Bulletin of the Chemical Society of Japan

Vol. 74, No. 12 (December, 2001)

 

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Copyright (C) 2001 The Chemical Society of Japan

 

CONTENTS


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Accounts
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Calorimetric Investigations of Phase Transitions Occurring in Molecule-Based Materials in Which Electrons Are Directly Involved

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M. Sorai

pages 2223-2253

 

Metallaphosphorane Chemistry: Preparations, Structures, and Reactivities

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H. Nakazawa,* K. Kubo, and K. Miyoshi

pages 2255-2267

 


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Headline Articles
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Molecular Dynamics Simulation of Neocarrabiose 2,4′-Bis(sulfate) and Carrabiose 4′,2-Bis(sulfate) as Building Blocks of -Carrageenan in Water

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K. Ueda,* K. Iwama, and H. Nakayama

pages 2269-2277

 


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Theoretical and Physical
Articles
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The Surface Reaction Mechanism on Al(111)

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T. Nakajima and K. Yamashita*

pages 2279-2283

 

New Interpretation of the Transfer Coefficient in Electrochemistry

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T. Sakata*, # and H. Nakamura

pages 2285-2293

 

Thermochromism and Solvatochromism by Reversible Dye Aggregation in Sugar-Gel Matrices

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R. Matsushima,* H. Okuda, M. Aida, and A. Ogiue

pages 2295-2301

 

Radicals in the Mechanochemical Dechlorination of Hazardous Organochlorine Compounds Using CaO Nanoparticles

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T. Ikoma,* Q. Zhang, F. Saito, K. Akiyama, S. Tero-Kubota, and T. Kato

pages 2303-2309

 

Enthalpy–Entropy Compensation of Cyclodextrin Complexation with Different Classes of Substrates

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L. Liu,*, # C. Yang, and Q.-X. Guo*

pages 2311-2314

 

Aromatic Character of Large Deltahedral Borane Dianions As Estimated Using the Kettle–Tomlinson Bonding Model

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J. Aihara

pages 2315-2318

 

The ESR Spectra, Electronic Structure, and Thermal Reactivity of Fluoroethane Cations

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K. Komaguchi, H. Sakurai, M. Shiotani, and A. Hasegawa*,

pages 2319-2324

 

Magnetic Field Effect on the Fluorescence of m-Phenylenebis(phenylmethylene) in a Rigid Glass at 77 K

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Y. Tanimoto,* Y. Akimoto, Y. Fujiwara, M. Mukai, T. Takui, T. Kinoshita, and K. Itoh

pages 2325-2326

 


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Analitical and Inorganic
Articles
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The Incomplete Cubane Complexes Having Co3O4 or Mo3S4 Core with the N–N–O Type Tridentates; L-histidinato and Ethylenediamine-N-acetato

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T. Ama,* Md. M. Rashid, A. K. Saker, H. Miyakawa, T. Yonemura, H. Kawaguchi, and T. Yasui

pages 2327-2333

 

Structure of EuCrO4 and Its Electronic and Magnetic Properties

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H. Konno,* Y. Aoki, Z. Klencsr, A. Vrtes, M. Wakeshima, K. Tezuka, and Y. Hinatsu

pages 2335-2341

 

Chloride Transfer across the Liquid–Liquid Interface Facilitated by a Mono-Thiourea as a Hydrogen-Bonding Ionophore

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S. Nishizawa, T. Yokobori, R. Kato, T. Shioya, and N. Teramae*

pages 2343-2347

 

Preparation, Crystal Structures and Spectroscopic Properties of a Series of Cobalt(III) Phosphine Complexes: trans- and cis-[Co(dtc)2(PMe3−n Phn)2]+ (dtc =N,N-Dimethyl-dithiocarbamate; n =0, 1, 2 or 3)

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T. Suzuki,* S. Kashiwamura, and K. Kashiwabara*,

pages 2349-2359

 

Pressure-Stabilized Low-Spin State for Binuclear Iron(III) Spin-Crossover Compounds

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S. Hayami,* Y. Hosokoshi, K. Inoue, Y. Einaga, O. Sato, and Y. Maeda*

pages 2361-2368

 

N, N-Dimethylindoaniline Mediated-Amperometric Detection of L-lactate

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K. Hirano,* H. Yamato, K. Kunimoto, and M. Ohwa

pages 2369-2372

 

Spectrophotometric Determination of Chromium in Ores, Steels and Pure Nickel Samples using Phenothiazines

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A. A. Mohamed

pages 2373-2374

 

Structures of Dinuclear Copper(II) Complexes Bridged by One Oximato, One Methoxo and One Perchlorato Ligand, and One Oximato and Two Acetato Ligands

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S. Sakamoto, A. Yatani, K. Kimura, M. Fujii, Y. Nakao,* S. Kashino, M. Kinoshita, and W. Mori

pages 2375-2376

 

Synthesis, Structure, and Magnetic Property of a Dinuclear Vanadium(III) Complexes with N-Hydroxyethyliminodiacetate

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K. Kanamori,* K. Ishida, K. Fujimoto, T. Kuwai, and K. Okamoto

pages 2377-2378

 


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Orgainc and Biological
Articles
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-Interactions of Modified Nucleobases. On Mesomeric Purine Betaines with Inversed Charge Properties.

