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 Vol. 83, No. 3 (March, 2010)

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Award Accounts
The Chemical Society of Japan Award for Young Chemists for 2007
  Web Release Date: February 18, 2010
 199-219  Aryne, ortho-Quinone Methide, and ortho-Quinodimethane: Synthesis of Multisubstituted Arenes Using the Aromatic Reactive Intermediates
 H. Yoshida,* J. Ohshita, and A. Kunai
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Direct synthesis of diverse multisubstituted arenes and benzo-annulated heterocycles based upon new transformations using such aromatic reactive intermediates as arynes, ortho-quinone methides, and ortho-quinodimethanes is described in this account.

BCSJ Award Article
  Web Release Date: February 26, 2010
 220-232  Chemistry of Anthracene–Acetylene Oligomers XV. Synthesis, Structures, and Dynamic Behavior of Chiral Anthrylene–Ethynylene Cyclic Tetramers and Related Derivatives and Resolution of Enantiomers
 T. Ishikawa, T. Shimasaki, H. Akashi, T. Iwanaga, S. Toyota,* and M. Yamasaki
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The rotation of the crank anthrylene group about acetylene linkers was so restricted that the enantiomers of the following cyclic tetramer were resolved by chiral HPLC. The structural and spectroscopic features of this compound are compared with another three derivatives having different crank moieties.

  Web Release Date: February 26, 2010
 233-245  Prediction of Log(IGC50)−1 for Benzene Derivatives to Ciliate Tetrahymena pyriformis from Their Molecular Descriptors
 M. H. Fatemi* and H. Malekzadeh
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The structure–toxicity relationships approaches were used to predict Log(IGC50)−1 of 392 substituted benzenes to the ciliate Tetrahymena pyriformis. The best MLR model had statistics of R2 = 0.822 and SE = 0.312 for training set and R2 = 0.815 and SE = 0.337 for prediction set.

  Web Release Date: February 26, 2010
 246-253  Singlet Oxygen Lifetime in Vitamin E Emulsion Depends on the Oil-Droplet Size
 K. Ohara,* T. Origuchi, and S. Nagaoka
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Singlet oxygen (1O2) lifetime in the emulsion dispersing natural vitamin E was dependent on size of the contained oil-droplet. The results indicate that the 1O2 emission occurs in the interface region around the oil-droplet rather than in the bulk phase.

  Web Release Date: February 26, 2010
 254-260  Dissociative Electron Capture of Hydrogen-Bonded Hydroxy Groups: Molecular Dynamics and Matrix Isolation ESR Study
 P. H. Kasai
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A molecular dynamics calculation has shown that on capture of an electron, hydrogen-bonded methanol dimer dissociates as follows. The OH-hydrogen of the acceptor side cleaves as an atom and abstracts a hydrogen from the methyl unit of the donor side. A matrix isolation ESR study confirmed the formation of the predicted radical, CH3–O−···HO–CH2●.

Selected Paper
  Web Release Date: February 26, 2010
 261-266  Calorimetric Study of Correlated Ligand Dynamics in Mixed-Valence MMX Chain Complex [{Ni2(n-BuCS2)4}I]
 S. Ikeuchi, Y. Yamamura, Y. Yoshida, M. Mitsumi, K. Toriumi, and K. Saito*
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The heat capacity of [{Ni2(n-BuCS2)4}I] was measured by adiabatic calorimetry. The experimental entropy is much smaller than a simple estimate based on the structural disorder found in the crystal structure, indicating the occurrence of correlated dynamics.

  Web Release Date: February 26, 2010
 267-272  Dibridged Bis(Zn2+–cyclen): A Novel Host Molecule of Malonate Dianion in Aqueous Solution
 H. Fujioka,* S. Kishida, T. Ishizu, M. Shiro, E. Kinoshita, and T. Koike
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A dinuclear zinc(II) complex, m,m-bis(Zn2+–cyclen) was synthesized as a novel host molecule for a malonate dianion.

  Web Release Date: February 18, 2010
 273-275  An Atomic Force Microscopy Assay of Intercalation Binding, Unwinding, and Elongation of DNA, Using a Water-Soluble Psoralen Derivative as a Covalent Binding Probe Molecule
 K. Nakano,* Y. Katsumi, N. Soh, and T. Imato
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A single-molecule strategy using atomic force microscopy has simply yet robustly probed an intercalation binding related specific structural relaxation or double-strand elongation of pBR322 by taking advantage of a new psoralen (7H-furo[3,2-g]chromen-7-one) derivative that covalently binds to DNA through a photochemical reaction.

