-STAGE)]  [Supporting Information]  Free Access Article

Transformation of C–F to C–O bond mediated by chiral bifunctional ruthenium and iridium complexes is described. This reaction proceeds through water O–H bond cleavage via metal–ligand cooperation and subsequent mediated ortho-oxometallation via SNAr in the newly developed 16e bifunctional complexes bearing chiral C6F5SO2-dpen ligand.

Selected Paper
  Web Release Date: March 23, 2013
 569-576  Identification of Hydrogen-Bonded Oligomers in Associating Liquid by 1H NMR: 1-Phenyl-1-cyclohexanol
 Shigenori Nagatomo, Megumi Nobuhira, Yasuhisa Yamamura, Masato Sumita, and Kazuya Saito*
[Full Text PDF(J-STAGE)]  [Supporting Information]

Calorimetric, FT-IR, dielectric, and 1H NMR experiments revealed the temperature dependence of the association state in the neat liquid.

Selected Paper
  Web Release Date: March 23, 2013
 577-582  Preparation of Diastereomerically Pure and Mixed (S)-PhGly/BIPHEP/Ru(II) Complexes and Their Catalytic Behavior with Li2CO3 in Asymmetric Cyanosilylation of Benzaldehyde
 Nobuhito Kurono, Taiki Katayama, and Takeshi Ohkuma*
[Full Text PDF(J-STAGE)]  [Supporting Information]

The 61:39 equilibrium mixture of [Ru{(S)-phgly}2{(S)-biphep}] and [Ru{(S)-phgly}2{(R)-biphep}] with Li2CO3 catalyzes cyanosilylation of benzaldehyde to afford the R product in 92% ee. The enantioselectivity is just slightly lower than that by using the diastereomerically pure (S)-PhGly/(S)-BIPHEP/Ru(II) catalyst of 96%.

Selected Paper
  Web Release Date: May 15, 2013
 583-585  Formation of Au Nanostructure by Electrodeposition in a Mesoporous Silica Film with Interconnected Cage-Type Mesopores
 Yosuke Kanno and Kazuyuki Kuroda*
[Full Text PDF(J-STAGE)]  [Supporting Information]

A mesoporous silica film with interconnected cage-type mesopores is found to work as a scaffold to construct a novel nanostructured Au by electrodeposition. The nanostructure consists of Au nanoparticles located in the mesopores and they are connected to each other, which induces a red shift in the visible absorption band.

  Web Release Date: May 15, 2013
 586-593  Negative Charge and Solvent Effects on Electronic Excited-State Hydrogen Bonding of 2′-Deoxycytidine 5′-Monophosphate (dCMP) in Aqueous Solution
 Xiaoyu Zhang and Weiping Zhang*
[Full Text PDF(J-STAGE)]

The influences of negative charge and solvent effects on the excited-state hydrogen-bonding dynamics of 2′-deoxycytidine 5′-monophosphate (dCMP) are investigated.

  Web Release Date: May 15, 2013
 594-599  Theoretical Model for the Carboxylic Group Acidity Constant Based on Connectivity Index 3χv
 Ante Miličević* and Nenad Raos
[Full Text PDF(J-STAGE)]

The regression model for prediction of COOH acidity constant on 19 amino and 16 aliphatic monocarboxylic acids was developed. As variables we employed two subsummations of 3χv index terms, 3χv(chain) and 3χv(side).

  Web Release Date: March 23, 2013
 600-607  Reaction of Binuclear Ruthenium–Fulvalene Intermediates Intramolecularly Bridged by Alkyl Disulfides
 Hiroki Yasuhara, Kazuki Koga, and Satoru Nakashima*
[Full Text PDF(J-STAGE)]  [Supporting Information]

The mechanism of the bis(thiolato)-bridging reaction by alkyl disulfide was investigated by using ruthenium–fulvalene complexes. Intermediates were isolated, and characterized in order to estimate detailed mechanism of this reaction. It was found that the reaction was stepwise and the rate-determining step was where RCN ligands were eliminated.

  Web Release Date: March 23, 2013
 608-614  Syntheses, Crystal Structures, and Photophysical Properties of Platinum(II) Complexes Containing a Disulfanenitrile Ligand
 Hiroya Honda, Takayoshi Fujii,* Junpei Kuwabara, and Takaki Kanbara
[Full Text PDF(J-STAGE)]  [Supporting Information]

The reaction of the bidendate Ph2S(=N(Ph2)S≡N)2 (ndsdsd) ligand with corresponding precursors gave the homoleptic complex [Pt(ndsdsd)2](hfac)2 (1) and heteroleptic complexes 2–5. X-ray crystallographic analyses indicate that the bond order in the N≡S–N=S=N–S≡N backbone of ndsdsd has been maintained.

