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 Vol. 85, No. 1 (January, 2012)

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Accounts
  Web Release Date: December 23, 2011
 1-32  Nanoarchitectonics for Mesoporous Materials
 Katsuhiko Ariga,* Ajayan Vinu,* Yusuke Yamauchi,* Qingmin Ji, and Jonathan P. Hill
[Full Text PDF(J-STAGE)]  Open Access Article

We introduce recent developments of mesoporous materials, including syntheses of mesoporous silica, metal oxides, semiconductors, metals, alloys, organic composites, biocomposites, carbon, carbon nitride, and boron nitride as well as film fabrication, pore alignment, and hierarchic structuring for novel functions.

  Web Release Date: December 23, 2011
 33-50  Polymers in Ionic Liquids: Dawn of Neoteric Solvents and Innovative Materials
 Takeshi Ueki and Masayoshi Watanabe*
[Full Text PDF(J-STAGE)]  Free Access Article

We review recent advances in the use of polymers in ionic liquids from the view point of the “dawn of neoteric solvents and innovative materials” and demonstrate material function and processing of such binary systems.

BCSJ Award Article
  Web Release Date: December 30, 2011
 51-60  Face-to-Face Dimeric Tetrathiafulvalenes and Their Cation Radical and Dication Species as Models of Mixed Valence and π-Dimer States
 Masashi Hasegawa,* Kota Daigoku, Kenro Hashimoto, Hiroyuki Nishikawa, and Masahiko Iyoda*
[Full Text PDF(J-STAGE)]  [Supporting Information]  Free Access Article

The electronic structures of mixed-valence (MV) and π-dimer states of 1,8-bis(tetrathiafulvalenyl)naphthalene derivatives were investigated. Observed electronic spectra in neutral, mono-, di-, and tetracationic states were in good accordance with theoretical calculations.

Selected Paper
  Web Release Date: December 23, 2011
 61-68  Control of Isomerization of Pyridinethiol–Ruthenium Complexes via External Stimuli and Factors Affecting Isomerization Behavior
 Tomohiko Hamaguchi,* Yoshimasa Inoue, Kikujiro Ujimoto, Satoshi Kawata, and Isao Ando
[Full Text PDF(J-STAGE)]  [Supporting Information]

A 2-pyridinethiol ruthenium complex undergoes electrochemically induced linkage isomerization and the isomerization is controlled by an acid and base.

Selected Paper
  Web Release Date: December 23, 2011
 69-78  Noncompetitive On-Chip Immunoassays for Detection of Nonlabeled Antibodies Based on the Excluded Volume Effect of the Target Itself
 Kin-ya Tomizaki,* Masaki Obi, and Hisakazu Mihara
[Full Text PDF(J-STAGE)]  [Supporting Information]

Proposed is a novel, noncompetitive, label-free, and on-chip immunoassay format based on the excluded volume effect by a target antibody that is itself bound to the corresponding epitope on a biochip.

Selected Paper
  Web Release Date: December 23, 2011
 79-86  Water-Soluble Fluorinated Polymer Nanoparticle as 19F MRI Contrast Agent Prepared by Living Random Copolymerization from Dendrimer Initiator
 Michihiro Ogawa, Hiromasa Kataoka, Satoshi Nitahara, Hiroyuki Fujimoto, Hiroyuki Aoki,* Shinzaburo Ito,* Michiko Narazaki, and Tetsuya Matsuda
[Full Text PDF(J-STAGE)]

Water-soluble fluorinated polymer nanoparticles with well-defined structure were successfully prepared as a 19F MRI contrast agent by living radical copolymerization of 2,2,3,3-tetrafluoropropyl methacrylate (TFPMA) and tert-butyl methacrylate (tBMA) initiated from a dendritic macroinitiator.