  Web Release Date: February 26, 2010
 276-278  Water Molecules as Binders in Transformation of 2D Coordination Polymer [Cu(4,4′-bpy)2(OTf)2]n into Parallel Aligned 3D Architectures
 K. Komori-Orisaku, K. Hoshino, S. Yamashita, and Y. Koide*
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A conversion of 2D frameworks of {[Cu(4,4′-bpy)2(OTf)2]·2CH3CN}n is performed and crystallographically characterized. Infinite linear water networks assembled in the inter-layer spaces are playing roles of binders that link multiple metal centers through the interplay of coordination and hydrogen bonding.

  Web Release Date: February 26, 2010
 279-287  Total Synthesis of (−)-Tetrodotoxin from d-Glucose: A New Route to Multi-Functionalized Cyclitol Employing the Ferrier(II) Reaction toward (−)-Tetrodotoxin
 S. Akai, H. Seki, N. Sugita, T. Kogure, N. Nishizawa, K. Suzuki, Y. Nakamura, Y. Kajihara, J. Yoshimura, and K. Sato*
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Total synthesis of (−)-tetrodotoxin from d-glucose employing the Ferrier(II) reaction is described.

  Web Release Date: February 26, 2010
 288-290  Tributyl Borate Mediated Biginelli Reaction: A Facile Microwave-Assisted Green Synthetic Strategy toward Dihydropyrimidinones
 C. Ranjith,* G. V. Srinivasan, and K. K. Vijayan*
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A new boron-based catalyst, tributyl borate, is introduced for the synthesis of multi-functionalized pharmacologically active dihydropyrimidinones under a solvent-free, fast, cost effective, and efficient microwave-assisted greener protocol is described.

Selected Paper
  Web Release Date: February 18, 2010
 291-297  Thermostable Rh Catalysts Supported on Metal Phosphates: Effect of Aging on Catalytic Activity for NO–CO–C3H6–O2 Reactions
 K. Ikeue, K. Murakami, S. Hinokuma, K. Uemura, D. Zhang, and M. Machida*
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Rh catalysts supported on tridymite AlPO4 exhibit higher thermal stability and catalytic activity for the NO–CO–C3H6–O2 reaction (A/F = 14.6), compared to those supported on metal oxides, other metal phosphates, and other AlPO4 polymorphs.

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List of Issues
[2009] [2008] [2007]
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[2003] [2002] [2001]
[2000] [1999] [1998]
[1997] [1996] [1995]

Vol. 83 (2010)
 No. 3   p. 199 -
 No. 2   p. 101 -
 No. 1   p. 1 -

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Vol. 82 (2009)
 No. 12 p. 1447 -
 No. 11 p. 1323 -
 No. 10 p. 1215 -
 No. 9   p. 1055 -
 No. 8   p. 917 -
 No. 7   p. 751 -
 No. 6   p. 631 -
 No. 5   p. 539 -
 No. 4   p. 419 -
 No. 3   p. 285 -
 No. 2   p. 127 -
 No. 1   p. 1 -

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Vol. 81 (2008)
 No. 12 p. 1535 -
 No. 11 p. 1337 -
 No. 10 p. 1183 -
 No. 9   p. 1039 -
 No. 8   p. 917 -
 No. 7   p. 785 -
 No. 6   p. 659 -
 No. 5   p. 539 -
 No. 4   p. 411 -
 No. 3   p. 307 -
 No. 2   p. 171 -
 No. 1   p. 1 -

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Vol. 80 (2007)
 No. 12 p. 2247 -
 No. 11 p. 2047 -
 No. 10 p. 1843 -
 No. 9   p. 1635 -
 No. 8   p. 1437 -
 No. 7   p. 1229 -
 No. 6   p. 1021 -
 No. 5   p. 797 -
 No. 4   p. 595 -
 No. 3   p. 433 -
 No. 2   p. 233 -
 No. 1   p. 1 -

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Vol. 79 (2006)
 No. 12 p. 1799 -
 No. 11 p. 1621 -
 No. 10 p. 1463 -
 No. 9   p. 1315 -
 No. 8   p. 1155 -
 No. 7   p. 965 -
 No. 6   p. 811 -
 No. 5   p. 663 -
 No. 4   p. 501 -
 No. 3   p. 361 -
 No. 2   p. 177 -
 No. 1   p. 1 -

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Vol. 78 (2005)
 No. 12 p. 2083 -
 No. 11 p. 1887 -
 No. 10 p. 1705 -
 No. 9   p. 1581 -
 No. 8   p. 1373 -
 No. 7   p. 1181 -
 No. 6   p. 941 -
 No. 5   p. 739 -
 No. 4   p. 537 -
 No. 3   p. 371 -
 No. 2   p. 195 -
 No. 1   p. 1 -