  Web Release Date: March 23, 2013
 615-619  Novel Formation of Oxazepino[4,5-a]quinolines by Tandem 1,3-Dipolar and Insertion Reaction of Quinoline N-Oxides with Arynes
 Kentaro Okuma,* Koki Hirano, Chisato Shioga, Noriyoshi Nagahora, and Kosei Shioji
[Full Text PDF(J-STAGE)]

By combination of 1,3-dipolar cycloaddition and N–O single bond insertion, tandem synthesis of dibenzo[1,4]oxazepino[4,5-a]quinolines was accomplished. Reaction of quinoline N-oxides with arynes afforded 2-(2-hydroxyphenyl)quinolines and 7-membered pentacyclic oxazepino[4,5-a]quinolines.

  Web Release Date: March 27, 2013
 620-627  Activation of Dioxygen in an Aqueous System of [FeIIITMPyP]–MBTH–O2 to Form Peroxide and Azine from MBTH: Reactivity of Superoxohemin ([FeIIITMPyP–OO]•) and Peroxohemin ([FeIIITMPyP–OO]−)
 Taku Nakano,* Hiroko Kakuda, Hiroyuki Shinoda, and Hiroshi Moriyama*
[Full Text PDF(J-STAGE)]  [Supporting Information]  Open Access Article



Activation of dioxygen in aqueous heme system, tetrakis(N-methylpyridyl)porphinatoiron(III) pentachloride ([FeIIITMPyP]Cl5) and 3-methyl-2-benzothiazolinonehydrazone (MBTH) is described to produce a bridging peroxide MBTPO, an azine MBTA, and a ketone MBTZ. Intermediates are suggested to be superoxohemin [FeIII–OO]• and peroxohemin [FeIII–OO]−.

  Web Release Date: March 23, 2013
 628-634  p-Aminosalicylic Acid Production by Enzymatic Kolbe–Schmitt Reaction Using Salicylic Acid Decarboxylases Improved through Site-Directed Mutagenesis
 Saori Ienaga, Sachiyo Kosaka, Yuki Honda, Yoshitaka Ishii, and Kohtaro Kirimura*
[Full Text PDF(J-STAGE)]  [Supporting Information]

By using salicylic acid decarboxylase mutant, Y64T-F195Y-Sdc, improved through site-directed mutagenesis, 140 mM p-aminosalicylic acid was produced from 200 mM m-aminophenol within 9 h, by the enzymatic Kolbe–Schmitt reaction in aqueous solution.

  Web Release Date: March 23, 2013
 635-641  Specificity of Lucigenin Solubility, and Solvent and Base Effects on Lucigenin Chemiluminescence
 Chiaki Tahara,* Yasushi Toyose, Hiroaki I. Ogawa, Toshio Yamaguchi, and Tetsutaro Yoshinaga
[Full Text PDF(J-STAGE)]

Chemiluminescent (CL) intensities of lucigenin in various solvents were found in the order of (1) > (2) > (3) > (4) > (5). At the specific ratio of alchohol–H2O mixed solvent (3) or (4), lucigenin gave the maximum solubility. It was found that the CL intensity order was dependent on polarity (ε) irrespective of the cluster structure of solvent.

  Web Release Date: March 27, 2013
 642-650  Size- and Shape-Controlled Syntheses of Colloidal Sn, Te, and Bi Nanocrystals
 Ryota Watanabe and Toshitaka Ishizaki*
[Full Text PDF(J-STAGE)]  [Supporting Information]

We report the synthesis of monodisperse spherical Sn nanocrystals 9.0 nm in size in a one-pot synthesis. The size and shape of the Sn nanocrystals were controllable. This method was also applied to the synthesis of Te and Bi nanocrystals.

  Web Release Date: March 23, 2013
 651-656  Structural Transition of Lipopolysaccharide and Reduction in the Biological Activity by Amphiphilic Lipid with Cationic Amino Acid
 Wenjing Li, Shinichi Mochizuki, and Kazuo Sakurai*
[Full Text PDF(J-STAGE)]  [Supporting Information]

Structural transition of lipopolysaccharide and reduction in the biological activity by amphiphilic lipid with cationic amino acid.

  Web Release Date: May 15, 2013
 657-662  Adsorptions of Iso- and Terephthalaldehydes on 3-Aminopropyl-Functionalized SBA-15 with Various Loadings
 Teruaki Koizumi and Hideaki Yoshitake*
[Full Text PDF(J-STAGE)]  [Supporting Information]

Isophthalaldehyde and terephthalaldehyde are adsorbed on 3-aminopropyl-functionalized SBA-15 (loadings: 1.1–1.8 mmol g−1). The Langmuir constant for isophthalaldehyde increases with loading (by a factor of 8.6), while the increase is negligible for that of terephthalaldehyde (by a factor of 1.6.).