  Web Release Date: January 15, 2012
 87-92  Theoretical Description of Substituent Effects in 2,4-Pentanedione: AIM, NBO, and NMR Study
 Heidar Raissi, Mehdi Yoosefian,* Ahmad Hajizadeh,* Jalal shakhs Imampour, Mohammad Karimi, and Farzaneh Farzad
[Full Text PDF(J-STAGE)]

Electron density contour plots in the F and COCH3 derivatives of acetylacetone which indicate the effect of substitution on electron density distribution in hydrogen-bond formation.

  Web Release Date: December 30, 2011
 93-100  Ambident Reactivity of Chloro(dialkylamino)(diphenylphosphinoyl)methanes
 Vasilii Petrovich Morgalyuk,* Tat’yana Vladimirovna Strelkova, and Eduard Eugenievich Nifant’ev
[Full Text PDF(J-STAGE)]  [Supporting Information]

Chloro(dialkylamino)(diphenylphosphinoyl)methanes show ambident reactivity when reacting with electrophiles and nucleophiles. Depending on coreactant nature, it behaves as either electrophilic substrate or phosphorus nucleophile.

  Web Release Date: December 30, 2011
 101-109  Molecular Recognition of Chiral Diporphyrin Receptor with a Macrocyclic Cavity for Intercalation of Aromatic Compounds
 Tadashi Ema,* Norichika Ura, Katsuya Eguchi, and Takashi Sakai*
[Full Text PDF(J-STAGE)]

Chiral diporphyrin receptor 1 with a cavity for the intercalation of aromatic guests enabled the naked-eye detection of aromatic explosive as well as chiral discrimination in NMR.

  Web Release Date: January 7, 2012
 110-123  Control of the Equilibrium between 2-Phosphinoazobenzenes and Inner Phosphonium Salts by Heat, Solvent, Acid, and Photoirradiation
 Masaki Yamamura, Naokazu Kano,* and Takayuki Kawashima*
[Full Text PDF(J-STAGE)]  [Supporting Information]

2-(Diphenylphosphino)azobenzenes bearing various substituents, which are in equilibrium with inner phosphonium salts, were synthesized. Substituents, solvents, heat, and acidic additives affected their equilibria. The properties and reactivity of the phosphonium salts in equilibrium with the phosphines can be successfully controlled by photoirradiation.

  Web Release Date: December 30, 2011
 124-132  Pathways and Kinetics of Anisole Pyrolysis Studied by NMR and Selective 13C Labeling. Heterolytic Carbon Monoxide Generation
 Yasuo Tsujino, Yoshiro Yasaka, Nobuyuki Matubayasi, and Masaru Nakahara*
[Full Text PDF(J-STAGE)]  Open Access Article



Conversion of the 13C-labeled anisole (H313COC6H5) at 500 °C was confined to the methoxy-originated fragments, 13CO (conversion fraction f = ca. 1/2) and 13CH4 (f = ca. 1/2), and the reactive intermediate, H13CHO* (f = ca. 1/20), without the phenyl ring disintegration.

  Web Release Date: December 30, 2011
 133-135  Synthesis of Non-Steroidal Estrogen Receptor Antagonists R1128 A, B, C, and D via an Oxazoline-Promoted Iterative ortho-Lithiation Strategy
 Tsutomu Fukuda, Koichiro Fukushima, Susumu Sanai, and Masatomo Iwao*
[Full Text PDF(J-STAGE)]  [Supporting Information]

A concise total synthesis of R1128 A–D has been achieved using iterative ortho-lithiation of 2-(4-methoxyphenyl)-4,4-dimethyloxazoline as the key reaction.

  Web Release Date: December 30, 2011
 136-143  Synthesis, Characterization, and OFET and OLED Properties of π-Extended Ladder-Type Heteroacenes Based on Indolodibenzothiophene
 Changsheng Wang, Jun-ichi Nishida,* Martin R. Bryce,* and Yoshiro Yamashita
[Full Text PDF(J-STAGE)]  [Supporting Information]

DIBBBT derivative (R1 = Cl) has been used as a synthon for extension of the π-system by metal-catalyzed cross-coupling reactions, including a copolymerization. p-Type OFET behavior is reported for the DIBBBT systems and OLED behavior is reported for a copolymer.

