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BCSJ Award Article (2012) The Bulletin of the Chemical Society of Japan, Vol. 85 (No. 1-12)
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2012 Vol. 85 Jan. |
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51-60 |
Face-to-Face Dimeric Tetrathiafulvalenes and Their Cation Radical and Dication Species as Models of Mixed Valence and π-Dimer States |

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Masashi Hasegawa,* Kota Daigoku, Kenro Hashimoto, Hiroyuki Nishikawa, and Masahiko Iyoda*
[Full Text PDF(J-STAGE)] [Supporting Information] [Full Text HTML]
The electronic structures of mixed-valence (MV) and π-dimer states of 1,8-bis(tetrathiafulvalenyl)naphthalene derivatives were investigated. Observed electronic spectra in neutral, mono-, di-, and tetracationic states were in good accordance with theoretical calculations.
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