  Web Release Date: March 23, 2013
 663-670  Synthesis and Properties of Partially Fluorinated Poly(arylene ether) Block Copolymers Containing Ammonium Groups as Anion Conductive Membranes
 Hideaki Ono, Junpei Miyake, Byungchan Bae, Masahiro Watanabe, and Kenji Miyatake*
[Full Text PDF(J-STAGE)]  [Supporting Information]

Aromatic block copolymers (QPE-bl-4) containing fluorinated phenylene and biphenylene groups and ammonium-substituted fluorene groups are reported. The QPE-bl-4 membrane with the highest ion-exchange capacity (IEC = 1.3 mequiv g−1) showed high hydroxide ion conductivity (45 mS cm−1) at 80 °C due to its phase-separated morphology with interconnected ion transporting pathway.

  Web Release Date: March 23, 2013
 671-673  Alkylhydrazide Derivatives as New Organogelators and Their Potential Ability to Gel Electrolytes
 Yutaka Ohsedo,* Misao Miyamoto, Hisayuki Watanabe, Masashi Oono, and Akihiro Tanaka
[Full Text PDF(J-STAGE)]  [Supporting Information]

We found that alkylhydrazides, which are commercially available reagents, formed organogels in various organic solvents having dielectric constants ranging from 2 to 66.

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[2003] [2002] [2001]
[2000] [1999] [1998]
[1997] [1996] [1995]

Vol. 86 (2013)
 No. 5   p. 547 -
 No. 4   p. 397 -
 No. 3   p. 299 -
 No. 2   p. 167 -
 No. 1   p. 1 -

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Vol. 85 (2012)
 No. 12 p. 1245 -
 No. 11 p. 1175 -
 No. 10 p. 1061 -
 No. 9   p. 931 -
 No. 8   p. 843 -
 No. 7   p. 731 -
 No. 6   p. 647 -
 No. 5   p. 533 -
 No. 4   p. 401 -
 No. 3   p. 249 -
 No. 2   p. 151 -
 No. 1   p. 1 -

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Vol. 84 (2011)
 No. 12 p. 1295 -
 No. 11 p. 1151 -
 No. 10 p. 983 -
 No. 9   p. 879 -
 No. 8   p. 819 -
 No. 7   p. 679 -
 No. 6   p. 569 -
 No. 5   p. 441 -
 No. 4   p. 353 -
 No. 3   p. 233 -
 No. 2   p. 133 -
 No. 1   p. 1 -

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Vol. 83 (2010)
 No. 12 p. 1401 -
 No. 11 p. 1285 -
 No. 10 p. 1133 -
 No. 9   p. 969 -
 No. 8   p. 855 -
 No. 7   p. 735 -
 No. 6   p. 595 -
 No. 5   p. 431 -
 No. 4   p. 299 -
 No. 3   p. 199 -
 No. 2   p. 101 -
 No. 1   p. 1 -

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Vol. 82 (2009)
 No. 12 p. 1447 -
 No. 11 p. 1323 -
 No. 10 p. 1215 -
 No. 9   p. 1055 -
 No. 8   p. 917 -
 No. 7   p. 751 -
 No. 6   p. 631 -
 No. 5   p. 539 -
 No. 4   p. 419 -
 No. 3   p. 285 -
 No. 2   p. 127 -
 No. 1   p. 1 -

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Vol. 81 (2008)
 No. 12 p. 1535 -
 No. 11 p. 1337 -
 No. 10 p. 1183 -
 No. 9   p. 1039 -
 No. 8   p. 917 -
 No. 7   p. 785 -
 No. 6   p. 659 -
 No. 5   p. 539 -
 No. 4   p. 411 -
 No. 3   p. 307 -
 No. 2   p. 171 -
 No. 1   p. 1 -

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Vol. 80 (2007)
 No. 12 p. 2247 -
 No. 11 p. 2047 -
 No. 10 p. 1843 -
 No. 9   p. 1635 -
 No. 8   p. 1437 -
 No. 7   p. 1229 -
 No. 6   p. 1021 -
 No. 5   p. 797 -
 No. 4   p. 595 -
 No. 3   p. 433 -
 No. 2   p. 233 -
 No. 1   p. 1 -

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Vol. 79 (2006)
 No. 12 p. 1799 -
 No. 11 p. 1621 -
 No. 10 p. 1463 -
 No. 9   p. 1315 -
 No. 8   p. 1155 -
 No. 7   p. 965 -
 No. 6   p. 811 -
 No. 5   p. 663 -
 No. 4   p. 501 -
 No. 3   p. 361 -
 No. 2   p. 177 -
 No. 1   p. 1 -