  Web Release Date: December 23, 2011
 144-149  Structure and CO Oxidation Activity of Pt/CeO2 Catalysts Prepared Using Arc-Plasma
 Satoshi Hinokuma, Madoka Okamoto, Eriko Ando, Keita Ikeue, and Masato Machida*
[Full Text PDF(J-STAGE)]

Pt/CeO2 as prepared by arc-plasma, which was characterized by highly dispersed uniform metallic Pt crystallites with the size of 2.6 ± 0.7 nm, exhibited higher catalytic activity for CO oxidation than those prepared by conventional wet impregnation.

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Vol. 85 (2012)
 No. 1   p. 1 -

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Vol. 84 (2011)
 No. 12 p. 1295 -
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 No. 9   p. 879 -
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Vol. 83 (2010)
 No. 12 p. 1401 -
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 No. 10 p. 1133 -
 No. 9   p. 969 -
 No. 8   p. 855 -
 No. 7   p. 735 -
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 No. 4   p. 299 -
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Vol. 82 (2009)
 No. 12 p. 1447 -
 No. 11 p. 1323 -
 No. 10 p. 1215 -
 No. 9   p. 1055 -
 No. 8   p. 917 -
 No. 7   p. 751 -
 No. 6   p. 631 -
 No. 5   p. 539 -
 No. 4   p. 419 -
 No. 3   p. 285 -
 No. 2   p. 127 -
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Vol. 81 (2008)
 No. 12 p. 1535 -
 No. 11 p. 1337 -
 No. 10 p. 1183 -
 No. 9   p. 1039 -
 No. 8   p. 917 -
 No. 7   p. 785 -
 No. 6   p. 659 -
 No. 5   p. 539 -
 No. 4   p. 411 -
 No. 3   p. 307 -
 No. 2   p. 171 -
 No. 1   p. 1 -

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Vol. 80 (2007)
 No. 12 p. 2247 -
 No. 11 p. 2047 -
 No. 10 p. 1843 -
 No. 9   p. 1635 -
 No. 8   p. 1437 -
 No. 7   p. 1229 -
 No. 6   p. 1021 -
 No. 5   p. 797 -
 No. 4   p. 595 -
 No. 3   p. 433 -
 No. 2   p. 233 -
 No. 1   p. 1 -

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Vol. 79 (2006)
 No. 12 p. 1799 -
 No. 11 p. 1621 -
 No. 10 p. 1463 -
 No. 9   p. 1315 -
 No. 8   p. 1155 -
 No. 7   p. 965 -
 No. 6   p. 811 -
 No. 5   p. 663 -
 No. 4   p. 501 -
 No. 3   p. 361 -
 No. 2   p. 177 -
 No. 1   p. 1 -

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Vol. 78 (2005)
 No. 12 p. 2083 -
 No. 11 p. 1887 -
 No. 10 p. 1705 -
 No. 9   p. 1581 -
 No. 8   p. 1373 -
 No. 7   p. 1181 -
 No. 6   p. 941 -
 No. 5   p. 739 -
 No. 4   p. 537 -
 No. 3   p. 371 -
 No. 2   p. 195 -
 No. 1   p. 1 -

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Vol. 77 (2004)
 No. 12 p. 2129 -
 No. 11 p. 1959 -
 No. 10 p. 1791 -
 No. 9   p. 1613 -
 No. 8   p. 1427 -
 No. 7   p. 1255 -
 No. 6   p. 1041 -
 No. 5   p. 835 -
 No. 4   p. 599 -
 No. 3   p. 407 -
 No. 2   p. 195 -
 No. 1   p. 1 -

