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new issue Vol. 85, No. 5, May 2012
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List of Award Articles
Web Release Date:  April 21, 2012
558-562

Directly Linked Corrole Oligomers via Facile Oxidative 3–3′ Coupling Reaction
Sho Hirabayashi, Masato Omote, Naoki Aratani,* and Atsuhiro Osuka*
[Full Text PDF(J-STAGE)]  [Supporting Information]  [Full Text HTML]  

5,10,15-Tris(pentafluorophenyl)corrole underwent regioselective oxidative coupling reaction at 3,3′-position to give dimer and trimer. Similar reaction of the dimer gave tetramer and hexamer. The structures of the trimer and tetramer cobalt(III) complexes have been unambiguously determined by X-ray diffraction analysis.




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