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A. Schmidt*, # and M. K. Kindermann

pages 2379-2384

 

The Reaction of Peroxynitrite with Organic Molecules Bearing a Biologically Important Functionality. The Multiplicity of Reaction Modes as Exemplified by Hydroxylation, Nitration, Nitrosation, Dealkylation, Oxygenation, and Oxidative Dimerization and Cleavage

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N. Nonoyama, H. Oshima, C. Shoda, and H. Suzuki*

pages 2385-2395

 

Novel Regioselective Synthesis of 6-(3-Hydroxy-1-propenyl)-2-phenyl-2,3-dihydrobenzo[b]-1,4-dioxin-3-methanol

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T. Ganesh, K. K. Sharma, and G. L. D. Krupadanam*

pages 2397-2399

 

Neutral Lithium Triflate (LiOTf) Efficiently Catalyzes Chemoselective Preparations of Cyclic and Acyclic Dithioacetals from Carbonyl Compounds, Acylals, and O,O-Cyclic and Open-Chain Acetals under Solvent-Free Conditions

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H. Firouzabadi,* S. Eslami, and B. Karimi

pages 2401-2406

 

Synthesis and Crystal Structures of Silapericyclynes

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M. Unno, T. Saito, and H. Matsumoto*

pages 2407-2413

 

Palladium-Catalyzed Synthesis of Biaryls from Arylzinc Compounds Using N-Chloro-succinimide or Oxygen as an Oxidant

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K. M. Hossain, T. Kameyama, T. Shibata, and K. Takagi*

pages 2415-2420

 

Hydrogen-Bond-Like Nature of the CH/ Interaction as Evidenced by Crystallographic Database Analyses and Ab Initio Molecular Orbital Calculations

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O. Takahashi,* Y. Kohno, S. Iwasaki, K. Saito, M. Iwaoka, S. Tomoda, Y. Umezawa, S. Tsuboyama, and M. Nishio*,

pages 2421-2430

 

EPR Studies at High-Pressure. VI. Spin-Exchange Reaction of Nitroxide Radical with Copper(II) and Iron(III) Complexes

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Y. Sueishi* and A. Hori

pages 2431-2432

 

One-Pot Preparations of (Dichloroiodo)arenes from Some Arenes

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P. Luliski, N. Obeid, and L. Skulski*

pages 2433-2434

 

Synthesis and Crystal Structure of a Calix[4]arene-Based Dual Boron–Dipyrrin System.

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T. Nishioka, T. Arimura,* Y. Suga, S. Murata, M. Tachiya, and M. Goto

pages 2435-2436

 


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Applied and Materials
Articles
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Liquid-Crystalline Properties of Dissymmetric Molecules Part 8: The Effect of Conformation on the Mesomorphic Properties for Liquid–Crystal Compounds Having a Lateral Long Alkoxy Group

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J. Wu, H. Okamoto,* Y. Morita, and S. Takenaka

pages 2437-2443

 

Optical Oxygen Sensing Material: Terbium(III) Complex Adsorbed Thin Film

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Y. Amao,* Y. Ishikawa, I. Okura, and T. Miyashita

pages 2445-2449

 

Artificial Neural Network for Predicting the Toxicity of Organic Molecules

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G. Admans, Y. Takahashi,* S. Ban, H. Kato, H. Abe, and S. Hanai

pages 2451-2461

 


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Errata
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Erratum : Bull. Chem. Soc. Jpn., 74, 869 (2001)
Copper(II) Complexes Resulting from the Oxygenation of (2,9-Dimethyl-1,10-phenanthroline)copper(I) Chloride in the Presence of Dimethylformamide

K. Oyaizu, M. Ueno, H. Li, and E. Tsuchida*

pages 2463-2463

 

Erratum : Bull. Chem. Soc. Jpn., 74, 873 (2001)
Transformation of Isatin 3-Acylhydrazones under Acetylating Conditions: Synthesis and Structure Elucidation of 1,5′-Disubstituted 3′-Acetylspiro[oxindole-3,2′-[1,3,4]oxadiazolines]

L. Somogyi

pages 2465-2465

 

Erratum : Bull. Chem. Soc. Jpn., 74, 889 (2001)
Synthesis and Properties of Head-to-head, Head-to-tail, and Tail-to-tail Orientational Isomers of Extended Dihexylbithiophene–Octaethylporphyrin System [OEP–(DHBT)n–OEP] Connected with 1,3-Butadiyne Linkages

H. Higuchi,* T. Ishikura, K. Mori, Y. Takayama, K. Yamamoto, K. Tani, K. Miyabayashi, and M. Miyake

pages 2467-2467