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Vol. 76 (2003)
 No. 12 p. 2233 -
 No. 11 p. 2059 -
 No. 10 p. 1873 -
 No. 9   p. 1693 -
 No. 8   p. 1471 -
 No. 7   p. 1291 -
 No. 6   p. 1093 -
 No. 5   p. 853 -
 No. 4   p. 673 -
 No. 3   p. 443 -
 No. 2   p. 225 -
 No. 1   p. 1 -

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Vol. 75 (2002)
 No. 12 p. 2547 -
 No. 11 p. 2309 -
 No. 10 p. 2081 -
 No. 9   p. 1863 -
 No. 8   p. 1637 -
 No. 7   p. 1407 -
 No. 6   p. 1173 -
 No. 5   p. 883 -
 No. 4   p. 623 -
 No. 3   p. 393 -
 No. 2   p. 187 -
 No. 1   p. 1 -

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Vol. 74 (2001)
 No. 12 p. 2223 -
 No. 11 p. 1983 -
 No. 10 p. 1775 -
 No. 9   p. 1525 -
 No. 8   p. 1361 -
 No. 7   p. 1167 -
 No. 6   p. 997 -
 No. 5   p. 773 -
 No. 4   p. 579 -
 No. 3   p. 407 -
 No. 2   p. 201 -
 No. 1   p. 1 -

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Vol. 73 (2000)
 No. 12 p. 2643 -
 No. 11 p. 2403 -
 No. 10 p. 2179 -
 No. 9   p. 1945 -
 No. 8   p. 1699 -
 No. 7   p. 1445 -
 No. 6   p. 1307 -
 No. 5   p. 1053 -
 No. 4   p. 775 -
 No. 3   p. 507 -
 No. 2   p. 267 -
 No. 1   p. 1 -

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Vol. 72 (1999)
  No. 12 p. 2573 -
 No. 11 p. 2357 -
 No. 10 p. 2149 -
 No. 9   p. 1947 -
 No. 8   p. 1647-
 No. 7   p. 1409-
 No. 6   p. 1163 -
 No. 5   p. 879 -
 No. 4   p. 603 -
 No. 3   p. 327 -
 No. 2   p. 151 -
 No. 1   p. 1 -

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Vol. 71 (1998)
  No. 12 p. 2741 -
 No. 11 p. 2465 -
 No. 10 p. 2267 -
 No. 9   p. 2023 -
 No. 8   p. 1739 -
 No. 7   p. 1483 -
 No. 6   p. 1259 -
 No. 5   p. 973 -
 No. 4   p. 755 -
 No. 3   p. 521 -
 No. 2   p. 305 -
 No. 1   p. 1 -

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Vol. 70 (1997)
  No. 12 p. 2861 -
 No. 11 p. 2571 -
 No. 10 p. 2341 -
 No. 9   p. 2005 -
 No. 8   p. 1727 -
 No. 7   p. 1465 -
 No. 6   p. 1211 -
 No. 5   p. 945 -
 No. 4   p. 719 -
 No. 3   p. 509 -
 No. 2   p. 293 -
 No. 1   p. 1 -

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Vol. 69 (1996)
  No. 12 p. 3387 -
 No. 11 p. 3007 -
 No. 10 p. 2673 -
 No. 9   p. 2403 -
 No. 8   p. 2131 -
 No. 7   p. 1805 -
 No. 6   p. 1459 -
 No. 5   p. 1149 -
 No. 4   p. 819 -
 No. 3   p. 515 -
 No. 2   p. 261 -
 No. 1   p. 1 -

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Vol. 68 (1995)
  No. 12 p. 3289 -
 No. 11 p. 2997 -
 No. 10 p. 2769 -
 No. 9   p. 2447 -
 No. 8   p. 2093 -
 No. 7   p. 1753 -
 No. 6   p. 1515 -
 No. 5   p. 1239 -
 No. 4   p. 1065 -
 No. 3   p. 683 -
 No. 2   p. 403 -
 No. 1   p. 1 -

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