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Vol. 78 (2005)
 No. 12 p. 2083 -
 No. 11 p. 1887 -
 No. 10 p. 1705 -
 No. 9   p. 1581 -
 No. 8   p. 1373 -
 No. 7   p. 1181 -
 No. 6   p. 941 -
 No. 5   p. 739 -
 No. 4   p. 537 -
 No. 3   p. 371 -
 No. 2   p. 195 -
 No. 1   p. 1 -

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Vol. 77 (2004)
 No. 12 p. 2129 -
 No. 11 p. 1959 -
 No. 10 p. 1791 -
 No. 9   p. 1613 -
 No. 8   p. 1427 -
 No. 7   p. 1255 -
 No. 6   p. 1041 -
 No. 5   p. 835 -
 No. 4   p. 599 -
 No. 3   p. 407 -
 No. 2   p. 195 -
 No. 1   p. 1 -

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Vol. 76 (2003)
 No. 12 p. 2233 -
 No. 11 p. 2059 -
 No. 10 p. 1873 -
 No. 9   p. 1693 -
 No. 8   p. 1471 -
 No. 7   p. 1291 -
 No. 6   p. 1093 -
 No. 5   p. 853 -
 No. 4   p. 673 -
 No. 3   p. 443 -
 No. 2   p. 225 -
 No. 1   p. 1 -

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Vol. 75 (2002)
 No. 12 p. 2547 -
 No. 11 p. 2309 -
 No. 10 p. 2081 -
 No. 9   p. 1863 -
 No. 8   p. 1637 -
 No. 7   p. 1407 -
 No. 6   p. 1173 -
 No. 5   p. 883 -
 No. 4   p. 623 -
 No. 3   p. 393 -
 No. 2   p. 187 -
 No. 1   p. 1 -

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Vol. 74 (2001)
 No. 12 p. 2223 -
 No. 11 p. 1983 -
 No. 10 p. 1775 -
 No. 9   p. 1525 -
 No. 8   p. 1361 -
 No. 7   p. 1167 -
 No. 6   p. 997 -
 No. 5   p. 773 -
 No. 4   p. 579 -
 No. 3   p. 407 -
 No. 2   p. 201 -
 No. 1   p. 1 -

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Vol. 73 (2000)
 No. 12 p. 2643 -
 No. 11 p. 2403 -
 No. 10 p. 2179 -
 No. 9   p. 1945 -
 No. 8   p. 1699 -
 No. 7   p. 1445 -
 No. 6   p. 1307 -
 No. 5   p. 1053 -
 No. 4   p. 775 -
 No. 3   p. 507 -
 No. 2   p. 267 -
 No. 1   p. 1 -

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Vol. 72 (1999)
  No. 12 p. 2573 -
 No. 11 p. 2357 -
 No. 10 p. 2149 -
 No. 9   p. 1947 -
 No. 8   p. 1647-
 No. 7   p. 1409-
 No. 6   p. 1163 -
 No. 5   p. 879 -
 No. 4   p. 603 -
 No. 3   p. 327 -
 No. 2   p. 151 -
 No. 1   p. 1 -

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Vol. 71 (1998)
  No. 12 p. 2741 -
 No. 11 p. 2465 -
 No. 10 p. 2267 -
 No. 9   p. 2023 -
 No. 8   p. 1739 -
 No. 7   p. 1483 -
 No. 6   p. 1259 -
 No. 5   p. 973 -
 No. 4   p. 755 -
 No. 3   p. 521 -
 No. 2   p. 305 -
 No. 1   p. 1 -

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Vol. 70 (1997)
  No. 12 p. 2861 -
 No. 11 p. 2571 -
 No. 10 p. 2341 -
 No. 9   p. 2005 -
 No. 8   p. 1727 -
 No. 7   p. 1465 -
 No. 6   p. 1211 -
 No. 5   p. 945 -
 No. 4   p. 719 -
 No. 3   p. 509 -
 No. 2   p. 293 -
 No. 1   p. 1 -

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Vol. 69 (1996)
  No. 12 p. 3387 -
 No. 11 p. 3007 -
 No. 10 p. 2673 -
 No. 9   p. 2403 -
 No. 8   p. 2131 -
 No. 7   p. 1805 -
 No. 6   p. 1459 -
 No. 5   p. 1149 -
 No. 4   p. 819 -
 No. 3   p. 515 -
 No. 2   p. 261 -
 No. 1   p. 1 -

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Vol. 68 (1995)
  No. 12 p. 3289 -
 No. 11 p. 2997 -
 No. 10 p. 2769 -
 No. 9   p. 2447 -
 No. 8   p. 2093 -
 No. 7   p. 1753 -
 No. 6   p. 1515 -
 No. 5   p. 1239 -
 No. 4   p. 1065 -
 No. 3   p. 683 -
 No. 2   p. 403 -
 No. 1   p. 1 -

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