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Vol. 77 (2004)
 No. 12 p. 2129 -
 No. 11 p. 1959 -
 No. 10 p. 1791 -
 No. 9   p. 1613 -
 No. 8   p. 1427 -
 No. 7   p. 1255 -
 No. 6   p. 1041 -
 No. 5   p. 835 -
 No. 4   p. 599 -
 No. 3   p. 407 -
 No. 2   p. 195 -
 No. 1   p. 1 -

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Vol. 76 (2003)
 No. 12 p. 2233 -
 No. 11 p. 2059 -
 No. 10 p. 1873 -
 No. 9   p. 1693 -
 No. 8   p. 1471 -
 No. 7   p. 1291 -
 No. 6   p. 1093 -
 No. 5   p. 853 -
 No. 4   p. 673 -
 No. 3   p. 443 -
 No. 2   p. 225 -
 No. 1   p. 1 -

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Vol. 75 (2002)
 No. 12 p. 2547 -
 No. 11 p. 2309 -
 No. 10 p. 2081 -
 No. 9   p. 1863 -
 No. 8   p. 1637 -
 No. 7   p. 1407 -
 No. 6   p. 1173 -
 No. 5   p. 883 -
 No. 4   p. 623 -
 No. 3   p. 393 -
 No. 2   p. 187 -
 No. 1   p. 1 -

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Vol. 74 (2001)
 No. 12 p. 2223 -
 No. 11 p. 1983 -
 No. 10 p. 1775 -
 No. 9   p. 1525 -
 No. 8   p. 1361 -
 No. 7   p. 1167 -
 No. 6   p. 997 -
 No. 5   p. 773 -
 No. 4   p. 579 -
 No. 3   p. 407 -
 No. 2   p. 201 -
 No. 1   p. 1 -

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Vol. 73 (2000)
 No. 12 p. 2643 -
 No. 11 p. 2403 -
 No. 10 p. 2179 -
 No. 9   p. 1945 -
 No. 8   p. 1699 -
 No. 7   p. 1445 -
 No. 6   p. 1307 -
 No. 5   p. 1053 -
 No. 4   p. 775 -
 No. 3   p. 507 -
 No. 2   p. 267 -
 No. 1   p. 1 -

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Vol. 72 (1999)
  No. 12 p. 2573 -
 No. 11 p. 2357 -
 No. 10 p. 2149 -
 No. 9   p. 1947 -
 No. 8   p. 1647-
 No. 7   p. 1409-
 No. 6   p. 1163 -
 No. 5   p. 879 -
 No. 4   p. 603 -
 No. 3   p. 327 -
 No. 2   p. 151 -
 No. 1   p. 1 -

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Vol. 71 (1998)
  No. 12 p. 2741 -
 No. 11 p. 2465 -
 No. 10 p. 2267 -
 No. 9   p. 2023 -
 No. 8   p. 1739 -
 No. 7   p. 1483 -
 No. 6   p. 1259 -
 No. 5   p. 973 -
 No. 4   p. 755 -
 No. 3   p. 521 -
 No. 2   p. 305 -
 No. 1   p. 1 -

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Vol. 70 (1997)
  No. 12 p. 2861 -
 No. 11 p. 2571 -
 No. 10 p. 2341 -
 No. 9   p. 2005 -
 No. 8   p. 1727 -
 No. 7   p. 1465 -
 No. 6   p. 1211 -
 No. 5   p. 945 -
 No. 4   p. 719 -
 No. 3   p. 509 -
 No. 2   p. 293 -
 No. 1   p. 1 -

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Vol. 69 (1996)
  No. 12 p. 3387 -
 No. 11 p. 3007 -
 No. 10 p. 2673 -
 No. 9   p. 2403 -
 No. 8   p. 2131 -
 No. 7   p. 1805 -
 No. 6   p. 1459 -
 No. 5   p. 1149 -
 No. 4   p. 819 -
 No. 3   p. 515 -
 No. 2   p. 261 -
 No. 1   p. 1 -

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Vol. 68 (1995)
  No. 12 p. 3289 -
 No. 11 p. 2997 -
 No. 10 p. 2769 -
 No. 9   p. 2447 -
 No. 8   p. 2093 -
 No. 7   p. 1753 -
 No. 6   p. 1515 -
 No. 5   p. 1239 -
 No. 4   p. 1065 -
 No. 3   p. 683 -
 No. 2   p. 403 -
 No. 1   p. 1 -

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